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HomeMy WebLinkAboutMATERIAL SAFETY DATA SHEETS Permit 09-0163 PRIOR LAKE TRANSMISSION 16783 TORONTO AVENUE SE PRIOR LAKE, MN 55372 952-440-6600 MSDS LIST PRODUCT Transmission Fluid 80-90 Gear Oil Penetrant Oil Spray can Engine Cleaner and Degreaser 5 -30 Motor Oil Flash Concrete Cleaner Zep 70 Aerosol Lubricant Antifreeze Coolant Brake Fluild Brake Cleaner Spray Paint Primer Red Ox Spray Paint Windshield Washer Fluid Lithium Grease Ace Aqua Kleen Alumasafe Powered Parts Wash QUANlTY 250 max. gallon container 15 gallon drum 1 - 12 cans 1 - 12 cans 1 - 4 cases 1 - 5 gallon pail 1 - 4 cans 1 - 4 - gallon containers 1 - 432 ounce bottles 1 - 5 gallon container 2 cans 4 cans 1 - 4 - gallon containers 6 grease gun tubes 1 - 1 gallon container " Service Pro Premium ATF, Dexron@ III/Mercon@ Material Safety Data Sheet Association of Independent Oil Distributors P.O. Box 1861 Montrose, CO 81402-1861 MSDS No. 633133386097 Revision Date 04/19/2005 IMPORTANT: Read this MSDS before handling or disposing of this product and pass this information on to employees, customers and users of this product. Emergency Overview Liquid. Red. Odor Mild petroleum odor Hazard Ranklngs Physical State Color Health Hazard Fire Hazard Reactivity HMIS 1 1 o NFPA o 1 o WARNINGI Oil injected into the skin from high-pressure leaks in hydraulic systems can cause severe injury. Most damage occurs during the first few hours. Seek medical attention immediately. Surgical removal of oil may be necessary. Spills may create a slipping hazard. . = Chronic Health Hazard PROTECTIVE EQUIPMENT Minimum Recommended See Section 8 for Details uo~1 SECTION 1 : IDENTIFICATION Product Number CAS Number Product Family Synonyms Service Pro Premium A TF, Dexron@ II1/Mercon@ 633133386097 Mixture. Automatic Transmission Fluid Automatic Transmission Fluid; Service Pro SAP Product Code No.: 633133386097 Technical Contact (800) 313-2463 Trade Name Medical Emergency (800) 313-2463 CHEMTREC Emergency (United States Only) (800) 424-9300 SECTION 2: COMPOSITION Component Name(s) 1) Distillates, petroleum, hydrotreated heavy paraffinic 2) Distillates, petroleum, solvent-refined heavy paraffinic 3) Proprietary Ingredients 4) Distillates, petroleum, solvent-refined light paraffinic CAS Registry No. 64742-54-7 64741-88-4 Proprietary Mixture 64741-89-5 Concentration (%) 0-95 0-15 0-20 0-95 SECTION 3: HAZARDS IDENTIFICATION Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS. Major Route(s) of Entry Skin contact. Signs and Symptoms of Acute Exposure Inhalation No significant adverse health effects are expected to occur upon short-term exposure. Eye Contact This product can cause transient mild eye irritation with short-term contact with liquid sprays or mists. MSDS No. 633133386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 1 Skin Contact Ingestion Chronic Health Effects Summary Conditions Aggravated by Exposure Target Organs Carcinogenic Potential Service Pro Premium A TF, Dexron@ III/Mercon@ This material can cause mild skin irritation from prolonged or repeated skin contact. Injection under the skin can cause inflammation and swelling. Injection of pressurized hydrocarbons can cause severe, permanent tissue damage. Initial symptoms may be minor. Injection of petroleum hydrocarbons requires immediate medical attention. If swallowed, large volumes of material can cause generalized depression, headache, drowsiness, nausea, vomiting and diarrhea. Smaller doses can cause a laxative effect. If aspirated into the lungs, liquid can cause lung damage. Contains a petroleum-based mineral oil. Prolonged or repeated skin contact can cause mild irritation and inflammation characterized by drying, cracking, (dermatitis) or oil acne. Repeated or prolonged inhalation of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause respiratory irritation or other pulmonary effects. Medical conditions aggravated by exposure to this material may indude pre-existing skin disorders. This material may cause damage to the following organs: skin. This product does not contain any components at concentrations above 0.1 % which are considered carcinogenic by OSHA, IARC or NTP. OSHA Hazard Classification is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present the product does not exhibit the hazard as defined in the OSHA Hazard Communication Standard 29 CFR 1910.1200. OSHA Health Hazard Classification OSHA Ph sical Hazard Classification Irritant Toxic 0 Combustible 0 E losive 0 ro horlc Sensitizer HI hi Toxic 0 Flammable Oxidizer 0 Water-reactive Corrosive Carcin enic 0 Com ressed Gas Or anic Peroxide 0 Unstable SECTION 4: FIRST AID MEASURES Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid. For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS. Inhalation Eye Contact Skin Contact Ingestion Notes to Physician Vaporization is not expected at ambient temperatures. This material is not expected to cause inhalation-related disorders under anticipated conditions of use. In case of overexposure, move the person to fresh air. Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water while occasionally lifting and lowering eyelids. Seek medical attention if excessive tearing, redness, or pain persists. If bumed by hot material, cool skin by quenching with large amounts of cool water. Remove contaminated shoes and dothing. Wipe off excess material. Wash exposed skin with mild soap and water. Seek medical attention if tissue appears damaged or if pain or irritation persists. Thoroughly dean contaminated clothing before reuse. Discard contaminated leather goods. If material is injected under the skin, seek medical attention immediately. Do not induce vomiting unless directed to by a physician. Do not give anything to drink unless directed to by a physician. Never give anything by mouth to a person who is not fully conscious. Seek medical attention immediately. The viscosity range ofthe product represented by this MSDS is 100 to 400 SUS at 1000 F. Accordingly, upon ingestion there is a low risk of aspiration. Careful gastric lavage or emesis may be considered to evacuate large quantities of material. In the event of injection in underlying tissue, immediate treatment should indude extensive incision, debridement and saline irrigation. Inadequate treatment can result in ischemia and gangrene. Early symptoms may be minimal. SECTION 5: FIRE FIGHTING MEASURES NFPA Flammability NFPA Class-illS combustible material. Slightly combustible! Classification MSDS No. 633133386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 2 Service Pro Premium A TF, Dexron@ III/Mercon@ Flash Point Method CLOSED CUP: 1710C (3400F) (Pensky-Martens (ASTM D-93)) OPEN CUP: 1990C (3900F) (Cleveland). Lower Flammable Limit Autoignition Temperature Hazardous Combustion Products No data. Upper Flammable Limit No data. Not available. Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and trace oxides of sulfur and/or nitrogen. This material can burn but will not readily ignite. This material will release vapors when heated above the flash point temperature that can ignite when exposed to a source of ignition. In enclosed spaces, heated vapor can ignite with explosive force. Mists or sprays may burn at temperatures below the flash point. Extinguishing Media Use dry chemical, foam, Carbon Dioxide or water fog. Special Properties Protection of Fire Fighters Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained breathing apparatus to protect against potential hazardous combustion or decomposition products and oxygen deficiencies. SECTION 6: ACCIDENTAL RELEASE MEASURES Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For more specific information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal Protection in Section 8 and Disposal Considerations in Section 13 of this MSDS. Do not touch damaged containers or spilled material unless wearing appropriate protective equipment. Slipping hazard; do not walk through spilled material. Stop leak if you can do so without risk. For small spills, absorb or cover with dry earth, sand, or other inert non-combustible absorbent material and place into waste containers for later disposal. Contain large spills to maximize product recovery or disposal. Prevent entry into waterways or sewers. In urban area, cleanup spill as soon as possible. In natural environments, seek cleanup advice from specialists to minimize physical habitat damage. SECTION 7: HANDLING AND STORAGE Handling Avoid contamination and extreme temperatures to minimize product degradation. Empty containers may contain product residues that can ignite with explosive force. Do not pressurize, cut, weld, braze solder, drill, grind or expose containers to flames, sparks, heat or other potential ignition sources. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers and/or waste residues of this product. Storage Keep container closed. Do not store with strong oxidizing agents. Do not store at temperatures above 1200 F or in direct sunlight for extended periods of time. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers or waste residues of this product. SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists and/or vapors below the recommended exposure limits (see below). An eye wash station and safety shower should be located near the work-station. Personal Protective Equipment Personal protective equipment should be selected based upon the conditions under which this material is used. A hazard assessment of the work area for PPE requirements should be conducted by a qualified professional pursuant to OSHA regulations. The following pictograms represent the minimum requirements for personal protective equipment. For certain operations, additional PPE may be required. oa~1 MSDS No. 633133386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 3 Service Pro Premium A TF I Dexron@ III/Mercon@ Eye Protection Wear goggles and/or face shield if splashing or spraying is anticipated. Wear goggles and face shield if material is heated above 1250F (510C). Have suitable eye wash water available. Hand Protection No special skin protection other than good personal hygiene practice is recommended under anticipated conditions of use. However, when prolonged or extensive contact is possible, use of disposable PCV or nitrile gloves is recommended. Wash hands with plenty of mild soap and water before eating, drinking, smoking, using toilet facilities, or leaving work. Body Protection Use clean and impervious protective clothing (e.g., neoprene or Tyvek@) if splashing or spraying conditions are present. Protective clothing may include long-sleeve outer garment, apron, or lab coat. If significant contact occurs, remove oil-contaminated clothing as soon as possible and promptly shower. Launder contaminated before reuse or discard. Wear heat protective boots and protective clothing when handling material at elevated temperatures. Respiratory Vaporization is not expected at ambient temperatures. Therefore, the need for respiratory protection is Protection not anticipated under normal use conditions and with adequate ventilation. If elevated airborne concentrations above applicable workplace exposure levels are anticipated, a NIOSH-approved organic vapor respirator equipped with a dust/mist prefilter should be used. Protection factors vary depending upon the type of respirator used. Respirators should be used in accordance with OSHA requirements (29 CFR 1910.134). General Comments Use good personal hygiene practices. Wash hands and other exposed skin areas with plenty of mild soap and water before eating, drinking, smoking, use of toilet facilities, or leaving work. DO NOT use gasoline, kerosene, solvents or harsh abrasives as skin cleaners. Since specific exposure standardslcontrollimits have not been established for this product, the "Oil Mist, Mineral" exposure limits shown below are suggested as minimum control guidelines. Occupational Exposure Guidelines Substance 1) Oil Mist, Mineral Applicable Workplace Exposure Levels ACGIH (United States). TWA: 5 mg/m3 STEL: 10 mglm3 OSHA (United States). TWA: 5 mg/m3 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid. Color Red. Odor Mild petroleum odor Specific Gravity 0.87 (Water = 1) pH Not Applicable. Vapor >1 (Air = 1) Density Melting/Freezing Not available. Point Boiling PointJRange Not available. Vapor Pressure <0.01 mm of Hg (at 200C) Viscosity (cSt @ 400C) 36 Volatile Negligible volatility Characteristics Solubility in Water Insoluble in cold water. Additional Properties Gravity, oAPI (ASTM D287) = 31.5 @ 6()0 F Density = 7.23 Lbslgal. Viscosity (ASTM D2161) = AP 180 SUS @ 100" F SECTION 1 0: STABILITY AND REACTIVITY Chemical Stability Stable. Hazardous Polymerization Not expected to occur Conditions to Avoid Keep away from extreme heat, sparks, open flame, and strongly oxidizing conditions. Materials Incompatibility Strong oxidizers. MSDS No. 633133386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 4 Service Pro Premium ATF, Dexron@III/Mercon@ Hazardous Decomposition Products No additional hazardous decomposition products were identified other than the combustion products identified in Section 5 of this MSDS, SECTION 11: TOXICOLOGICAL INFORMATION For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification In Section 3 of this MSDS. Toxicity Data Distillates, petroleum, hydrotreated heavy paraffinic: ORAL (LD50): Acute: >5000 mg/kg [Rat]. DERMAL (LD50): Acute: >2000 mglkg [Rabbit]. Distillates, petroleum, solvent-refined heavy paraffinic: ORAL (LD50): Acute: >5000 mglkg [Rat]. DERMAL (LD50): Acute: >2000 mglkg [Rabbit]. Distillates, petroleum, solvent-refined light paraffinic: ORAL (LD50): Acute: >5000 mg/kg [Rat]. DERMAL (LD50): Acute: >2000 mglkg [Rabbit]. Distillates, petroleum, hydrotreated heavy paraffinic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested. Distillates, petroleum, solvent-refined heavy paraffinic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested. Analyses conducted by method IP 346 indicate that the polycyclic aromatic concentration of this mineral oil is below 3.0 weight percent. Distillates, petroleum, solvent-refined light paraffinic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested. Analyses conducted by method IP 346 indicate that the polycyclic aromatic concentration of this mineral oil is below 3.0 weight percent. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Analysis for ecological effects has not been conducted on this product. However, if spilled, this product, its storage tank water bottoms and sludge, and any contaminated soil or water may be hazardous to human, animal, and aquatic life. Also, the coating action associated with this product can be harmful or fatal to aquatic life and waterfowl. An environmental fate analysis has not been conducted on this specific product. Plants and animals may experience harmful or fatal effects when coated with petroleum-based products. Petroleum-based (mineral) lube oils will normally float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway can result in a loss of marine life or create an anaerobic environment. Environmental Fate MSDS No. 633133386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 5 Service Pro Premium ATF, Oexron@III/Mercon@ SECTION 13: DISPOSAL CONSIDERATIONS Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent materials and residues at the time of disposition. Conditions of use may cause this material to become a "hazardous waste", as defined by federal or state regulations. It is the responsibility of the user to determine if the material is a RCRA "hazardous waste" at the time of disposal. Transportation, treatment, storage and disposal of waste material must be conducted in accordance with RCRA regulations (see 40 CFR 260 through 40 CFR 271). State and/or local regulations may be more restrictive. Contact the RCRAlSuperfund Hotline at (800) 424-9346 or your regional US EPA office for guidance concerning case specific disposal issues. DOT Status SECTION 14: TRANSPORT INFORMATION Not a U.S. Department of Transportation regulated material. Proper Shipping Name Packing Group(s) Reportable Quantity Placards HAZMA T STCC No. MARPOL III Status Not regulated. Hazard Class Not regulated, Not applicable. UN/NA ID Not regulated. A Reportable Quantity (RQ) has not been established for any components of this material. ~~ r I'. ~ Emergency Response Guide No. Not applicable. Not assigned. Not a DOT "Marine Pollutant" per 49 CFR 171.8. SECTION 15: REGULATORY INFORMATION TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory. SARA 3021304 SARA 311/312 SARA 313 CERCLA CWA California Proposition 65 The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to Subparts 302 and 304 to submit emergency planning and notification information based on Threshold Planning Quantities (TPQs) and Reportable Quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355. No components were identified. The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to this subpart to submit aggregate information on chemicals by "Hazard Category" as defined in 40 CFR 370.2. This material would be classified under the following hazard categories: No SARA 311/312 hazard categories identified. This product contains the following components in concentrations above de minimis levels that are listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section 313 of SARA: No components were identified. The Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) requires notification of the National Response Center concerning release of quantities of "hazardous substances" equal to or greater than the reportable quantities (RQs) listed in 40 CFR 302.4. As defined by CERCLA, the term "hazardous substance" does not include petroleum, including crude oil or any fraction thereof which is not otherwise specifically designated in 40 CFR 302.4. Chemical substances present in this product or refinery stream that may be subject to this statute are: None identified. This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. This material may contain the following components which are known to the State of California to cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): Toluene: 0.0008%. MSDS No. 633133386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 6 Service Pro Premium A TF, Dexron@ III/Mercon@ New Jersey Petroleum Oil (Automatic Transmission Fluid) Right-to-Know Label Additional Regulatory Remarks No additional regulatory remarks. SECTION 16: OTHER INFORMATION Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product. REVISION INFORMATION Version Number 3.2 Revision Date 04/19/2005 Print Date Printed on 04/19/2005. ABBREVIATIONS AP: Approximately EQ: Equal >: Greater Than <: Less Than NA: Not Applicable NO: No Data NE: Not Established ACGIH: American Conference of Governmental Industrial Hygienists IARC: International Agency for Research on Cancer NIOSH: National Institute of Occupational Safety and Health NPCA: National Paint and Coating Manufacturers Association NFPA: National Fire Protection Association AIHA: American Industrial Hygiene Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration HMIS: Hazardous Materials Information System EPA: US Environmental Protection Agency DISCLAIMER OF LIABILITY THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. . * * * . END OF MSDS * * * * * MSDS No. 633133386097 Revision Date 04/19/2005 Page Number: 7 Service Pro Premium SOW-gO Gear Oil Material Safety Data Sheet Association of Independent Oil Distributors P.O. Box 1861 Montrose, CO 81402-1861 MSDS No. 631330386097 Revision Date 04/19/2005 Hazard Rankings HMIS NFPA Health Hazard 0 0 Fire Hazard 1 1 Reactivity 0 0 . = Chronic Health Hazard PROTECTIVE EQUIPMENT Minimum Recommended See Section 8 for Details OC7~t IMPORTANT: Read this MSDS before handling or disposing of this product and ass this information on to em 10 ees, customers and users of this roducl Emergency Overview Physical State Liquid. Color Amber to black. Odor Mild petroleum odor WARNINGI Protect eyes from misting or spraying material. Protect exposed skin from repeated or prolonged exposure. Do not store material in open or unmarked containers. Spills may create a slipping hazard. SECTION 1 : IDENTIFICATION Trade Name Product Number CAS Number Product Family Synonyms Service Pro Premium 80W-90 Gear Oil 631330386097 Mixture. Gear Oil Gear Oil; Service Pro SAP Product Code No.: 631330386097 Technical Contact (800) 313-2463 Medical Emergency (800) 313-2463 CHEMTREC Emergency (United States Only) (800) 424-9300 SECTION 2: COMPOSITION Component Name(s) 1) Distillates, petroleum, hydrotreated heavy paraffinic 2) Distillates, petroleum, solvent-refined heavy paraffinic 3) Residual oils, petroleum, solvent-refined 4) Sulfurized Olefin 5) Proprietary Ingredients CAS Registry No. 64742-54-7 64741-88-4 64742-01-4 Proprietary Proprietary Mixture Concentration (0/0) 0-90 0-60 10 - 40 1-5 0-5 SECTION 3: HAZARDS IDENTIFICATION Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS. Major Route(s) of Entry Skin contact. Signs and Symptoms of Acute Exposure Inhalation No significant adverse health effects are expected to occur upon short-term exposure. Eye Contact Skin Contact This material can cause mild eye irritation from contact with product or product mists. No skin irritation is expected from short-term exposure. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and rash (dermatitis). Ingestion If swallowed, large volumes of material can cause generalized depression, headache, drowsiness, nausea, vomiting and diarrhea. Smaller doses can cause a laxative effect. MSDS No. 631330386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 1 Chronic Health Effects Summary Conditions Aggravated by Exposure Target Organs Carcinogenic Potential Service Pro Premium SOW-go Gear Oil Contains a petroleum-based mineral oil. Prolonged or repeated skin contact can cause mild irritation and inflammation characterized by drying, cracking, (dermatitis) or oil acne. Repeated or prolonged inhalation of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause respiratory irritation or other pulmonary effects. Medical conditions aggravated by exposure to this material may include pre-existing skin disorders. This material may cause damage to the following organs: skin. This product does not contain any components at concentrations above 0.1 % which are considered carcinogenic by OSHA, IARC or NTP. Combustible Flammable Com ressed Gas SECTION 4: FIRST AID MEASURES Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid. For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS. Inhalation Eye Contact Skin Contact Ingestion Notes to Physician Vaporization is not expected at ambient temperatures. This material is not expected to cause inhalation-related disorders under anticipated conditions of use. In case of overexposure, move the person to fresh air. Check for and remove contact lenses. Flush eyes with cool, dean, low-pressure water while occasionally lifting and lowering eyelids. Seek medical attention if excessive tearing, redness, or pain persists. If burned by hot material, cool skin by quenching with large amounts of cool water. Remove contaminated shoes and dothing. Wipe off excess material. Wash exposed skin with mild soap and water. Seek medical attention if tissue appears damaged or if pain or irritation persists. Thoroughly dean contaminated clothing before reuse. Discard contaminated leather goods. If material is injected under the skin, seek medical attention immediately. Do not induce vomiting unless directed to by a physician. Do not give anything to drink unless directed to by a physician. Never give anything by mouth to a person who is not fully conscious. Seek medical attention immediately. The viscosity range of the product(s) represented by this MSDS is greater than 400 SUS at 1OOoF. Accordingly, upon ingestion there is a low risk of aspiration. Careful gastric lavage or emesis may be considered to evacuate large quantities of material. Subcutaneous or intramuscular injection requires prompt surgical debridement. SECTION 5: FIRE FIGHTING MEASURES NFPA Flammability NFPA Class-illS combustible material. Slightly combustible! Classification Flash Point Method CLOSED CUP: 1800C (3560F). (Pensky-Martens [ASTM 0-93]) OPEN CUP: 2140C (417"F) (Cleveland). Lower Flammable Limit Autoignition Temperature Hazardous No data. Upper Flammable Limit No data. Not available. Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons. aldehydes and other MSDS No. 631330386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 2 Service Pro Premium SOW-90 Gear Oil Combustion products of incomplete combustion. Also, depending upon the conditions of use, low concentrations of Products hydrogen sulfide can be released. Special Properties This material will release vapors when heated above the flash point temperature that can ignite when exposed to a source of ignition. In enclosed spaces, vapors can ignite with explosive force. Mists or sprays may bum at temperatures below the flash point. Extinguishing Media Use dry chemical, foam, Carbon Dioxide or water fog. Protection of Fire Fighters Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained breathing apparatus to protect against potential hazardous combustion or decomposition products and oxygen deficiencies. SECTION 6: ACCIDENTAL RELEASE MEASURES Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For more specific information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal Protection in Section 8 and Disposal Considerations in Section 13 of this MSDS. Do not touch damaged containers or spilled material unless wearing appropriate protective equipment. Slipping hazard; do not walk through spilled material. Stop leak if you can do so without risk. For small spills, absorb or cover with dry earth, sand, or other inert non-combustible absorbent material and place into waste containers for later disposal. Contain large spills to maximize product recovery or disposal. Prevent entry into waterways or sewers. In urban area, cleanup spill as soon as possible. In natural environments, seek cleanup advice from specialists to minimize physical habitat damage. This material will float on water. Absorbent pads and similar materials can be used. Comply with all laws and regulation. SECTION 7: HANDLING AND STORAGE Storage Avoid contamination and extreme temperatures to minimize product degradation. Empty containers may contain product residues that can ignite with explosive force. Do not pressurize, cut, weld, braze solder, drill, grind or expose containers to flames, sparks, heat or other potential ignition sources. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers and/or waste residues of this product. Keep container closed. Do not store with strong oxidizing agents. Do not store at temperatures above 1200 F or in direct sunlight for extended periods of time. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers or waste residues of this product. Handling SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION Engineering Controls Provide exhaust ventilation or other engineering controls if airborne mists or vapors concentrations exceed recommended occupational exposure limits listed below. An eye wash station and safety shower should be located near the work-station. Personal Protective Equipment Personal protective equipment should be selected based upon the conditions under which this material is used. A hazard assessment of the work area for PPE requirements should be conducted by a qualified professional pursuant to OSHA regulations. The following pictograms represent the minimum requirements for personal protective equipment. For certain operations, additional PPE may be required. oa~1 Hand Protection Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. Wear goggles and/or face shield if splashing or spraying is anticipated. Wear goggles and face shield if material is heated above 1250F (510C). Have suitable eye wash water available. Use gloves constructed of chemical resistant materials such as neoprene or heavy nitrile rubber if frequent or prolonged contact is expected. Use heat-protective gloves when handling product at elevated temperatures. Eye Protection Body Protection Use clean and impervious protective clothing (e.g., neoprene or Tyvek@) if splashing or spraying conditions are present. Protective clothing may include long-sleeve outer garment, apron, or lab coat. If MSDS No. 631330386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 3 Service Pro Premium SOW-90 Gear Oil significant contact occurs, remove oil-contaminated clothing as soon as possible and promptly shower. Launder contaminated before reuse or discard. Wear heat protective boots and protective clothing when handling material at elevated temperatures. Respiratory Vaporization is not expected at ambient temperatures. Therefore, the need for respiratory protection is Protection not anticipated under normal use conditions and with adequate ventilation. If elevated airborne concentrations above applicable workplace exposure levels are anticipated, a NIOSH-approved organic vapor respirator equipped with a dust/mist prefilter should be used. Protection factors vary depending upon the type of respirator used. Respirators should be used in accordance with OSHA requirements (29 CFR 1910.134). General Comments Use good personal hygiene practices. Wash hands and other exposed skin areas with plenty of mild soap and water before eating, drinking, smoking, use of toilet facilities, or leaving work. DO NOT use gasoline, kerosene, solvents or harsh abrasives as skin cleaners. Since specific exposure standardslcontrollimits have not been established for this product, the "Oil Mist, Mineral" exposure limits shown below are suggested as minimum control guidelines. Occupational Exposure Guidelines Substance 1) Oil Mist, Mineral Applicable Workplace Exposure Levels ACGIH (United States). TWA: 5 mg/m3 STEL: 10 mglm3 OSHA (United States). TWA: 5 mg/m3 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid. Color Amber. Odor Mild petroleum odor Specific Gravity 0.89 (Water = 1) pH Not Applicable. Vapor Density >10 (Air = 1) Boiling Point/Range Not available. Melting/Freezing Not available, Point Vapor Pressure <0.001 kPa (<0.01 mmHg) (at 20.C). Viscosity (cSt @ 400C) 142. Solubility in Water Insoluble in cold water. Volatile Characteristics Negligible volatility Additional Properties Gravity, GAPI (ASTM D287) = 26.7 @ 60" F Density = 7.45 Lbslgal Viscosity (ASTM D2161) = AP 710 SUS @ 100" F SECTION 10: STABILITY AND REACTIVITY Chemical Stability Stable. Hazardous polymerization Not expected to occur Conditions to Avoid Keep away from extreme heat, sparks, open flame, and strongly oxidizing conditions. Materials Incompatibility Oxidizing materials. Hazardous Decomposition Products No additional hazardous decomposition products were identified other than the combustion products identified in Section 5 of this MSDS. SECTION 11: TOXICOLOGICAL INFORMATION For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification in Section 3 of this MSDS. Toxicity Data Distillates, petroleum, hydrotreated heavy paraffinic: ORAL (LD50): Acute: >5000 mglkg [Rat]. DERMAL (LD50): Acute: >2000 mglkg [Rabbit]. MSDS No. 631330386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 4 Service Pro Premium 80W-90 Gear Oil Distillates, petroleum, solvent-refined heavy paraffinic: ORAL (LD50): Acute: >5000 mg/kg [Rat). DERMAL (LD50): Acute: >2000 mglkg [Rabbit]. Residual Oils, petroleum, solvent-refined: ORAL (LD50): Acute: >5000 mg/kg [Rat]. DERMAL (LD50): Acute: >2000 mglkg [Rabbit]. Distillates, petroleum, hydrotreated heavy paraffinic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable \NOrkplace exposure levels indude lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current \NOrk place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested. Distillates, petroleum, solvent-refined heavy paraffinic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable \NOrkplace exposure levels indude lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current \NOrk place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested. Analyses conducted by method IP 346 indicate that the polycydic aromatic concentration of this mineral oil is below 3.0 weight percent. Residual Oils, petroleum, solvent-refined: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable \NOrkplace exposure levels indude lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current \NOrk place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested. SECTION 12: ECOLOGICAL INFORMATION Ecotoxiclty Analysis for ecological effects has not been conducted on this product. However, if spilled, this product and any contaminated soil or water may be harmful to human, animal, and aquatic life. Also, the coating action associated with petroleum and petroleum products can be harmful or fatal to aquatic life and waterfowl. Environmental Fate An environmental fate analysis has not been conducted on this specific product. Plants and animals may experience harmful or fatal effects when coated with petroleum-based products. Petroleum-based (mineral) lube oils will normally float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway may be sufficient to cause a fish kill or create an anaerobic environment. SECTION 13: DISPOSAL CONSIDERATIONS Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent materials and residues at the time of disposition. Conditions of use may cause this material to become a "hazardous waste", as defined by federal or state regulations. It is the responsibility of the user to determine if the material is a RCRA "hazardous waste" at the time of disposal. Transportation, treatment, storage and disposal of waste material must be conducted in accordance with RCRA regulations (see 40 CFR 260 through 40 CFR 271). State and/or local regulations may be more restrictive. Contact the RCRAlSuperfund Hotline at (800) 424-9346 or your regional US EPA office for guidance concerning case specific disposal issues. SECTION 14: TRANSPORT INFORMATION DOT Status Not a U.S. Department of Transportation regulated material. Proper Shipping Not regulated. Hazard Class Not regulated. MSDS No. 631330386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 5 Name Packing Group(s) Reportable Quantity Placards HAZMAT STCC No. MARPOL III Status Service Pro Premium SOW-90 Gear Oil Not applicable. UN/NA 10 Not available. A Reportable Quantity (RQ) has not been established for any components of this material. ~ Emergency Response Guide No. Not applicable. Not available. SECTION 15: REGULATORY INFORMATION Not a DOT "Marine Pollutant" per 49 CFR 171.8. TSCA Inventory SARA 3021304 SARA 311/312 SARA 313 CERCLA CWA California Proposition 65 This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory. The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to Subparts 302 and 304 to submit emergency planning and notification information based on Threshold Planning Quantities (TPQs) and Reportable Quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355. No components were identified. The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to this subpart to submit aggregate information on chemicals by "Hazard Category" as defined in 40 CFR 370.2. This material would be dassified under the following hazard categories: No SARA 311/312 hazard categories identified. This product contains the following components in concentrations above de minimis levels that are listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section 313 of SARA: No components were identified. The Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) requires notification of the National Response Center concerning release of quantities of "hazardous substances" equal to or greater than the reportable quantities (RQs) listed in 40 CFR 302.4. As defined by CERCLA, the term "hazardous substance" does not indude petroleum, induding crude oil or any fraction thereof which is not otherwise specifically designated in 40 CFR 302.4. Chemical substances present in this product or refinery stream that may be subject to this statute are: None identified. This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. This material may contain the following components which are known to the State of California to cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): Toluene: 0.001%; Ethyl Acrylate: 0.0007%. Petroleum Oil (Gear Oil) New Jersey Right-to-Know Label Additional Regulatory Remarks No additional regulatory remarks. SECTION 16: OTHER INFORMATION Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product REVISION INFORMATION Version Number Revision Date 2.2 04/19/2005 MSDS No. 631330386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 6 Service Pro Premium BOW-go Gear Oil Print Date Printed on 04119/2005. ABBREVIATIONS AP: Approximately EO: Equal >: Greater Than <: Less Than ACGIH: American Conference of Govemmentallndustrial Hygienists IARC: Intemational Agency for Research on Cancer NIOSH: National Institute of Occupational Safety and Health NPCA: National Paint and Coating Manufacturers Association NFPA: National Fire Protection Association NA: Not Applicable NO: No Data NE: Not Established AIHA: American Industrial Hygiene Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration HMIS: Hazardous Materials Information System EPA: US Environmental Protection Agency DISCLAIMER OF LIABILITY THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE, HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. * * * . * END OF MSDS . * * * * MSDS No. 631330386097 Revision Date 04119/2005 Page Number: 7 MSDS Number: SP4012 f' ..NU., Page 1 of 4 Revision Date: 06/23/04 MSDS ~oiter;al Safety Data Sheet SERVICE PRO PENETRANT SP 4012 _ PRODUCT AND COMPANY IDENTIFICATION Manufacturer AIOD ASSOCIATION OF INDEPENDENT OIL DISTRIBUTORS 700 S. CASCADE MONTROSE, CO 81401 Contact: Telephone Number: (970) 249-6336 FAX Number: (970) 240-4131 E-Mail: Web product Name: SERVICE PRO PENETRANT SP 4012 Revision Date: 06/23/04 MSDS Number: SP4012 Common Name: AEROSOL PENETRANT CONTAINING PETROLEUM DISTILLATES EMERGENCY PHONE NUMBER (800) 752-7869 NFPA 704M RATING: HEAL TH:1 FIRE:2 REACTIVITY: 0 SPECIAL: O=INSIGNIFICANT 1=SLlGHT 2=MODERATE 3=HIGH 4=EXTREME COMPOSITION/INFORMA TION ON INGREDIENTS INGREDIENT MINERAL SPIRITS HYDROTREATED LIGHT PETROLEUM DISTILLATES PROPANE-ISOBUTANE-n-BUTANE SOLVENT DEWAXED HEAVY NAPHTHENIC DISTILLATE CAS NUMBER 64741-88-4 64742-47-8 68476-86-8 64742-63-8 PERCENT WEIGHT 30-40 % 30-40 % 10-20 % 6-8 % _ HAZARDS IDENTIFICATION Route of Entry: Skin absorption and inhalation Target Organs: Lungs, kidneys, liver and nervous system. Inhalation: Respiratory irritation and dizziness Skin Contact: Prolonged contact with skin can cause irritation. Repeated skin contact may cause persistent irritation and dermatitis Eye Contact: Will cause irritation upon contact. Ingestion: Product may cause discomfort, nausea,vomiting and diarrhea. CARCINOGENICITY: Product is not considered a carcinogen by OSHA, NTP or IARC. MEDICAL CONDITIONS: Pre-existing eye or skin conditions may be aggravated by over-exposure to this product. MSDS~J'oterial Safety Data Sheet SERVICE PRO PENETRANT SP 4012 " NNIlAY Page 2 of 4 Revision Date: 06/23/04 MSDS Number: SP4012 _ FIRST AID MEASURES Inhalation: Remove to fresh air. If not breathing, give artificial respiration. Seek medical attention. Inhalation hazard unlikely due to low volatility of product. Wash area with soap and water. seek medical attention if irritation persists Immediately flush eyes with plenty of water for 15 minutes. Seek medical attention. DO NOT induce vomiting. Only give CONSCIOUS victim two glasses of water and seek medical attention. NEVER give UNCONSCIOUS anything by mouth. Skin Contact: Eye Contact: Ingestion: _ FIRE FIGHTING MEASURES Flash point: 110 F Flash point Method: TCC other: EXTINGUISHING MEDIA: carbon Dioxide ( co2) Dry chemical, Foam.UNUSUAL FIRE AND EXPLOSION HAZARDS: vapors are heavier than air and can collect in low areasFIRE FIGHTING INSTRUCTIONS: containers can build up pressure if exposed to fire. containers should be cooled with water supply. FIRE FIGHTING EQUIPMENT: self- contained breathing apparatus with full face piece operated in positive pressure mode. ACCIDENTAL RELEASE MEASURES SPILLlLEAK PROCEDURES: Notify safety personnel ,evacuate all unnecessary personnel and provide adequate ventilation. If feasible, and without risk,c1ean-up personnel should stop leak. All clean up personnel should wear proper personal protective equipment. SMALL SPILLS:Clean with inert absorbent and place in recovery drums for disposal. LARGE SPILLS: Dike to prevent further migration of material. DO NOT release into waterways or sewers. Follow applicable federal and state regulations. _ HANDLING AND STORAGE Handling Precautions: Wash thoroughly after handling. Do not get into eyes, on skin or on clothing.. Do not smoke while using this product.Do not use near excessive heat, sparks, or open flame. Storage Requirements: Store in clean, dry locations away from excessive heat. Store in areas designated for the storage of Levell! aerosols according to NFPA 30B ( Manufacturing and Storage of Aerosol Products.) EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Eye wash station and safety shower. General ventilation. Material non - volatile Protective Equipment: EYE: Chemical splash goggles with indirect or no ventilation. SKIN :Chemical resistant gloves, such as nitrile. RESPIRATORY: Organic vapor air purifying respiator if vapors are a nuisance or if the concentrations are above PEL or TLV. Never eat, drink or smoke in work area MSDS ~J'oterial Safety Data Sheet SERVICE PRO PENETRANT SP 4012 " NNIlM' MSDS Number: SP4012 _ PHYSICAL AND CHEMICAL PROPERTIES Page 3 of 4 Revision Date: 06/23/04 Appearance: Physical State: Odor: pH: Vapor Pressure: Vapor Density: amber colored liquid petroleum distillate BT 0.80-2.0 mmHG >4.8 Boiling Point: BT 390-424 F FreezinglMelting Pt.: Solubility: Not soluble in water Spec GravJDensity: 0.8085 _ STABILITY AND REACTIVITY Stability: Material is stable. Conditions to avoid: Materials to avoid (incompatabillty): Hazardous Decomposition products: Hazardous polymerization: Excessive heat and open flame. Strong oxidizing agents. Carbon Monoxide and Carbon Dioxide Cannot occur. _ TOXICOLOGICAL INFORMATION NO DATA _ ECOLOGICAL INFORMATION No data. _ DISPOSAL CONSIDERATIONS Dispose of in accordance with all applicable state, federal and local regulations. _ TRANSPORT INFORMATION DOMESTIC: CONSUMER COMMODITY ORM-D EXPORT: AEROSOL DISPENSERS, CLASS 2.1 UN1950, LIMITED QUANTITY MSDS ~~terial Safety Data Sheet SERVICE PRO PENETRANT SP 4012 " "'NIlM' Page 4 of 4 Revision Date: 06/23/04 MSDS Number: SP4012 _ REGULATORY INFORMATION U.S. FEDERAL REGULATIONS OSHA: considered to be a hazardous material as defined by 29CFR1910.1200 EPA SARA TITLE III section 311-312 (40CFR370): If stored in excess of the threshold quantities, this product should be reported as a(n): IMMEDIATE (acute) HEALTH HAZARD DELAYED (chronic) HEALTH HAZARD FIRE HAZARD section 313(40CFR372) This product contains ingredients which are subject to the reporting requirements of SARA 313: NONE _ OTHER INFORMATION CALIFORNIA PROPOSITION 65: This prodUct does not contain ingredients which are on the current Proposition 65 list. Notes: NG= NOT GIVEN BT= BETWEEN <= LESS THAN >= GREATER THAN USERS RESPONSIBILlTY;This MSDS provides environmental, health and safety information. This product is to be used in applications consistent with our product literature and container label. Individuals handling this product should be informed to the recommended safety precautions and have access to this MSDS. Please contact your local sales representative ot our EH&S Department for further information. END OF MSDS END OF MSDS DOCUMENT MSDSf1J'oterial Safety Data Sheet SERVICE PRO ENGINE CLEANER AND DEGREASER--SP4220 MSDS Number: SP4220 " ".IIM' Page 1 of 4 Revision Date: 06/23/04 _ PRODUCT AND COMPANY IDENTIFICATION Manufacturer AIOD ASSOCIATION OF INDEPENDENT OIL DISTRIBUTORS 700 S. CASCADE MONTROSE, CO 81401 Contact: Telephone Number: (970) 249-6336 FAX Number: (970) 240-4131 E-Mail: Web product Name: SERVICE PRO ENGINE CLEANER AND DEGREASER--SP4220 Revision Date: 06/23/04 MSDS Number: SP4220 Common Name: AEROSOL ENGINE CLEANER AND DEGREASER CONTAINING KEROSENE EMERGENCY PHONE NUMBER (800) 752-7869 NFPA 704M RATING: HEAL TH:1 FIRE:3 REACTIVITY: 0 SPECIAL: O=INSIGNIFICANT 1=SLlGHT 2=MODERATE 3=HIGH 4=EXTREME COMPOSITION/INFORMA TION ON INGREDIENTS INGREDIENT KEROSENE 2-BUTOXYETHANOL 9016-45-5 PROPANE-ISOBUTANE-N-BUTANE WATER CAS NUMBER 8008-20-6 111-76-2 5-15% 68476-86-8 7732-18-5 PERCENT WEIGHT 15-25% 2-4% NONYL PHENOL ETHOXYLATE 12-18% 46-56% _ HAZARDS IDENTIFICATION Route of Entry: Skin absorption and inhalation Target Organs: Lungs, kidneys, liver and nervous system. Inhalation: Respiratory irritation and dizziness Skin Contact: Prolonged contact with skin can cause irritation. Repeated skin contact may cause persistent irritation and dermatitis Will cause irritation upon contact. Product may cause discomfort, nausea,vomiting and diarrhea. Eye Contact: Ingestion: CARCINOGENICITY: Product is not considered a carcinogen by OSHA. NTP or IARC. MEDICAL CONDITIONS: Pre-existing eye or skin conditions may be aggravated by over-exposure to this product. MSDS~toterial Safety Data Sheet SERVICE PRO ENGINE CLEANER AND DEGREASER--SP4220 MSDS Number: SP4220 _ FIRST AID MEASURES Inhalation: Remove to fresh air. If not breathing, give artificial respiration. Seek medical attention. Inhalation hazard unlikely due to low volatility of product. Wash area with soap and water. seek medical attention if irritation persists Immediately flush eyes with plenty of water for 15 minutes. Seek medical attention. DO NOT induce vomiting. Only give CONSCIOUS victim two glasses of water and seek medical attention. NEVER give UNCONSCIOUS anything by mouth. " PlNIlA" Page 2 of 4 Revision Date: 06/23/04 Skin Contact: Eye Contact: Ingestion: _ FIRE FIGHTING MEASURES Flash point: 120-200 F Flash point Method: TCC other: EXTINGUISHING MEDIA: carbon Dioxide ( C02) Dry chemical, Foam.UNUSUAL FIRE AND EXPLOSION HAZARDS: vapors are heavier than air and can collect in low areas FIRE FIGHTING INSTRUCTIONS: Containers can build up pressure if exposed to fire. containers should be cooled with water supply. FIRE FIGHTING EQUIPMENT: self- contained breathing apparatus with full face piece operated in positive pressure mode. _ ACCIDENTAL RELEASE MEASURES SPILLlLEAK PROCEDURES: Notify safety personnel ,evacuate all unnecessary personnel and provide adequate ventilation. If feasible, and without risk,clean-up personnel should stop leak. All dean up personnel should wear proper personal protective equipment. SMALL SPILLS:Clean with inert absorbent and place in recovery drums for disposal. LARGE SPILLS: Dike to prevent further migration of material. 00 NOT release into waterways or sewers. Follow applicable federal and state regulations. _ HANDLING AND STORAGE Handling Precautions: Wash thoroughly after handling. Do not get into eyes, on skin or on clothing.. Do not smoke while using this product.Do not use near excessive heat, sparks, or open flame. Storage Requirements: Store in clean, dry locations away from excessive heat. Store in areas designated for the storage of Level II aerosols according to NFPA 30B ( Manufacturing and Storage of Aerosol Products.) EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Eye wash station and safety shower. Strong general ventilation or local exhaust. Protective Equipment: EYE: Chemical splash goggles with indirect or no ventilation. SKIN :Chemical resistant gloves, such as nitrile. RESPIRATORY: Organic vapor air purifying respiator if vapors are a nuisance or if the concentrations are above PEL or TLV. Never eat, drink or smoke in work area MSDS Wtoterial Safety Data Sheet SERVICE PRO ENGINE CLEANER AND DEGREASER--SP4220 MSDS Number: SP4220 _ PHYSICAL AND CHEMICAL PROPERTIES " "NItA\' Page 3 of 4 Revision Date: 06/23/04 Appearance: Physical State: Odor: pH: Vapor Pressure: Vapor Density: Colorless liquid liquid petroleum distillate BT 0.4-5.0 mmHG BT 4.5 - 6.2 Boiling Point: BT 220-440 F FreezingJMelting Pt.: Solubility: Not soluble in water Spec Grav./Density: BT 0..820-0.825 VOC: <45 % Evap. Rate: >1.0 _ STABILITY AND REACTIVITY Stability: Material is stable. Conditions to avoid: Materials to avoid (incompatability): Hazardous Decomposition products: Hazardous Polymerization: Excessive heat and open flame. Strong oxidizing agents. Carbon Monoxide and Carbon Dioxide Cannot occur. _ TOXICOLOGICAL INFORMATION LD50 KEROSENE 28 mljkg (oral) _ ECOLOGICAL INFORMATION No data. _ DISPOSAL CONSIDERATIONS Dispose of in accordance with all applicable state, federal and local regulations. _ TRANSPORT INFORMATION DOMESTIC: CONSUMER COMMODITY ORM-D EXPORT: AEROSOL DISPENSERS, CLASS 2.1 UN1950, IMCO 9.0, pAGE 9022 MSDS ~J'oter;al Safety Data Sheet SERVICE PRO ENGINE CLEANER AND DEGREASER--SP4220 MSDS Number: SP4220 _ REGULATORY INFORMATION u.s. FEDERAL REGULATIONS OSHA: considered to be a hazardous material as defined by 29CFR1910.1200 EPA SARA TITLE III section 311-312 (40CFR370): If stored in excess of the threshold quantities, this product should be reported as a(n): IMMEDIATE (acute) HEALTH HAZARD DELAYED (chronic) HEALTH HAZARD FIRE HAZARD SUDDEN RELEASE HAZARD f' "NIlA\' Page 4 of 4 Revision Date: 06/23/04 section 313(40CFR372) This product contains ingredients which are subject to the reporting requirements of SARA 313: 2-Butoxyethanol _ OTHER INFORMATION CALIFORNIA PROPOSITION 65: This product does not contain ingredients which are on the current Proposition 65 list. Notes: NG= NOT GIVEN BT= BETWEEN <= LESS THAN >= GREATER THAN USERS RESPONSIBILlTY;This MSDS provides environmental, health and safety information. This product is to be used in applications consistent with our product literature and container label. Individuals handling this product should be informed to the recommended safety precautions and have access to this MSDS. Please contact your local sales representative ot our EH&S Department for further information. END OF MSDS END OF MSDS DOCUMENT Service Pro Premium Motor Oil, SAE 5W-30 Material Safety Data Sheet Association of Independent Oil Distributors P.O. Box 1861 Montrose, CO 81402-1861 MSDS No. 620805386097 Revision Date 04/19/2005 Hazard Rankings IMPORTANT: Read this MSDS before handling or disposing of this product and pass this information on to employees. customers and users of this product. Emergency Overview Liquid. Dark amber to black. Odor Mild petroleum odor HMIS Health Hazard 0 Fire Hazard 1 Reactivity 0 NFPA o 1 o Physical State Color . = Chronic Health Hazard CAUTION: Hot oil can cause thermal burns on contact. "Used" motor oil has been associated with skin cancer in laboratory animals following extended contact. Spills may create a slipping hazard. PROTECTIVE EQUIPMENT Minimum Recommended See Section 8 for Details uo~1 SECTION 1 : IDENTIFICATION Trade Name Product Number CAS Number Product Family Synonyms Service Pro Premium Motor Oil, SAE 5W-30 620805386097 Mixture. Motor oil Heavy duty motor oil; Service Pro SAP Product Code No.: 620805386097 Technical Contact (800) 313-2463 Medical Emergency (800) 313-2463 CHEMTREC Emergency (United States Only) (800) 424-9300 SECTION 2: COMPOSITION Component Name(s) 1) Distillates, petroleum, hydrotreated heavy paraffinic 2) Distillates, petroleum, solvent-refined heavy paraffinic 3) Proprietary Ingredients 4) Zinc alkyldithiophosphate CAS Registry No. 64742-54-7 64741-88-4 Proprietary Mixture 68649-42-3 Concentration (%) 70 - 90 5 - 30 0-10 0-1 SECTION 3: HAZARDS IDENTIFICATION Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS. Major Route(s) of Entry Skin contact. Signs and Symptoms of Acute Exposure Inhalation No significant adverse health effects are expected to occur upon short-term exposure. Eye Contact This product can cause transient mild eye irritation with short-term contact with liquid sprays or mists. Skin Contact This product can cause mild, transient skin irritation with short-term exposure. Skin contact with hot material may result in severe burns. Ingestion If swallowed, large volumes of material can cause generalized depression, headache, drowsiness, nausea, vomiting and diarrhea. Smaller doses can cause a laxative effect. If aspirated into the lungs, liquid can cause lung damage. MSDS No. 620805386097 Revision Date 04119/2005 Continued on Next Page Page Number: 1 Chronic Health Effects Summary Conditions Aggravated by Exposure Target Organs Carcinogenic Potential Service Pro Premium Motor Oil, SAE 5W-30 Contains a petroleum-based mineral oil. Prolonged or repeated skin contact can cause mild irritation and inflammation characterized by drying, cracking, (dermatitis) or oil acne. Repeated or prolonged inhalation of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause respiratory irritation or other pulmonary effects. Medical conditions aggravated by exposure to this material may include pre-existing skin disorders. This material may cause damage to the following organs: skin. This product does not contain any components at concentrations above 0.1% which are considered carcinogenic by OSHA, IARC or NTP. o o o SECTION 4: FIRST AID MEASURES Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid. For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS. Inhalation Eye Contact Skin Contact Ingestion Notes to Physician Vaporization is not expected at ambient temperatures. This material is not expected to cause inhalation-related disorders under anticipated conditions of use. In case of overexposure, move the person to fresh air. Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water while occasionally lifting and lowering eyelids. Seek medical attention if excessive tearing, redness, or pain persists. If burned by hot material, cool skin by quenching with large amounts of cool water. Remove contaminated shoes and clothing. Wipe off excess material. Wash exposed skin with mild soap and water. Seek medical attention if tissue appears damaged or if pain or irritation persists. Thoroughly clean contaminated clothing before reuse. Discard contaminated leather goods. If material is injected under the skin, seek medical attention immediately. Do not induce vomiting unless directed to by a physician. Do not give anything to drink unless directed to by a physician. Never give anything by mouth to a person who is not fully conscious. Seek medical attention immediately. The viscosity range of the product represented by this MSDS is 100 to 400 SUS at 100. F. Accordingly, upon ingestion there is a low risk of aspiration. Careful gastric lavage or emesis may be considered to evacuate large quantities of material. Subcutaneous or intramuscular injection requires prompt surgical debridement. SECTION 5: FIRE FIGHTING MEASURES NFPA Flammability NFPA Class-illS combustible material. Slightly combustible! Classification Flash Point Method OPEN CUP: 233.C (451.F) (Cleveland). Lower Flammable Limit Autoignition Temperature No data. Upper Flammable Limit No data. Not available. MSDS No. 620805386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 2 Hazardous Combustion Products Special Properties Service Pro Premium Motor Oil, SAE 5W-30 Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and trace oxides of sulfur, phosphorus, zinc and/or nitrogen. This material can burn but will not readily ignite. This material will release vapors when heated above the flash point temperature that can ignite when exposed to a source of ignition. In enclosed spaces, heated vapor can ignite with explosive force. Mists or sprays may bum at temperatures below the flash point. Extinguishing Media Use dry chemical, foam, Carbon Dioxide or water fog. Protection of Fire Fighters Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained breathing apparatus to protect against potential hazardous combustion or decomposition products and oxygen deficiencies. SECTION 6: ACCIDENTAL RELEASE MEASURES Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For more specific information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal Protection In Section 8 and Disposal Considerations in Section 13 of this MSDS. Do not touch damaged containers or spilled material unless wearing appropriate protective equipment. Slipping hazard; do not walk through spilled material. Stop leak if you can do so without risk. For small spills, absorb or cover with dry earth, sand, or other inert non-combustible absorbent material and place into waste containers for later disposal. Contain large spills to maximize product recovery or disposal. Prevent entry into waterways or sewers. In urban area, cleanup spill as soon as possible. In natural environments, seek cleanup advice from specialists to minimize physical habitat damage. This material will float on water. Absorbent pads and similar materials can be used. Comply with all laws and regulations. Handling SECTION 7: HANDLING AND STORAGE Storage Avoid contamination and extreme temperatures to minimize product degradation. Empty containers may contain product residues that can ignite with explosive force. Do not pressurize, cut, weld, braze solder, drill, grind or expose containers to flames, sparks, heat or other potential ignition sources. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers and/or waste residues of this product. Keep container closed. Do not store with strong oxidizing agents. Do not store at temperatures above 120. F or in direct sunlight for extended periods of time. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers or waste residues of this product. SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists andlor vapors below the recommended exposure limits (see below). An eye wash station and safety shower should be located near the work-station. Personal Protective Equipment Eye Protection Hand Protection Personal protective equipment should be selected based upon the conditions under which this material is used. A hazard assessment of the work area for PPE requirements should be conducted by a qualified professional pursuant to OSHA regulations. The following pictograms represent the minimum requirements for personal protective equipment. For certain operations, additional PPE may be required. ua01 Wear goggles and/or face shield if splashing or spraying is anticipated. Wear goggles and face shield if material is heated above 125.F (51.C). Have suitable eye wash water available. Use gloves constructed of chemical resistant materials such as neoprene or heavy nitrile rubber if frequent or prolonged contact is expected. Use heat-protective gloves when handling product at elevated temperatures. MSDS No. 620805386097 Revision Date 04119/2005 Continued on Next Page Page Number: 3 Service Pro Premium Motor Oil, SAE 5W-30 Body Protection Avoid prolonged and/or repeated skin contact. Use clean and impervious protective clothing (e.g., neoprene or Tyveklll>) if splashing or spraying conditions are present. Protective clothing should include long-sleeves, apron, boots and additional facial protection. Remove oil contaminated clothing. Launder oil contaminated clothing before reusing. Contaminated leather goods should be removed promptly and discarded. Respiratory Vaporization is not expected at ambient temperatures. Therefore, the need for respiratory protection is Protection not anticipated under normal use conditions and with adequate ventilation. If elevated airborne concentrations above applicable workplace exposure levels are anticipated, a NIOSH-approved organic vapor respirator equipped with a dust/mist prefilter should be used. Protection factors vary depending upon the type of respirator used. Respirators should be used in accordance with OSHA requirements (29 CFR 1910.134). General Comments Use good personal hygiene practices. Wash hands and other exposed skin areas with plenty of mild soap and water before eating, drinking, smoking, use of toilet facilities, or leaving work. DO NOT use gasoline, kerosene, solvents or harsh abrasives as skin cleaners. Since specific exposure standards/control limits have not been established for this product, the "Oil Mist, Mineral" exposure limits shown below are suggested as minimum control guidelines. Occupational Exposure Guidelines Substance 1) Oil Mist, Mineral Applicable Workplace Exposure Levels ACGIH (United States). TWA: 5 mglm3 STEL: 10 mglm3 OSHA (United States). TWA: 5 mg/m3 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid. Color Dark amber to black. Odor Mild petroleum odor Specific Gravity 0.865 (Water = 1) pH Not Applicable. Vapor >1 (Air = 1) Density Boiling PointlRange Not available. Melting/Freezing Not available. Point Vapor Pressure <0.001 kPa (<0.01mmHg) (at 20.C) Viscosity (cSt @ 400C) 64 Volatile Negligible volatility Characteristics Solubility in Water Insoluble in cold water. Additional Properties Gravity, oAPI (ASTM D287) = 32.0 @ 000 F Density = 7.21 Lbs/gal. Viscosity (ASTM D2161) = 223 SUS @ 100" F SECTION 10: STABILITY AND REACTIVITY Chemical Stability Stable. Hazardous Polymerization Not expected to occur Conditions to A void Keep away from extreme heat, sparks, open flame, and strongly oxidizing conditions. Materials Incompatibility Strong oxidizers. Hazardous Decomposition Products No additional hazardous decomposition products were identified other than the combustion products identified in Section 5 of this MSDS. MSDS No. 620805386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 4 Service Pro Premium Motor Oil, SAE 5W-30 SECTION 11: TOXICOLOGICAL INFORMATION For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification in Section 3 of this MSDS. Toxicity Data Distillates, petroleum, hydrotreated heavy paraffinic: ORAL (LD5O): Acute: >5000 mg/kg [Rat]. DERMAL (LD5O): Acute: >2000 mg/kg [Rabbit}. Distillates, petroleum, solvent-refined heavy paraffinic: ORAL (LD5O): Acute: >5000 mglkg [Rat]. DERMAL (LD50): Acute: >2000 mglkg [Rabbit}. Distillates, petroleum, hydrotreated heavy paraffinic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested. Distillates, petroleum, solvent-refined heavy paraffinic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested. Analyses conducted by method IP 346 indicate that the polycyclic aromatic concentration of this mineral oil is below 3.0 weight percent. Motor Oils: Used motor oil was associated with cancer in lifetime skin painting studies with laboratory animals. Avoid prolonged or repeated contact with used motor oil. Use of good hygiene practices will reduce the likelihood of potential health effects. SECTION 12: ECOLOGICAL INFORMATION Environmental Fate Analysis for ecological effects has not been conducted on this product. However, if spilled, this product, its storage tank water bottoms and sludge, and any contaminated soil or water may be hazardous to human, animal, and aquatic life. Also, the coating action associated with this product can be harmful or fatal to aquatic life and waterfowl. An environmental fate analysis has not been conducted on this specific product. Plants and animals may experience harmful or fatal effects when coated with petroleum-based products. Petroleum-based (mineral) lube oils will normally float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway can result in a loss of marine life or create an anaerobic environment. This material contains phosphorus which is a controlled element for disposal in effluent waters in most sections of North America. Phosphorus is known to enhance the formation of algae. Severe algae growth can reduce oxygen content in the water possibly below levels necessary to support marine life. Ecotoxicity SECTION 13: DISPOSAL CONSIDERATIONS Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent materials and residues at the time of disposition. Conditions of use may cause this material to become a "hazardous waste", as defined by federal or state regulations. It is the responsibility of the user to determine if the material is a RCRA "hazardous waste" at the time of disposal. Transportation, treatment, storage and disposal of waste material must be conducted in accordance with RCRA regulations (see 40 CFR 260 through 40 CFR 271). State and/or local regulations may be more restrictive. Contact the RCRAlSuperfund Hotline at (800) 424-9346 or your regional US EPA office for guidance concerning case specific disposal issues. SECTION 14: TRANSPORT INFORMATION MSDS No. 620805386097 Revision Date 0411912005 Continued on Next Page Page Number: 5 DOT Status Proper Shipping Name Hazard Class Packing Group(s) UN/NA ID Reportable Quantity Placards HAZMAT STCC No. MARPOL III Status Service Pro Premium Motor Oil, SAE 5W-30 Not a U.S. Department of Transportation regulated material. Not regulated. Not regulated. Not applicable. Not regulated. A Reportable Quantity (RQ) has not been established for any components of this material. ~ Emergency Response Guide No. Not applicable, Not assigned. Not a DOT "Marine Pollutant" per 49 CFR 171.8. SECTION 15: REGULATORY INFORMATION TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory. SARA 3021304 SARA 311/312 SARA 313 CERCLA CWA California Proposition 65 New Jersey Right-to-Know Label The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to Subparts 302 and 304 to submit emergency planning and notification information based on Threshold Planning Quantities (TPQs) and Reportable Quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355. No components were identified, The Superfund Amendments and Reauthorization Ad of 1986 (SARA) Title III requires facilities subject to this subpart to submit aggregate information on chemicals by "Hazard Category" as defined in 40 CFR 370.2. This material would be classified under the following hazard categories: No SARA 311/312 hazard categories identified. This product contains the following components in concentrations above de minimis levels that are listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section 313 of SARA: no components were identified. The Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) requires notification of the National Response Center concerning release of quantities of "hazardous substances" equal to or greater than the reportable quantities (RQs) listed in 40 CFR 302.4. As defined by CERCLA, the term "hazardous substance" does not include petroleum, including crude oil or any fraction thereof which is not otherwise specifically designated in 40 CFR 302.4. Chemical substances present in this product or refinery stream that may be subject to this statute are: Zinc and Zinc Compounds, Concentration: 0 -1%. This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. This material may contain the following components which are known to the State of California to cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): Toluene: 0.0001%. Motor oil Additional Regulatory Remarks No additional regulatory remarks. MSDS No. 620805386097 Revision Date 04119/2005 Continued on Next Page Page Number: 6 Service Pro Premium Motor Oil, SAE 5W-30 SECTION 16: OTHER INFORMATION Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product. REVISION INFORMATION Version Number 3.1 Revision Date 04/19/2005 Print Date Printed on 04/19/2005. ABBREVIATIONS AP: Approximately EQ: Equal >: Greater Than <: Less Than NA: Not Applicable NO: No Data NE: Not Established ACGIH: American Conference of Govemmentallndustrial Hygienists IARC: Intemational Agency for Research on Cancer NIOSH: National Institute of Occupational Safety and Health NPCA: National Paint and Coating Manufacturers Association NFPA: National Fire Protection Association AIHA: American Industrial Hygiene Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration HMIS: Hazardous Materials Information System EPA: US Environmental Protection Agency DISCLAIMER OF LIABILITY THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. * * * * * END OF MSDS * * * * * MSDS No. 620805386097 Revision Date 04/19/2005 Page Number: 7 ZEP Manufacturing Company Acuity Specialty Products Group, Inc. P,O. Box 2015 Atlanta, GA 30301 @ 1-877-I-BlN-ZEP (428-9937) www.zep.com PRIOR LAKE TRANSMISSION 16783 TORONTO AVE SE PRIOR LAKE MN 55372 Section 1. Chemical Product and Company Identification Product name FLASH Product Use Concrete Cleaner Product Code 0723 Date of issue 11/09/05 Supersedes 08/02/04 Emergency For MSDS Information: Telephone Acuity Specialty Products Group, Inc. Numbers Compliance Services 1-877-I-BUY-ZEP (428-9937) For Medical Emergency INFOTRAC: (877) 541-2016 Toll Free - All Calls Recorded Printing date: 02/06/07 For a Transportation Emergency CHEMTREC: (800) 424-9300 - All Calls Recorded In the District of Columbia (202) 483-7616 Prepared by Compliance Services Group Acuity Specialty Products Group 1420 Seaboard Industrial Blvd. Atlanta, GA 30318 Section 2. Composition, Information on Ingredients Name of Hazardous Ingredients CAS # SODIUM METASILICATE; silicic acid (H2-Si-03) disodium salt; water 6834-92-0 glass SODIUM CARBONATE; soda ash; carbonic acid. disodium salt 497-19-8 5 - 15 Exposure Limits ACGIH TLV (United States). TW A: 10 mg/m' 8 hour(s), Form: Dust OSHA PEL (United States). : 15 mg/m' Form: Dust ACGIH (United States). : 15 mg/m' Form: Dust OSHA PEL (United States). TWA: 15 mg/mJ 8 hour(s). Fonn: Total dust ACGrn TLV (United States). TW A: 10 mg/m' 8 hour(s). Form: Inhalable TWA: 3 mg/mJ 8 hour(s). Form: Respirable OSHA PEL (United States). TWA: 15 mg/mJ 8 hour(s). Form: Total dust TW A: 5 mg/m3 8 hour(s). Form: Respirable % by Weight 70 - 80 TRISODIUM ORTHOPHOSPHATE; TSP; phosphoric acid, trisodium 10101-89-0 salt; sodium phosphate, tribasic <5 Section 3. Hazards Identification Acute Effects Routes of Entry Dermal contact. Skin Skin contact may produce burns. The amount of tissue damage depends on length of contact. Skin inflammation is characterized by itching. scaling, or reddening. Eyes Corrosive to eyes. Direct contact with the eyes can cause irreversible damage including Personal Protection D,q blindness. Inhalation A void breathing dust. Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Ingestion May be harmful if swallowed. May cause burns to mouth, throat and stomach. NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse health effects are lessened by following all prescribed safety precautions, including use of proper personal protective equipment. HMIS Carcinogenic Effects Chronic Effects Ingredients: Not listed as carcinogen by OSHA, NTP or IARC. The substance may be toxic to upper respiratory tract, eyes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. See Toxicological Information (section 11) Page: 1/3 1-357 -A97330-14282-0-0-725-4-1437-2 Material Safety Data$heet Product Name FLASH ~ode 0723 ...ection 12. Ecological Information Ecotoxicity Not available. Biodegradable/OECD Not available. Section 13. Disposal Considerations Waste Waste must be disposed of in accordance with federal, Information state and local environmental control regulations. Consult your local or regional authorities, Waste Stream Code: - (None.) Classification: - (Non-hazardous waste) Section 14. Transport Information Proper shipping name Not applicable. DOT Classification Not a DOT controlled material (United States). UN number Not applicable. NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to the Bill of Lading with your shipment. Section 15. Regulatory Information U.S. Federal Regulations SARA 313 toxic chemical notification and release reporting: No products were found. Clean Water Act (CWA) 311: Trisodium Orthophosphate (RQ 5,000 Ibs) Clean air act (CAA) 112 regulated toxic substances: No products were found. All Components ofthis product are listed or exempt from listing on TSCA inventory. Section 16. Other Information To the best olour knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever jar the accuracy or completeness of the inlormation contained herein. Final determination olsuitability ol any material is the sole responsibility of the user, All materials may present unknown hazards and should be used with caution, Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 1-357 -A97330-14282-0-1-725-4-1438-3 ZEP Manufacturing Company Acuity Specialty Products Group, Inc. P.O, Box 2015 Atlanta, GA 30301 @ 1-877-1-BUY-ZEP (428-9937) www.zep.com 1 111111 11111 11111 11111 11111 UI 00725 8357 PRIOR LAKE TRANSMISSION 16783 TORONTO AVE SE PRIOR LAKE MN 55372 Printing date: 02/06/07 Section 1. Chemical Product and Company Identification Product name ZEP 70 Product Use Aerosol Lubricant Product Code 0030 Date of issue 06/14/06 Supersedes Emergency For MSDS Information: Telephone Acuity Specialty Products Group, Inc. Numbers Compliance Services 1-877-I-BUY-ZEP (428-9937) For Medical Emergency INFOTRAC: (877) 541-2016 Toll Free - All Calls Recorded For a Transportation Emergency CHEMTREC: (800) 424..9300 - All Calls Recorded In the District of Columbia (202) 483-7616 Prepared by Compliance Services Group Acuity Specialty Products Group 1420 Seaboard Industrial Blvd. Atlanta, GA 30318 Section 2. Composition, Information on Ingredients Name of Hazardous Ingredients ALKYL (C16-C18) METHYL ESTERS BLEND OF ISOBUT ANE & PROPANE CAS # 67784-80-9 74-98-6; 75-28- 5 % by Weight 60-70 10 - 20 Exposure Limits Not established ACGrn TLV (United States). TWA: 800 ppm 8 hour(s), OSHA PEL (United States). TW A: 1000 ppm 8 hour(s), Section 3. Hazards Identification Acute Effects Routes of Entry Skin contact. Inhalation. Skin Causes skin irritation. Skin inflammation is characterized by itching, scaling, or reddening. Sensitizer for skin, May cause allergic reactions to certain individuals. Eyes Causes eye irritation. Inflammation of the eye is characterized by redness, watering, and Personal Protection B itching. Inhalation High vapor concentrations can cause irritation to mucous membranes and upper respiratory tract. HMIS Ingestion Unlikely in this form. NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse health effects are lessened by following all prescribed safety precautions, including use of proper personal protective equipment. Carcinogenic Effects Chronic Effects Ingredients: Not listed as carcinogen by OSHA, NTP or IARC. Prolonged or repeated contact may dry skin and cause irritation. See Toxicologicallnfonnation (section 11) Section 4. First Aid Measures Eye Contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops. Wash with soap and water. Get medical attention if irritation develops. If inhaled, remove to fresh air. If irritation persists, get medical attention. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If affected person is conscious, give plenty of water to drink. Get medical attention immediately. Skin Contact Inhalation Ingestion 1-357 -A97330-14282-1-0-725-4-1435-0 Page: 1/3 -,de 0030 Material Safety Data Sheet Product Name ZEP 70 Aion 15. Regulatory Information U.S. Federal Regulations SARA 313 toxic chemical notification and release reporting: No products were found. Clean Water Act (CW A) 311: No products were found. Clean air act (CAA) 112 regulated toxic substances: No products were found. All Components of this product are listed or exempt from listing on TSCA inventory. Section 16. Other Information To the best olour knowledge, the information contained herein is accurate, However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness olthe in/ormation contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution, Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 1-357 -A97330-14282-Q-Q-725-4-1436-1 SERVICE PRO- SECTION 1 : IDENTIFICATION MSDS 10: 503 PRODUCT NAME: SERVICEPRO COMPLETETM ANTIFREEZE/COOLANT PRODUCT NUMBER: 16705 FORMULA NUMBER: Y A956G, Y A956G-B DISTRIBUTOR: Association of Independent Oil Distributors Montrose, CO 81402-1861 www.service-pro.com MANUFACTURER: Honeywell Consumer Products Group 39 Old Ridgebury Road Danbury, CT 06810-5109 CANADIAN OFFICE: Honeywell Consumer Products Group 3333 Unity Drive Mississauga, Ontario L5L 3S6 EMERGENCY PHONE NUMBER: (800) 862-7737 (in the US) (800) 668-9349 (in Canada) CHEMTREC 1-800-424-9300 (in the US) CANUTEC (613) 996-6666 (in Canada) MSDS DATE OF PREPARATION/REVISION: 10/28/04 INFORMATION PHONE NUMBER: PRODUCT USE: Automobile antifreeze - consumer product NFPA RATING (NFPA 704) - FIRE: 1 HEALTH: 2 REACTIVITY: 0 SECTION 2: PRODUCT COMPONENTS HAZARDOUS COMPONENTS CAS# PERCENT EXPOSURE LIMITS Ethylene Glycol (Aerosol) 107-21-1 80-95 None Established-OSHA PEL 100 mg/m3 Ceiling ACGIH TL V Diethylene Glycol 111-46-6 0-5 None Established OSHA PEL, ACGIH TL V Service Pro Complete Antifreeze/Coolant Page 1 of 9 SERVlCEPRD. NON-HAZARDOUS INGREDIENTS >1% Water 2-Ethyl Hexanoic Acid, Sodium Salt Neodacanoic Acid, Sodium Salt CAS# 7732-18-5 19766-89-3 31548-27-3 SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Eye and upper respiratory irritant. May cause nausea, vomiting, headache, drowsiness, blurred vision, convulsions, coma or death if ingested or inhaled. Prolonged or repeated skin contact may cause dermatitis or skin sensitization. POTENTIAL HEALTH EFFECTS: INHALATION: May cause irritation of the nose and throat with headache, particularly from mists. High vapor concentrations caused, for example, by heating the material in an enclosed and poorly ventilated workplace, may produce nausea, vomiting, headache, dizziness and irregular eye movements. SKIN CONTACT: No evidence of adverse effects from available information. EYE CONTACT: Liquid, vapors or mist may cause discomfort in the eye with persistent conjunctivitis, seen as slight excess redness or conjunctiva. Serious corneal injury is not anticipated. INGESTION: May cause abdominal discomfort or pain, nausea, vomiting, dizziness, drowsiness, malaise, blurring of vision, irritability, back pain, decrease in urine output, kidney failure, and central nervous system effects, including irregular eye movements, convulsions and coma. Cardiac failure and pulmonary edema may develop. Severe kidney damage that may be fatal may follow the swallowing of ethylene glycol. A few reports have been published describing the development of weakness of the facial muscles, diminishing hearing, and difficulty with swallowing, during the late stages of severe poisoning. CHRONIC EFFECTS: Prolonged or repeated inhalation exposure may produce signs of central nervous system involvement, particularly dizziness and jerking eye movements. Prolonged or repeated skin contact may cause skin sensitization and an associated dermatitis in some individuals. Ethylene glycol has been found to cause birth defects in laboratory animals. The significance of this finding to humans has not been determined. See Section 11 for additional information. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: The available toxicological information and a knowledge of the physical and chemical properties of the material suggest that overexposure in unlikely to aggravate existing medical conditions. Service Pro Complete Antifreeze/Coolant Page 2 of 9 SERVICE PRO- CARCINOGEN: None of the components of these products is listed as a carcinogen or suspected carcinogen by IARC, NTP or OSHA. SECTION 4: FIRST AID MEASURES INHALATION: Remove the victim to fresh air. If breathing has stopped administer artificial respiration. If breathing is difficult, have medical personnel administer oxygen. Get medical attention. SKIN CONTACT: Remove contaminated clothing. Immediately wash contacted area thoroughly with soap and water. If irritation persists, get medical attention. EYE CONTACT: Immediately flush eyes with large amounts of water for 15 minutes. Get medical attention if irritation persists. INGESTION: Seek immediate medical attention. Immediately call local poison control center or go to an emergency department. Never give anything by mouth to or induce vomiting in an unconscious or drowsy person. NOTES TO PHYSICIAN: The principal toxic effects of ethylene glycol, when swallowed, are kidney damage and metabolic acidosis. The combination of metabolic acidosis, an osmol gap and oxalate crystal in the urine is evidence of ethylene glycol poisoning. Pulmonary edema with hypoxemia has been described in a number of patients following poisoning with ethylene glycol. Respiratory support with mechanical ventilation may be required. There may be cranial nerve involvement in the late stages of toxicity from swallowed ethylene glycol. In particular, effects have been reported involving the seventh, eighth, and ninth cranial nerves, presenting with bilateral facial paralysis, diminished hearing and dysphagia. Ethanol is antidotal and its early administration may block the formation of nephrotoxic metabolites of ethylene glycol in the liver. The objective is to rapidly achieve and maintain a blood ethanol level of approximately 100 mg/dl by giving a loading dose of ethanol followed by a maintenance dose. Intravenous administration of ethanol is the preferred route. Ethanol blood levels should be checked frequently. Hemodialysis may be required. 4-Methylpyrazole (Antizole(R) or Fomepizole), a potent inhibitor of alcohol dehydrogenase, has been used therapeutically to decrease the metabolic consequences of ethylene glycol poisoning. Additional therapeutic modalities that may decrease the adverse consequences of ethylene glycol metabolism are the administration of both thiamine and pyridoxine. As there are complicated and serious overdoses, we recommend you consult with the toxicologists at your poison control center. This antidote is now approved by the F.D.A. and in many cases has replaced ethanol in the treatment of ethylene glycol poisoning. Service Pro Complete Antifreeze/Coolant Page 3 of 9 SERVlCEPRoe SECTION 5: FIRE AND EXPLOSION DATA FLASH POINT: 2540 F (1230 C) TOC >2300 F (>1100 C) Setaflash AUTOIGNITION TEMPERATURE: Not determined NFPA CLASSIFICATION: IIIB FLAMMABILITY LIMITS: LEL: Not determined UEL: Not determined EXTINGUISHING MEDIA: For large fires, use alcohol type or all-purpose foams. For small fires, use water spray, carbon dioxide or dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Do not spray pool fires directly. Firefighters should wear positive pressure self- contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. UNUSUAL FIRE HAZARDS: A solid stream of water or foam directed into hot, burning liquid can cause frothing. HAZARDOUS COMBUSTION PRODUCTS: Burning may produce carbon monoxide and carbon dioxide. SECTION 6: ACCIDENTAL RELEASE MEASURES Wear appropriate protective clothing and equipment (See Section 8). Collect with absorbent material and place in appropriate, labeled container for disposal or, if permitted flush spill area with water. SECTION 7: HANDLING AND STORAGE DANGER: Harmful or Fatal if Swallowed Do not drink antifreeze or solution. Avoid eye and prolonged or repeated skin contact. A void breathing vapors or mists. Wash exposed skin thoroughly with soap and water after use. Do not store in opened or unlabeled containers. Keep container away from open flames and excessive heat. Do not reuse empty containers unless properly cleaned. Empty containers retain product residue and may be dangerous. Do not cut, weld, drill, etc. containers, even empty. Service Pro Complete Antifreeze/Coolant Page 4 of 9 SERVlCEPRDe Sudden release of hot organic chemical vapors or mists from process equipment operating at elevated temperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions without any obvious ignition sources. Published "autoignition" or "ignition" temperatures cannot be treated as safe operating temperatures in chemical processes without analysis of the actual process conditions. Use of this product in elevated temperature applications should be thoroughly evaluated to assure safe operating conditions. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION: Use general ventilation or local exhaust as required to maintain exposures below the occupational exposure limits. RESPIRATORY PROTECTION: For operations where the TL V is exceeded a NIOSH approved respirator with organic vapor cartridges and dust/mist prefilters or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration. Select and use in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus. GLOVES: Chemical resistant gloves such as neoprene or PVC where contact is possible. EYE PROTECTION: Splash-proof goggles. OTHER PROTECTIVE EQUIPMENT/CLOTHING: Appropriate protective clothing as needed to minimize skin contact. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: Yellow liquid with a characteristic odor. There is no odor threshold data for this product. pH: 8.7-9.2 SPECIFIC GRAVITY: 1.07-1.14 BOILING POINT (F): 3400 F VAPOR PRESSURE: Not determined FREEZING POINT (F): -360 F VAPOR DENSITY: Not determined SOLUBILITY IN WATER: 100% EVAPORATION RATE: Not determined PERCENT VOLATILE: Not determined VISCOSITY: Not determined COEFFICIENT OF WATER/OIL DISTRIBUTION: Not determined SECTION 10: STABILITY AND REACTIVITY STABILITY: Stable CONDITIONS TO AVOID: None INCOMPATIBILITY: Normally unreactive, however, avoid strong bases at high temperatures, strong acids, strong oxidizing agents, and materials reactive with hydroxyl compounds. DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide. HAZARDOUS POLYMERIZATION: Will not occur. Service Pro Complete Antifreeze/Coolant Page 5 of 9 SERVlCEPRO. CONDITIONS TO AVOID: None known. SECTION 11: TOXICOLOGICAL INFORMATION ACUTE TOXICITY VALUES: LD50 Oral Rat: 4700 mg/kg LD50 Skin Rabbit: 9530 mg/kg LD50 Oral Rat: 12,565 mg/kg LD50 Skin Rabbit: 11,890 mg/kg SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH: Ethylene Glycol: Diethylene Glycol: Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. Also, in a preliminary study to assess the effects of exposure of pregnant rats and mice to aerosols at concentrations 150, 1,000 and 2,500 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentrations, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether inhalation of aerosol, percutaneous absorption of ethylene glycol from contaminated skin or swallowing of ethylene glycol as a result of grooming the wetted coat mediated the developmental toxicity. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose-only exposure resulted in maternal toxicity (1,000 and 2,500 mg/m3) and developmental toxicity in with minimal evidence of teratogenicity (2,500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to the skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen; there is currently no available information to suggest that ethylene glycol caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity; exposure to high aerosol concentration is only minimally effective in producing developmental toxicity; the major route for producing developmental toxicity is perorally. Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in tumor incidence or a different pattern of tumors compared with untreated controls. The absence of carcinogenic potential for ethylene glycol has been supported by numerous invitro genotoxicity studies showing that it does not produce mutagenic or c1astogenic effects. This product contains less than 0.3% tolytriazole which has demonstrated mutagenic activity in a bacterial test system. A correlation has been established between mutagenic activity and carcinogenic activity for many chemicals. NTP, IARC or OSHA have not identified Tolytriazole as a carcinogen or probable carcinogen. Service Pro Complete Antifreeze/Coolant Page 6 of 9 SERVlCEPRD. SECTION 12: ECOLOGICAL INFORMATION Ethylene Glycol: LC50 Goldfish: 5,000 mg/U24 hr. at 20 C static conditions. Toxicity threshold (cell multiplication inhibition test): Bacterial (Pseudomonas putida): 10,000 mgll Protozoa (Entosiphon sulcatum and Uronema parduczi Chatton-Lwoff): >10,000 mgll Algae (Microcystis aeruginosa): 2,000 mg/I Green algae (Scenedesmus quandricauda): >10,000 mg/I SECTION 13: DISPOSAL INFORMATION Dispose of product in accordance with all local, state/provincial and federal regulations. SECTION 14: TRANSPORT INFORMATION u.s. DOT HAZARD CLASSIFICATION: Not Regulated DOT MARINE POLLUTANTS: This product does not contain Marine Pollutants as defined in 49 CFR 171.8. IMDG CODE SHIPPING CLASSIFICATION: Not Regulated CANADIAN TOG CLASSIFICATION: Not Regulated Note: IF A BULK SHIPMENT IS INVOLVED, THE FOLLOWING INFORMATION APPLIES: U.S. DOT HAZARD CLASSIFICATION: PROPER SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s. (Ethylene glycol) UN NUMBER: UN3082 LABELS REQUIRED: Class 9, UN3082 SECTION 15: REGULATORY INFORMATION EPA SARA 311/312 HAZARD CLASSIFICATION: Acute health, chronic health EPA SARA 313: This Product Contains the Following Chemicals Subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): Ethylene Glycol 1 07 -21-1 80-95% (glycol ethers) PROTECTION OF STRATOSPHERIC OZONE: This product is not known to contain or to have been manufactured with ozone depleting substances as defined in 40 CFR Part 82, Appendix A to Subpart A. Service Pro Complete Antifreeze/Coolant Page 7 of 9 SERVlCEPRD. CERCLA SECTION 103: Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center. The RQ for this product, based on the RQ for Ethylene Glycol (95% maximum) of 5,000 Ibs., is 5,260 Ibs. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. CALIFORNIA PROPOSITION 65: The normal consumer use of this product does not result in exposures to chemicals known to the State of California to cause Cancer and/or Reproductive Harm above the significant risk level for carcinogens or the maximum allowable dose levels for reproductive toxins. Therefore, no warnings are required for consumer packages. Industrial or other occupational use of this product at higher frequency and using larger quantities of this product may result in exposures exceeding these levels and are labeled accordingly. EPA TSCA INVENTORY: All of the components of this material are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory. CANADIAN ENVIRONMENTAL PROTECTION ACT: All of the ingredients are listed on the Canadian Domestic Substances List. CANADIAN WHMIS CLASSIFICATION: Class D - Division 2 - Subdivision B - (A toxic material causing other chronic effects) CANADIAN WHIMIS HAZARD SYMBOLS: Toxic - Division 2 This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS contains all of the information required by the CPR. EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES (EINECS): All of the ingredients are listed on the EINECS inventory. JAPAN: All of the ingredients of this product are listed on the Japanese Existing and New Chemical Substances (MITI) List. AUSTRALIA: All of the ingredients of this product are listed on the Australian Inventory of Chemical Substances. SECTION 16: OTHER INFORMATION REVISION SUMMARY: New Product This MSDS is directed to professional users and bulk handlers of the product. Consumer products are labeled in accordance with Federal Hazardous Substances Act regulations. While Prestone Products Corporation believes that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as a warranty or representation for which Prestone Products Corporation Service Pro Complete Antifreeze/Coolant Page 8 of 9 SERVlCEPRD. assumes legal responsibility. They are offered for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. If more information is needed, please contact: Technical Services Prestone Products Corporation 55 Federal Road Danbury, CT 06810 (800) 862-7737 Service Pro Complete Antifreeze/Coolant Page 9 of 9 MSDSW~terial Safety Data Sheet SERVICE PRO BRAKE FLUID SP6012 " ....... Page 1 of 4 MSDS Number: SP6012 Revision Date: 06/23/04 _ PRODUCT AND COMPANY IDENTIFICATION Manufacturer AIOD ASSOCIATION OF INDEPENDENT OIL DISTRIBUTORS 700 S. CASCADE MONTROSE, CO 81401 Contact: Telephone Number: (970) 249-6336 FAX Number: (970) 240-4131 E-Mail: Web product Name: SERVICE PRO BRAKE FLUID sp6012 Revision Date: 06/23/04 MSDS Number: SP6012 Common Name: SOLUTION OF GLYCOL ETHERS AND POLYETHYLENE GLYCOL EMERGENCY PHONE NUMBER (800) 752-7869 NFPA 704M RATING: HEAL TH:1 FIREO REACTIVITY: 0 SPECIAL: O=INSIGNIFICANT 1=SLlGHT 2=MODERATE 3=HIGH 4=EXTREME COMPOSITION/INFORMA TION ON INGREDIENTS INGREDIENT POLYETHYLENE GLYCOL ETHERS POLETHYLENE GLYCOL CAS NUMBER 112-50-5 25322-68-3 PERCENT WEIGHT 50-85% 15-50% _ HAZARDS IDENTIFICATION Route of Entry: Skin absorption and inhalation Target Organs: Lungs, kidneys. liver and nervous system. Inhalation: Respiratory irritation and dizziness Skin Contact: Prolonged contact with skin can cause irritation. Repeated skin contact may cause persistent irritation and dermatitis Eye Contact: Will cause irritation upon contact. Ingestion: Product may cause discomfort, nausea,vomiting and diarrhea. CARCINOGENICITY: Product is not considered a carcinogen by OSHA, NTP or IARC. MEDICAL CONDITIONS: Pre-existing eye or skin conditions may be aggravated by over-exposure to this product. M SDS W~terial Safety Data Sheet SERVICE PRO BRAKE FLUID SP6012 " ..N..... Page 2 of 4 Revision Date: 06/23/04 MSDS Number: SP6012 _ FIRST AID MEASURES Inhalation: Remove to fresh air. If not breathing, give artificial respiration. Seek medical attention. Inhalation hazard unlikely due to low volatility of product. Wash area with soap and water. seek medical attention if irritation persists Immediately flush eyes with plenty of water for 15 minutes. Seek medical attention. DO NOT induce vomiting. Only give CONSCIOUS victim two glasses of water and seek medical attention. NEVER give UNCONSCIOUS anything by mouth. Skin Contact: Eye Contact: Ingestion: _ FIRE FIGHTING MEASURES Fl ash poi nt: 270 F Flash point Method: TCC Other: EXTINGUISHING MEDIA: carbon Dioxide ( C02) Dry Chemical, Foam.UNUSUAL FIRE AND EXPLOSION HAZARDS: vapors are heavier than air and can collect in low areas FIRE FIGHTING INSTRUCTIONS: containers can build up pressure if exposed to fire. containers should be cooled with water supply. FIRE FIGHTING EQUIPMENT: self- contained breathing apparatus with full face piece operated in positive pressure mode. _ ACCIDENTAL RELEASE MEASURES SPllULEAK PROCEDURES: Notify safety personnel ,evacuate all unnecessary personnel and provide adequate ventilation. If feasible, and without risk,clean-up personnel should stop leak. All clean up personnel should wear proper personal protective equipment. SMAll SPlllS:Clean with inert absorbent and place in recovery drums for disposal. LARGE SPillS: Dike to prevent further migration of material. DO NOT release into waterways or sewers. Follow applicable federal and state regulations, _ HANDLING AND STORAGE Handling Precautions: Wash thoroughly after handling. Do not get into eyes, on skin or on clothing.. Do not smoke while using this product.Do not use near excessive heat, sparks, or open flame. Storage Requirements: Store in clean, dry locations away from excessive heat. _ EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Eye wash station and safety shower. General ventilation. Material non - volatile Protective Equipment: EYE: Chemical splash goggles with indirect or no ventilation. SKIN :None required RESPIRATORY: None required ,except in emergency situations. Never eat, drink or smoke in work area MSDS f1&terial Safety Data Sheet SERVICE PRO BRAKE FLUID SP6012 " ....... Page 3 of 4 Revision Date: 06/23/04 MSDS Number: SP6012 _ PHYSICAL AND CHEMICAL PROPERTIES Appearance: Physical State: Odor: pH: Vapor Pressure: Vapor Density: Clear amber liquid liquid slight petroleum odor Soluble in water 1.038-1.04 <0.1 mmHG >1 Boiling Point: Freezing/Melting Pt.: Solubility: Spec Grav.lDensity: 455-475 F _ STABILITY AND REACTIVITY Stability: Material is stable. Conditions to avoid: Excessive heat and open flame. Materials to avoid (incompatability): Strong oxidizing agents. Hazardous Decomposition products: Carbon Monoxide and Carbon Dioxide Hazardous Polymerization: Cannot occur. _ TOXICOLOGICAL INFORMATION ___________________LD50__________________________ Toxicity studies done on this product have shown: LD50 (oral) ......... > 2000 mg/kg _ ECOLOGICAL INFORMATION No Data. _ DISPOSAL CONSIDERATIONS Dispose of in accordance with all applicable state, federal and local regulations. _ TRANSPORT INFORMATION DOMESnc: Not regulated EXPORT: Not regulated MSDS ~&terial Safety Data Sheet SERVICE PRO BRAKE FLUID SP6012 " NNIUlY Page 4 of 4 Revision Date: 06/23/04 MSDS Number: SP6012 _ REGULATORY INFORMATION u.s. FEDERAL REGULATIONS OSHA: considered to be a hazardous material as defined by 29cFR1910.1200 EPA SARA TITLE III section 311-312 (40CFR370): If stored in excess of the threshold quantities, this product should be reported as a(n): IMMEDIATE (acute) HEALTH HAZARD section 313(40CFR372) This product does notcontain ingredients which are subject to the reporting requirements of SARA 313: _ OTHER INFORMATION CALIFORNIA PROPOSITION 65: This product does not contain ingredients which are on the current Proposition 65 list Notes: NG= NOT GIVEN BT= BETWEEN <= LESS THAN >= GREATER THAN USERS RESPONSIBILlTY;This MSDS provides environmental, health and safety information. This product is to be used in applications consistent with our product literature and container label. Individuals handling this product should be informed to the recommended safety precautions and have access to this MSDS. Please contact your local sales representative ot our EH&S Department for further information. END OF MSDS END OF MSDS DOCUMENT Material Safety Data Sheet Brake Cleaner Non-Chlorinated Date of Preparation: 09-10-01 MSDS No. 073 Revision: 12-02-05 Section 1 - Chemical Product and Company Identification Product/Chemical Name: Brake Cleaner Non-Chlorinated Part Number(s): 2401, 2405, 2416, 2455 (Blend 5M-VOCR) CAS Number: Not applicable to mixtures General Use: Automotive product Manufacturer: Berryman Products, Inc., 3800 E. Randol Mill Rd., Arlington, TX 76011-5434 Phone: 1-800-433-1704, Emergency phone number: 1-800-535-5053. I ***** Emergency Overview ***** I Section 2 - Composition / Information on Ine:redients Ingredient Name CAS Number 0/0 wt or 0/0 vol Acetone 67-64-1 45-55 Toluene 108-88-3 7-12 Heptanes Mixture 7-12 Methanol 67-56-1 20-30 Trace Impurities: ..........................-............--...................-..--...........................--.........-................................-..-........-.......................-......--.......-.....-.............-..............-........-... I OSHA PEL I ACGIH TLV I NIOSH REL I NIOSH Ine:redient TWA STEL TWA STEL TWA STEL IDLH Acetone 1000 none estab. 500 750 none estab. none estab. none estab. Toluene 200 none estab. 50 none estab. none estab. none estab. none estab. Heptanes 500 none estab. 400 500 none estab. none estab. none estab. Methanol 200 none estab. 200 250 none estab. none estab. none estab. Section 3 - Physical and Chemical Properties Physical State: Liquid Boiling Point: 133-232 OF Appearance and Odor: Clear, Ketone Refractive Index: 1.3932 Vapor Pressure: 180 nun Hg at 68 OF (Major % Volatile: 100 Component) Evaporation Rate: Slower than ether Vapor Density (Air=I): Heavier than air Density: 6.58 Ibs/gal Specific Gravity (H20=1, at 4 oC): 0.790 Section 4 - Fire-Fiehtine: Measures Flash Point: <40 OF NFPA Flash Point Method: CC ~ LEL: 2.5% v/v (Major Component) Flammability Classification: Class IB Extinguishing Media: Carbon dioxide, alcohol-resistant foam, dry chemicals Unusual Fire or Explosion Hazards: Extremely flammable liquid. Vapors can cause flash fire. Fire-Fighting Instructions: Do not release runoff from fire control methods to sewers or waterways. Fire-Fighting Equipment: Wear self-contained breathing apparatus pressure demand, MSNAlOSHA (approved or equivalent) and full protective gear. Use water spray to keep fire-exposed containers cool. Section 5 - Stability and Reactivity Stability: Brake Cleaner Non-Chlorinated is stable at room temperature in closed containers under normal storage and handling conditions. Polymerization: Hazardous polymerization cannot occur. Chemical Incompatibilities & Conditions to Avoid: Isolate from oxidizers, heat, sparks, electric equipment and open flame. MSDS No. 073 Brake Cleaner Non-Chlorinated Revision: 12-02-05 Hazardous Decomposition Products: Thermal oxidative decomposition of Brake Cleaner Non-Chlorinated can produce carbon monoxide and carbon dioxide. Section 6 - Health Hazard Information Potential Health Effects Primary Entry Routes: Skin, dermal, inhalation and ingestion. Target Organs: Eyes, skin, respiratory system, CNS, liver and kidneys. Acute Effects: May cause irritation to the eyes, skin, nose, throat and respiratory system. Nausea, headache, light-headedness, dizziness, fatigue, loss of consciousness, abdominal pain and dermatitis. May cause blindness if ingested. Harmful or fatal if swallowed. Carcinogenicity: IARC, NTP, and OSHA do not list Brake Cleaner Non-Chlorinated as a carcinogen. Chronic Effects: May affect liver, kidneys or central nervous system. Can cause nervous system depression. ...-..............-...-.........................-..........................-.............-........................-........................................-..............-................--.-.......................................................... Emergency and First Aid Procedures Inhalation: Remove to fresh air. Ifnot breathing, give artificial respiration. Get medical attention immediately. Eye Contact: Immediately flush eyes with plenty of water. Get medical attention, if irritation persists. Skin Contact: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse. Ingestion: GET MEDICAL A TIENTION IMMEDlA TEL Y. Do not induce vomiting. After first aid, get appropriate in-plant, paramedic, or community medical support. Section 7 - Spill, Leak, and Disposal Procedures Spill /Leak Procedures: Eliminate all sources of ignition. Stop spill at source. Wear appropriate personal protective equipment (Sec. 8). Contain the spill to facilitate cleanup with absorbent. Use non-sparking tools and equipment. Transfer to disposal containers. Containment: For large spills, dike far ahead ofliquid spill for later disposal. Do not release into sewers or waterways. Disposal: Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, state and local regulations. Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120). Section 8 - Exposure Controls / Personal Protection Ventilation: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec. 2). Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source. Respiratory Protection: Seek professional advice prior to respirator selection and use. Follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary, wear a MSHAlNIOSH-approved respirator. Select respirator based on its suitability to provide adequate worker protection for given working conditions, level of airborne contamination, and presence of sufficient oxygen. For emergency or nonroutine operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA. Warning! Air-purifYing respirators do not protect workers in oxygen-deficient atmospheres. If respirators are used, OSHA requires a written respiratory protection program that includes at least: medical certification, training, fit-testing, periodic environmental monitoring, maintenance, inspection, cleaning, and convenient, sanitary storage areas. Protective ClothinglEquipment: Wear chemically protective gloves, boots, aprons, and gauntlets to prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations (29 CFR 1910.133). Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses. Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area. Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove this material from your shoes and clean personal protective equipment. Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics. Section 9 - Special Precautions and Comments Handling Precautions: Avoid prolonged breathing of vapor and contact with eyes, skin and clothing. Use in well ventilated area. Wash thoroughly after handling. Storage Requirements: Keep away from heat, sparks and flame. Keep container closed when not in use. California Proposition 65: This product contains the following chemicals know to the state of California to cause cancer and/or reproductive toxicity: Toluene. .............................................................................................._..._...._......................__n......................................_.._........_.....................-......................................-.......... Page 2 of3 Revision: 12-02-05 Brake Cleaner Non-Chlorinated DOT Transportation Data (49 CFR 172.101): MSDS No. 073 Part Number(s): 2401, 2405, 2416,2420,2455 Shipping Name: Flammable Liquid, N.O.S., contains (Toluene, Acetone and Methanol) Hazard Class: 3 ID No.: UN 1993 Packing Group: II SARA Title III Section 313 Supplier Notification: This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the emergency Planning & Community Right- To-Know-Act of 1986 & of 40CFR 372: Toluene and Methanol. Prepared By: Alicia L. Reed Disclaimer: All infonnation appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the nfonnation is believed to be accurate, we make no representations as to its accuracy or sufficiency. Conditions of use are beyond our control, herefore users are responsible for verifYing the data under their own operating conditions to detennine whether the product is suitable for their articular purposes and they assume all risks of their use, handling and disposal of the product. Users also assume all risks in regards to the ublications of use of, or reliance upon infonnation contained herein. This infonnation relates only to the product designated herein, and does not elate to its use in combination with any other material or process. Page 3 of3 The Valspar Corporation Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Material Identification Product ID: Product Name: Product Use: Print date Revision Date 405.0000234.076 T-234 RED OX SAND PRIM 2U Paint or Coatings Related Product 20/Dec/2006 20/Dec/2006 Company Identification The Valspar Corporation - Architectural Coatings Division 1000 Lake Road Medina, OH 44256 Manufacturer's Phone: 1-330-725-4511 24-Hour Medical Emergency Phone: 1-888-345-5732 2. COMPOSITION I INFORMATION ON HAZARDOUS INGREDIENTS Common Name Approx, Chemical name CAS-No. Weiaht % DIMETHYL KETONE 35 - 40 ACETONE 67-64-1 PROPANE 15 - 20 Propane 74-98-6 ~ALC 5 -10 TALC (MG3H2(SI03)4) 14807-96-6 BUTANE 5 -10 Butane 1 06-97-8 XYLENE (WI ANTI-STATIC) 5 -10 Xylenes (0-, m-, p- isomers) 1330-20-7 ISOPROPYL ALCOHOL 1 - 5 Isopropyl alcohol 67-63-0 [ETHYL 3- 1 - 5 Ethyl 3-ethoxypropionate ETHOXYPROPIONA TE 1763-69-9 METHYL ETHYL KETONE 1 - 5 Methyl ethyl ketone 178-93-3 ISOBUTYL ACETATE 1 - 5 Isobutyl acetate 110-19-0 PROPRIETARY PIGMENT 1 - 5 PROPRIETARY PIGMENT PROPRIETARY RESIN 1 - 5 PROPRIETARY RESIN ETHYLBENZENE 1 - 5 Ethyl benzene 100-41-4 If this section is blank there are no hazardous components per OSHA guidelines. 3. HAZARDS IDENTIFICATION Product 10: 405,0000234,076 Page 1 / 8 3. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Emergency Overview: This section not in use. This product contains ingredients that may contribute to the following potential acute health effects: Inhalation Effects: Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or respiratory irritation. Eye Contact: Causes eye irritation. Skin Contact: May cause moderate skin irritation. Acute Ingestion: None known Other Effects: May cause kidney damage. May cause liver damage. This product contains ingredients that may contribute to the following potential chronic health effects: Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. May cause eye damage and pain. Prolonged and/or repeated contact can result in skin irritation. May cause skin drying with prolonged exposure. See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens. If this section is blank, no information is available. 4. FIRST AID MEASURES Inhalation: If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention. Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Skin Contact: In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get medical attention. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean contaminated shoes. Ingestion: If swallowed, contact medical personnel immediately to determine best course of action. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Flash point (Fahrenheit): Lower explosive limit: _310 F ( -350 C) TeC/PM 2% Product 10: 405.0000234.076 Page 2 I 8 5. FIRE FIGHTING MEASURES Upper explosive limit: Autoignition temperature: Sensitivity to impact: Sensitivity to static discharge: Hazardous combustion products: 13% Not available. 0 F ( 0 C) No. Subject to static discharge hazards. Please see bonding and grounding information in Section 7. See Section 10. Unusual fire and explosion hazards: Contaminated rags, wipes, saw dust, etc., may catch fire spontaneously. Store waste under water in closed metal containers until disposed of in compliance with applicable regulations. Contains oxidizable materials. Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Fire fighting procedures: Use water spray to cool nearby containers and structures exposed to fire. Firefighters should be equipped with self- contained breathing apparatus and turn out gear. 6. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with inert absorbent and non sparking tools. Avoid contact with eyes. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above the f1ashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly bonded and grounded at all times. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and face protection: Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye. Skin protection: Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all exposed areas. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dusUmist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Ventilation Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate ignition sources. Product ID: 405.0000234.076 Page 3 / 8 Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Common Name ~pprox. TWA (final) lCeilings limits (final) ~kin designations CAS-No. lNeiaht % DIMETHYL KETONE 35 - 40 '400 mg/m3 1000 ppm 57-64-1 :lROPANE 15 - 20 1800 mg/m3 1000 ppm 74-98-6 ALC 5 -10 Respirable. Listed. 14807-96-6 Total dust. Listed. KYLENE (WI ANTI-STATIC) 5 -10 435 mg/m3 100 ppm 1330-20-7 ISOPROPYL ALCOHOL 1 - 5 g80 mg/m3 400 ppm 37-63-0 ~ETHYLETHYLKETONE 1 - 5 590 mg/m3 200 ppm 78-93-3 ISOBUTYL ACETATE 1 - 5 700 mg/m3 150 ppm 110-19-0 PROPRIETARY PIGMENT 1 - 5 10 mg/m3 Fume. ETHYLBENZENE 1 - 5 435 mg/m3 100 ppm 100-41-4 ACGIH Threshold Limit Value (TLV's) Common Name ~pprox. TWA STEL Ceiling limits Skin designations CAS-No. Weight % DIMETHYL KETONE 35 - 40 500 ppm 750 ppm 37-64-1 PROPANE 15 - 20 1000 ppm 74-98-6 T"ALC 5 -10 , mg/m3 14807-96-6 Respirable fraction. The value is for particulate matter ~ontaining no asbestos and <1% crvstalline silica. BUTANE 5 -10 1000 ppm 1 06-97-8 XYLENE (WI ANTI-STATIC) 5 -10 100 ppm 150 ppm 1330-20-7 ISOPROPYL ALCOHOL 1 - 5 200 ppm 400 ppm 67-63-0 METHYL ETHYL KETONE 1 - 5 '00 ppm 300 ppm 78-93-3 ISOBUTYL ACETATE 1 - 5 150 ppm 11 0-19-0 PROPRIETARY PIGMENT 1 - 5 5 mg/m3 Dust and ume. Fe ETHYLBENZENE 1 - 5 100 ppm 125 ppm 100-41-4 If this section is blank, no information is available. Product 10: 405,0000234.076 Page 4 I 8 9. PHYSICAL PROPERTIES Odor: Physical State: pH: Vapor pressure: Vapor density (air = 1.0): Boiling point: Solubility in water: Coefficient of water/oil distribution: Density (Ibs per US gallon): Specific Gravity Evaporation rate (butyl acetate = 1.0): Normal for this product type. Liquid Not determined. NOT DETERMINED mmHG @ 680 F ( 200 C) 5 -420 F ( -410 C) Not determined. Not determined. 6.74 .81 5.6 1 O. STABILITY AND REACTIVITY Stability Conditions to Avoid: Incompatibility: Hazardous Polymerization: Hazardous Decomposition Products: Stable None known. Strong oxidizers. None anticipated. Silicon dioxide. Carbon monoxide and carbon dioxide. Metal oxide fumes. Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding information in Section 7. 11. TOXICOLOGICAL INFORMATION Mutagens: Teratogens: Carcinogens: Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to humans. IARC has classified ethyl benzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans. ommon Name AS-No. THYLBENZENE 100-41-4 IARC Group 1 - Human IARC Group 2A - Limited IARC Group 28 - Evidence Human Data ufficient Animal Data Monograph 77,2000 ommon Name AS-No. ALC 14807-96-6 THYLBENZENE 1 00-41-4 1 - 5 Product 10: 405.0000234.076 Page 5 I 8 ommon Name AS-No. THYLBENZENE 100-41-4 Group A3 Confirmed nimal carcinogen with unknown relevance to humans. CGIH Carcinogens If this section is blank, no information is available. 12. ECOLOGICAL DATA Not available at this time. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation Proper Shipping Name: CONSUMER COMMODITY ORM-D UN 10 Number: CONCOM 49 CFR Hazardous Material Regulations Parts 100-180 The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to determine if the use of these exceptions applies to your shipments when re-shipping our products. International Air Transport Association: Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 UN 10 Number: UN1950 International Maritime Organization: Proper Shipping Name: AEROSOLS Hazard Class: 2 Non-Bulk UN 10 Number: UN1950 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: Common Name IApprox. SARA 302 ISARA 313 ~ERCLA RQ in Ibs. CAS-No. Weiaht % DIMETHYL KETONE 35-40 5000 67-64-1 XYLENE (WI ANTI-STATIC) 5 -10 orm R reporting required 100 1330-20-7 or 1.0% de minimis oncentration METHYL ETHYL KETONE 1 - 5 5000 78-93-3 SO BUTYL AGET ATE 1 - 5 5000 11 0-19-0 ~THYLBENZENE 1 - 5 orm R reporting required 1000 100-41-4 or 1.0% de minimis concentration Product 10: 405.0000234.076 Page 6 I 8 SARA 311/312 Hazard Class: Acute: Yes Chronic: Yes Flammability: Yes Reactivity: No Sudden Pressure: Yes U.s. STATE REGULATIONS: Pennsylvania Right To Know: ETHYLBENZENE BUTANE ISOBUTYL ACETATE PROPRIETARY PIGMENT XYLENE (wi ANTI-STATIC) TALC ISOPROPYL ALCOHOL DIMETHYL KETONE PROPANE ETHYL 3-ETHOXYPROPIONATE METHYL ETHYL KETONE PROPRIETARY RESIN 100-41-4 106-97-8 1l0-19-0 Trade Secret 1330-20-7 14807-96-6 67-63-0 67-64-1 74-98-6 763-69-9 78-93-3 Trade Secret California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer. Rule 66 status of product Photochemically reactive. INTERNATIONAL REGULATIONS - Chemical Inventories Canada Domestic Substances List: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. All components of this product are listed on the Domestic Substances List. TSCA Inventory: 16. OTHER INFORMATION HMIS Codes Health: Flammability: Reactivity: PPE: 2 4 1 X - See Section 8 for Personal Protective Equipment (PPE). Abbreviations: OSHA _ Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH- National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, lATA - International Air Transport Association, IMO - International Maritime Organization, DOT- Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.AV - Not available, RQ- Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, MPPCF _ Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Product 10: 405.0000234.076 Page 7 / 8 Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Pennsylvania. Product 10: 405,0000234.076 Page 8 I 8 The Valspar Corporation Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Material Identification Product 10: Product Name: Product Use: Print date Revision Date 400.0000202.076 202 UNIVERSAL GRAY Paint product. 17/Jan/2007 09/Jan/2007 6U Company Identification The Valspar Corporation - Architectural Coatings Division 1000 Lake Road Medina, OH 44256 Manufacturer's Phone: 1-330-725-4511 24-Hour Medical Emergency Phone: 1-888-345-5732 2. COMPOSITION I INFORMATION ON HAZARDOUS INGREDIENTS Common Name Approx. Chemical name CAS-No. Weight % DIMETHYL KETONE 40 - 45 ~CETONE 67-64-1 PROPANE 15 - 20 Propane 74-98-6 p<YLENE (WI ANTI-STATIC) 5 -10 p<ylenes (0-, m-, p- isomers) 1330-20-7 BUTANE 5 -10 Butane 1 06-97-8 ETHYL 3- 1 - 5 Ethyl 3-ethoxypropionate ETHOXYPROPIONA TE 763-69-9 ETHYL ACETATE 1 - 5 Ethylacetate 141-78-6 l=THYLBENZENE 1 - 5 Ethyl benzene 100-41-4 rrlTANIUM DIOXIDE 1 - 5 IT itanium dioxide 13463-67 -7 ~ETHYL ETHYL KETONE 1 - 5 Methyl ethyl ketone b'8-93-3 IPROPRIETARY RESIN 1 - 5 PROPRIETARY RESIN IPROPRIETARY INERT 1 - 5 PROPRIETARY INERT ICARBON BLACK .1 - 1 ICARBON BLACK 1333-86-4 If this section is blank there are no hazardous components per OSHA guidelines. 3. HAZARDS IDENTIFICATION Product 10: 400.0000202.076 Page 1 I 8 3. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Emergency Overview: This section not in use. This product contains ingredients that may contribute to the following potential acute health effects: Inhalation Effects: Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or respiratory irritation. Eye Contact: Causes eye irritation. Skin Contact: May cause moderate skin irritation. Acute Ingestion: None known Other Effects: May cause kidney damage. May cause liver damage. This product contains ingredients that may contribute to the following potential chronic health effects: Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Prolonged and/or repeated contact can result in skin irritation. May cause skin drying with prolonged exposure. Possible cancer hazard. Contains ingredients which may cause cancer based on animal data. Risk of cancer depends on duration and level of exposure. See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens. If this section is blank, no information is available. 4. FIRST AID MEASURES Inhalation: If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention. Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Skin Contact: In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get medical attention. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean contaminated shoes. Ingestion: If swallowed, contact medical personnel immediately to determine best course of action. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Product 10: 400.0000202.076 Page 2 I 8 5. FIRE FIGHTING MEASURES Flash point (Fahrenheit): Lower explosive limit: Upper explosive limit: Autoignition temperature: Sensitivity to impact: Sensitivity to static discharge: Hazardous combustion products: -310 F ( -350 C) TCC/PM 2% 13% Not available. 0 F ( 0 C) No. Subject to static discharge hazards. Please see bonding and grounding information in Section 7. See Section 10. Unusual fire and explosion hazards: Contaminated rags, wipes, saw dust, etc., may catch fire spontaneously. Store waste under water in closed metal containers until disposed of in compliance with applicable regulations. Contains oxidizable materials. Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Fire fighting procedures: Use water spray to cool nearby containers and structures exposed to fire. Firefighters should be equipped with self- contained breathing apparatus and turn out gear. 6. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with inert absorbent and non sparking tools. Avoid contact with eyes. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly bonded and grounded at all times. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and face protection: Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye. Skin protection: Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all exposed areas. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dusUmist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Product 10: 400.0000202.076 Page 3 / 8 Ventilation Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate ignition sources. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Common Name ~pprox. TWA (final) Ceilings limits (final) Skin designations CAS-No. Weiaht % DIMETHYL KETONE 40 - 45 2400 mg/m3 1000 ppm 57 -64-1 PROPANE 15 - 20 1800 mg/m3 1000 ppm 74-98-6 XYLENE (WI ANTI-STATIC) 5 -10 435 mg/m3 100 ppm 1330-20-7 ETHYL ACETATE 1 - 5 1400 mg/m3 400 ppm 141-78-6 ETHYLBENZENE 1 - 5 435 mg/m3 100 ppm 100-41-4 TITANIUM DIOXIDE 1 - 5 15 mg/m3 Total dust. 13463-67-7 METHYL ETHYL KETONE 1 - 5 590 mg/m3 200 ppm 8-93-3 PROPRIETARY INERT 1 - 5 5 mg/m3 Respirable raction. 15 ma/m3 Total dust. ~ARBON BLACK .1 - 1 3.5 mg/m3 1333-86-4 ACGIH Threshold Limit Value (TLV's) Common Name ~pprox. TWA STEL Ceiling limits $kin designations CAS-No. Weiaht % DIMETHYL KETONE 40 - 45 500 ppm 1750 ppm 67-64-1 PROPANE 15 - 20 1000 ppm 74-98-6 XYLENE (WI ANTI-STATIC) 5 -10 100 ppm 150 ppm 1330-20-7 BUTANE ~ -10 1000 ppm 1 06-97 -8 THYLACETATE 1 - 5 400 ppm 141-78-6 _THYLBENZENE 1 - 5 100 ppm 125 ppm 100-41-4 "ITANIUM DIOXIDE 1 - 5 1 0 mg/m3 13463-67-7 ~ETHYLETHYLKETONE 1 - 5 200 ppm 300 ppm 78-93-3 PROPRIETARY INERT 1 - 5 10 mg/m3 CARBON BLACK .1 - 1 3.5 mg/m3 1333-86-4 If this section is blank, no information is available. Product 10: 400.0000202.076 Page 4 I 8 9. PHYSICAL PROPERTIES Odor: Physical State: pH: Vapor pressure: Vapor density (air = 1.0): Boiling point: Solubility in water: Coefficient of water/oil distribution: Density (Ibs per US gallon): Specific Gravity Evaporation rate (butyl acetate = 1.0): Normal for this product type. Liquid Not determined. NOT DETERMINED mmHG @ 680 F ( 200 C) 5 -420 F ( -410 C) Not determined. Not determined. 6.45 .77 5.6 10. STABILITY AND REACTIVITY Stability Conditions to Avoid: Incompatibility: Hazardous Polymerization: Hazardous Decomposition Products: Stable None known. Strong oxidizers. None anticipated. Carbon monoxide and carbon dioxide. Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding information in Section 7. 11. TOXICOLOGICAL INFORMATION Mutagens: Teratogens: Carcinogens: Contains ethyl benzene, which has been determined by NTP to be an animal carcinogen with no known relevance to humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans. Contains TI02 which is listed by IARC as a possible human carcinogen (Group 2B) based on animal data. Neither long term animal studies, nor human epidemiology studies of workers exposed to TI02 provide an adequate basis to conclude TI02 is carcinogenic. TI02 is not classified as a carcinogen by NTP, U.S. OSHA, or the U.S. EPA. Common Name IApprox. ARC Group 1 - Human IARC Group 2A - limited IARC Group 28 - CAS-No. Weiaht % Evidence Human Data Isufficient Animal Data L...THYLBENZENE 1 - 5 Monograph 77,2000 100-41-4 'r"ITANIUM DIOXIDE 1 - 5 ~B Possible Carcinogen 13463-67 -7 ~ARBON BLACK .1 - 1 Monograph 65, 1996 1333-86-4 ommon Name AS-No. THYLBENZENE 100-41-4 Product 10: 400.0000202.076 Page 5 / 8 ommon Name AS-No. THYLBENZENE 100-41-4 Group A3 Confirmed nimal carcinogen with unknown relevance to humans. CGIH Carcinogens If this section is blank, no information is available. 12. ECOLOGICAL DATA Not available at this time. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION u.S. Department of Transportation Proper Shipping Name: CONSUMER COMMODITY ORM-O UN ID Number: CONCOM 49 CFR Hazardous Material Regulations Parts 100-180 The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to determine if the use of these exceptions applies to your shipments when re-shipping our products. International Air Transport Association: Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 UN ID Number: UN1950 International Maritime Organization: Proper Shipping Name: AEROSOLS Hazard Class: 2 Non-Bulk UN 10 Number: UN1950 15. REGULATORY INFORMATION u.S. FEDERAL REGULATIONS: ~ommon Name Approx. SARA 302 SARA 313 CERCLA RQ in Ibs. ::AS-No. Weight % )IMETHYL KETONE 40-45 5000 57-64-1 XYLENE (W/ ANTI-STATIC) 5 -10 orm R reporting required 100 1330-20-7 or 1.0% de minimis r'oncentration ETHYL ACETATE 1 - 5 5000 141-78-6 ETHYLBENZENE 1 - 5 orm R reporting required 1000 100-41-4 or 1.0% de minimis ~oncentration Product 10: 400.0000202.076 Page 6 / 8 ommon Name AS-No. ETHYL ETHYL KETONE 8-93-3 ARA 302 SARA 313 ERCLA RQ in Ibs. 5000 SARA 311/312 Hazard Class: Acute: Yes Chronic: Yes Flammability: Yes Reactivity: No Sudden Pressure: Yes U.S. STATE REGULATIONS: Pennsylvania Right To Know: ETHYLBENZENE BUTANE XYLENE (Wi ANTI-STATIC) PROPRIETARY PIGMENT ETHYL ACETATE DIMETHYL KETONE PROPANE ETHYL 3-ETHOXYPROPIONATE METHYL ETHYL KETONE PROPRIETARY RESIN 100-41-4 106-97-8 1330-20-7 Trade Secret 141-78-6 67-64-1 74-98-6 763-69-9 78-93-3 Trade Secret Additional Non-Hazardous Materials PROPRIETARY RESIN Trade Secret California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer. Rule 66 status of product Photochemically reactive. INTERNATIONAL REGULATIONS - Chemical Inventories Canada Domestic Substances List: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. All components of this product are listed on the Domestic Substances List. TSCA Inventory: 16. OTHER INFORMATION HMIS Codes Health: Flammability: Reactivity: PPE: 2 4 1 X - See Section 8 for Personal Protective Equipment (PPE). Product 10: 400.0000202.076 Page 7 / 8 Abbreviations: OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH- National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, lATA - International Air Transport Association, IMO - International Maritime Organization, DOT- Oepartment of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.AV. - Not available, RQ- Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup I Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLlEO, ANO OISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Pennsylvania. Product 10: 400.0000202.076 Page 8 I 8 Revision Date: 01/30/2001 MATERIAL SAFETY DATA SHEET Product Name: SERVICE PRO WINDSHIELD WASHER CLEANER AND ANTI-FREEZE--SP5212 Manufacturer: Address: Telephone: Emergency: Contact: AIOD (ASSOCIATION OF INDEPENDENT OIL 301 N. CASCADE, SUITE A MONTROSE (970) 249-6336 (800) 752-7869 EH&S MANAGER DISTRIBUTORS) CO 81401-1861 ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ SECTION 01 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name: SERVICE PRO WINDSHIELD WASHER CLEANER AND ANTI-FREEZE--SP5212 Synonyms: Description: WINDSHIELD WASHER ANTI-FREEZE CONTAINING METHANOL NFPA 704M9 Rating: Health: 2 Fire: 4 Reactivity: 0 Special: O=Insignificant l=Slight 2=Moderate 3=High 4=Extreme ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ SECTION 02 COMPOSITION AND INFORMATION ON INGREDIENTS Chemical Ingredients (% by Weight) Ingredient CAS Number Percent Weight METHANOL 67-56-1 65% - 75% ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ ------------------------------------------------------------------------------- SECTION 03 HAZARD IDENTIFICATION EMERGENCY OVERVIEW: Prolonged contact with skin may cause moderate irritation. Contact with eyes can cause severe irritation, redness, tearing, and blurred vision. Harmful if swallowed, or absorbed through skin. POTENTIAL HEALTH EFFECTS CARCINOGENICITY: Product not considered a carcinogen by OSHA, NTP, or IARC. MEDICAL CONDITIONS: Pre-existing eye or skin conditions may be aggravated by over- exposure to this product. TARGET ORGANS: Liver, lungs, kidneys, optic nerve. PRIMARY ENTRY ROUTES: Skin absorption. ACUTE HEALTH EFFECTS EYE: Will cause irritation upon contact. SKIN: Prolonged contact with skin can cause irritation. Repeated skin contact may cause persistent irritation and dermatitis. INHALATION: Product non-volatile, inhalation hazard unlikely. INGESTION: Product may be harmful if swallowed and may cause nausea, vomiting, and diarrhea. CHRONIC HEALTH EFFECTS: Overexposure to the ingredients in this product can cause liver abnormalities, eye and kidney damage. ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ SECTION 04 FIRST AID INFORMATION -----------------~-------------------------------- -------------------------------------------------------- EYE CONTACT: Immediately flush eyes with plenty of water for 15 minutes. Seek medical attention. SKIN CONTACT: Wash area with soap and water. Seek medical attention if irritation persists. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. Seek medical attention. Inhalation hazard unlikely due to low volatility of product. INGESTION: INDUCE vomiting. Only give CONSCIOUS victim two glasses of water and seek medical attention. NEVER give UNCONSCIOUS victim anything by mouth. -------------------------------------------------------------------------- -------------------------------------------------------------------------- SECTION 05 FIRE FIGHTING MEASURES ---------------------------------------- ------------------------------------ FLASH POINT: BT 50 - 60 F TCC EXTINGUISHING MEDIA: Carbon Dioxide (C02), Dry Chemical, Foam. UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors are heavier than air and can collect in low areas. FIRE FIGHTING INSTRUCTIONS: Containers can build up pressure if exposed to fire. Containers should be cooled with water spray. FIRE FIGHTING EQUIPMENT: Self contained breathing apparatus with full face piece operated in positive pressure mode. --------------------------------------------------- ----------------------------------~--- SECTION 06 ACCIDENTAL RELEASE MEASURES -------------------------------------------------------------------- --------------------------------------------------------------------- SPILL/LEAK PROCEDURES: Notify safety personnel, evacuate all unnecessary personnel and provide adequate ventilation. If feasible and without risk, clean-up personnel should stop leak. All clean-up personnel should wear proper personal protective equipment. SMALL SPILL: Clean with inert absorbant and place in recovery drums for disposal. LARGE SPILL: Dike to prevent further migration of material. DO NOT release into waterways or sewers. Follow applicable federal and state regulations (20CFR1910.120). ------------------------------------------------------------------------ ---------------------------------------------------------------------------- SECTION 07 HANDLING AND STORAGE -------------------------------------------------------------------------- -------------------------------------------------------------------------- STORAGE REQUIREMENTS: Store in clean, dry locations away from excessive heat. Store in areas designated for the storage of flammable liquids according to NFPA 30 (Flammable and Combustible Liquids Code) HANDLING PRECAUTIONS: Wash throughly after handling. Do not get into eyes, on skin, or on clothing. ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ SECTION 08 EXPOSURE CONTROLS AND PERSONAL PROTECTION ENGINEERING CONTROLS: Eye wash station and safety shower. VENTILATION: General ventilation. Material non-volatile. PERSONNEL PROTECTIVE EQUIPMENT EYE: Chemical splash goggles with indirect or no ventilation. SKIN: Chemical resistant gloves such as nitrile. RESPIRATORY: Wear organic vapor respirator if vapors are a nuisance or if concentrations are above PEL/TLV. COMMENTS: Never eat, drink, or smoke in work areas. ====================---=========== ==================================== SECTION 09 PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT: BT 148 - 212 F SPECIFIC GRAVITY: BT 0.791 - 1.000 VAPOR PRESSURE: < 96 VAPOR DENSITY: < 1.11 EVAPORATION RATE: < 2 SOLUBILITY IN WATER: Completely. ODOR/APPEARANCE/CHARACTERISTICS: Blue liquid, no odor. ===================--==================--================--====================== SECTION 10 STABILITY AND REACTIVITY ============================================================================== STABILITY: Material is stable POLYMERIZATION: Hazardous polymerization cannot occur. CHEMICAL INCOMPATIBILITIES: Strong oxidizing and reducing agents. CONDITION TO AVOID: Excessive heat and open flame. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, and carbon dioxide. ==================================== ===================================== SECTION 11 TOXICOLOGICAL INFORMATION ___________________LD50_____________________ Methanol: 5.6 g/kg (oral), 15.8 g/kg (dermal) . """"..,_._'..,"~.~__"".M.._.'.'",.~_~'_..,~._...__.._~___..,.--._~......._-_.__.._- =================================== ----------------------------------------------------------------------- ------------------------------------------- SECTION 12 ECOLOGICAL INFORMATION No data. ===================--========================================--============= ----------------------------------------------- --------------------------------------------- SECTION 13 DISPOSAL CONSIDERATIONS As a waste, this product in its raw form =DOES MEET= the criteria of a hazardous waste as defined by RCRA (40CFR361). Dispose of in accordance with all applicable state, federal, and local regulations. --------------------------------------------------------------------------- -------------------------------------------------------------------------- ----------------------------------------------------- ----------------------------------------------------- SECTION 14 TRANSPORTATION INFORMATION DOMESTIC: *5016: Consumer Commodity ORM-D. *5001/5005/5055: Methanol Solution, Class 3.2, UN1230, PGII EXPORT: *5016: Methanol Solution, Class 3.2, UN1230, 6.1, Page 3251, FP 50 deg. F, Limited Quantity. *5001/5005/5055: Methanol Solution, Class 3.2, UN1230, 6.1, Page 3251, FP 50 deg. F. -------------------------------------------------------------------- -------------------------------------------------- ---------------------------------------------------------- --------------------------------------------------------------------------- SECTION 15 REGULATORY INFORMATION U. S. FEDERAL REGULATIONS OSHA: Considered hazardous material as defined by 29CFR1910.1200 EPA SARA TITLE III: -Section 311-312 (40CFR370): If stored in excess of the threshold quantities, this product should be reported as a(n): *IMMEDIATE (acute) HEALTH HAZARD *DELAYED (chronic) HEALTH HAZARD *FlRE HAZARD -Section 313 (40CFR372): This product contains ingredients which are subject to the reporting requirements of SARA 313: *Methanol STATE REGULATIONS CALIFORNIA PROPOSITION 65: This product does not contain ingredients which are on the current Proposition 65 list. NEW JERSEY RIGHT-TO-KNOW: This product contains the following ingredients, which are non-hazardous, but are among the top five ingredients in this product: -----CAS#----- 7732-18-5: WATER ------------------------------------------------------------------------- ------------------------------------------------------------------------- ------------------------------------------------------------------------------ ------------------------------------------------------------------------- SECTION 16 OTHER INFORMATION REVISION: 2 NOTES: *NG="NOT GIVEN" *BT="BETWEEN" *<="LESS THAN" *>="GREATER THAN" USER'S RESPONSIBILITY: This MSDS provides environmental, health and safety information. This product is to be used in applications consistent with our product literature and container label. Individuals handling this product should be informed to the recommended safety precautions and have access to this MSDS. Please contact your local sales representative or our Environmental, Health and Safety Department for further information. END OF MSDS IMPORTANT: Read this MSDS before handling or disposing of this product and pass this information on to emplovees, customers and users of this product. Emergency Overview Physical State Semi-solid to solid (buttery texture). Color Amber to dark amber. Odor Mild petroleum odor WARNINGI If stored or applied via high-pressure grease gun, a potential skin injection hazard may exist. Injection under the skin can cause severe injury. Most damage occurs in the first few hours. Initial symptoms may be minimal. Hot grease will cause thermal burns upon contact. This product can cause mild skin irritation and inflammation Spills may create a slipping hazard. Service Pro Premium EP-2 Lithium Grease Material Safety Data Sheet Association of Independent Oil Distributors P.O. Box 1861 Montrose, CO 81402-1861 MSDS No. 631140386097 Revision Date 04/19/2005 Hazard Rankings Health Hazard Fire Hazard Reactivity HMIS 1 1 o NFPA o 1 o . = Chronic Health Hazard PROTECTIVE EQUIPMENT Minimum Recommended See Section 8 for Details oa~t SECTION 1: IDENTIFICATION Trade Name Product Number CAS Number Product Family Synonyms Service Pro Premium EP-2 Lithium Grease 631140386097 Mixture. Lubricating Grease Lubricating grease; Service Pro SAP Product Code No.: 631140386097 Technical Contact (800) 313-2463 Medical Emergency CHEMTREC Emergency (United States Only) SECTION 2: COMPOSITION Component Name(s) 1) Distillates, petroleum, hydrotreated heavy naphthenic 2) Distillates, petroleum, solvent-refined heavy paraffinic 3) Residual oils, petroleum, solvent-refined 4) Lithium Carboxylate Soap 5) Raffinate, low-asphaltene vacuum residues 6) Proprietary Ingredients 7) Zinc alkyldithiophosphate 8) Olefin sulfide CAS Registry No. 64742-52-5 64741-88-4 64742-01-4 Proprietary 164907-77-1 Proprietary Mixture 68649-42-3 Proprietary SECTION 3: HAZARDS IDENTIFICATION Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS. Major Route(s) of Entry Skin contact. MSDS No. 631140386097 Revision Date 04/19/2005 Continued on Next Page (800) 313-2463 (800) 424-9300 Concentration (%) 20 - 40 30-50 10 - 30 1 - 15 0-5 0-5 0-2 0-1 Page Number: 1 Service Pro Premium EP-2 Lithium Grease Inhalation Signs and Symptoms of Acute Exposure Eye Contact Skin Contact Ingestion Chronic Health Effects Summary Conditions Aggravated by Exposure Target Organs Carcinogenic Potential No significant adverse health effects are expected to occur upon short-term exposure at ambient temperatures. If heated above its flash point, this product's vapors may cause respiratory tract irritation. Repeated or prolonged overexposure to product mists can result in respiratory tract inflammation and an increased risk of infection. This material can cause mild eye irritation from contact with product or product mists. This material can cause mild skin irritation from prolonged or repeated skin contact. Injection under the skin can cause inflammation and swelling. Injection of pressurized hydrocarbons can cause severe, permanent tissue damage. Initial symptoms may be minor. Injection of petroleum hydrocarbons requires immediate medical attention. Skin contact with hot material may result in severe burns. This material can cause a laxative effect. If swallowed in large quantities, this material can obstruct the intestine. Contains a petroleum-based mineral oil. Prolonged or repeated skin contact can cause mild irritation and inflammation characterized by drying, cracking, (dermatitis) or oil acne. Repeated or prolonged inhalation of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause respiratory irritation or other pulmonary effects. Medical conditions aggravated by exposure to this material may include pre-existing skin disorders. This material may cause damage to the following organs: skin. This product does not contain any components at concentrations above 0.1 % which are considered carcinogenic by OSHA, IARC or NTP. OSHA Hazard Classification is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present the product does not exhibit the hazard as defined in the OSHA Hazard Communication Standard 29 CFR 1910.1200 . OSHA Health Hazard Classification OSHA Ph sical Hazard Classification Irritant 0 Toxic 0 Combustible 0 Ex losive 0 ro horic 0 Sensitizer 0 Hi hi Toxic 0 Flammable 0 Oxidizer 0 Water-reactive 0 Corrosive 0 Carcino enic 0 Com ressed Gas 0 Or anic Peroxide 0 Unstable 0 SECTION 4: FIRST AID MEASURES Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid. For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS. Inhalation Eye Contact Skin Contact Ingestion Notes to Physician Vaporization is not expected at ambient temperatures. This material is not expected to cause inhalation-related disorders under anticipated conditions of use. In case of overexposure, move the person to fresh air. Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water while occasionally lifting and lowering eyelids. Seek medical attention if excessive tearing, redness, or pain persists. If bumed by hot material, cool skin by quenching with large amounts of cool water. Remove contaminated shoes and clothing. Wipe off excess material. Wash exposed skin with mild soap and water. Seek medical attention if tissue appears damaged or if pain or irritation persists. Thoroughly clean contaminated clothing before reuse. Discard contaminated leather goods. If material is injected under the skin, seek medical attention immediately. Do not induce vomiting unless directed to by a physician. Do not give anything to drink unless directed to by a physician. Never give anything by mouth to a person who is not fully conscious. Seek medical attention immediately. In the event of injection in underlying tissue, immediate treatment should include extensive incision, debridement and saline irrigation. Inadequate treatment can result in ischemia and gangrene. Early symptoms may be minimal, immediate treatment should include extensive incision, debridement and MSDS No. 631140386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 2 Service Pro Premium EP-2 Lithium Grease saline irrigation. Inadequate treatment can result in ischemia and gangrene. Early symptoms may be minimal. SECTION 5: FIRE FIGHTING MEASURES NFPA Flammability NFPA Class-IIIB combustible material. Slightly combustible! Classification Flash Point Method OPEN CUP: >2000C (>3920F) (Estimated). Lower Flammable limit Autoignition Temperature Hazardous Combustion Products Special Properties No data. Upper Flammable limit No data. Not available. Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and trace oxides of sulfur, phosphorus, zinc and/or nitrogen. Fight the fire from a safe distance in a protected location. Open any masses with a water stream to prevent reignition due to smoldering. Cool surface with water fog. Molten material can form flaming droplets if ignited. Water or foam can cause frothing. Use of water on product above 1000C (2120F) can cause product to expand with explosive force. Do not allow liquid runoff to enter sewers or public waters. Extinguishing Media Use dry chemical, foam, Carbon Dioxide or water fog. Protection of Fire Fighters Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained breathing apparatus to protect against potential hazardous combustion or decomposition products and oxygen deficiencies. SECTION 6: ACCIDENTAL RELEASE MEASURES Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For more specific information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal Protection in Section 8 and Disposal Considerations in Section 13 ofthis MSDS. Do not touch damaged containers or spilled material unless wearing appropriate protective equipment. Slipping hazard; do not walk through spilled material. Stop leak if you can do so without risk. For small spills, absorb or cover with dry earth, sand, or other inert non-combustible absorbent material and place into waste containers for later disposal. Contain large spills to maximize product recovery or disposal. Prevent entry into waterways or sewers. In urban area, cleanup spill as soon as possible. In natural environments, seek cleanup advice from specialists to minimize physical habitat damage. This material will float on water. Absorbent pads and similar materials can be used. Comply with all laws and regulation. Handling SECTION 7: HANDLING AND STORAGE Storage If this product is stored or applied in high-pressure systems such as grease guns or hydraulic lines, there is the potential for accidental injection into the skin and underlying tissues. Hydrocarbons injected into skin or underlying tissues are not readily removed by body fluids and can cause pain, swelling, chemical irritation, infection and tissue destruction. Early symptoms may be minimal. Workers must be aware of the significant hazards associated with a hydrocarbon injection injury. In the event of an injection injury, workers should seek medical treatment immediately. Avoid water contamination and elevated temperatures to minimize product degradation. Empty containers may contain product residues that can ignite with explosive force. Do not pressurize, cut, weld, braze solder, drill, grind or expose containers to flames, sparks, heat or other potential ignition sources. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers and/or waste residues of this product. Keep container closed. Do not store with strong oxidizing agents. 00 not store at temperatures above 1200 F or in direct sunlight for extended periods of time. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers or waste residues of this product. MSDS No. 631140386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 3 Service Pro Premium EP-2 Lithium Grease SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION Engineering Controls Ventilation controls are not normally required under anticipated conditions of use. Provide exhaust ventilation or other engineering controls if airborne mists or vapors concentrations exceed recommended occupational exposure limits listed below. An eye wash station and safety shower should be located near the work-station. Personal Protective Equipment Personal protective equipment should be selected based upon the conditions under which this material is used. A hazard assessment of the work area for PPE requirements should be conducted by a qualified professional pursuant to OSHA regulations. The following pictograms represent the minimum requirements for personal protective equipment. For certain operations, additional PPE may be required. oo~t Eye Protection Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. Wear goggles and/or face shield if splashing or spraying is anticipated. Wear goggles and face shield if material is heated above 1250F (510C). Have suitable eye wash water available. Hand Protection Use gloves constructed of chemical resistant materials such as neoprene or heavy nitrile rubber if frequent or prolonged contact is expected. Use heat-protective gloves when handling product at elevated temperatures. Body Protection Use clean and impervious protective clothing (e.g., neoprene or Tyvek@) if splashing or spraying conditions are present. Protective clothing may include long-sleeve outer garment, apron, or lab coat. If significant contact occurs, remove oil-contaminated clothing as soon as possible and promptly shower. Launder contaminated before reuse or discard. Wear heat protective boots and protective clothing when handling material at elevated temperatures. Respiratory Vaporization is not expected at ambient temperatures. Therefore, the need for respiratory protection is Protection not anticipated under normal use conditions and with adequate ventilation. If elevated airborne concentrations above applicable workplace exposure levels are anticipated, a NIOSH-approved organic vapor respirator equipped with a dust/mist prefilter should be used. Protection factors vary depending upon the type of respirator used. Respirators should be used in accordance with OSHA requirements (29 CFR 1910.134). General Comments Use good personal hygiene practices. Wash hands and other exposed skin areas with plenty of mild soap and water before eating, drinking, smoking, use of toilet facilities, or leaving work. DO NOT use gasoline, kerosene, solvents or harsh abrasives as skin cleaners. Since specific exposure standards/control limits have not been established for this product, the "Oil Mist, Mineral" exposure limits shown below are suggested as minimum control guidelines. Occupational Exposure Guidelines Substance 1) Oil Mist, Mineral Applicable Workplace Exposure Levels ACGIH (United States). TWA: 5 mg/m3 STEL: 10 mg/m3 OSHA (United States). TWA: 5 mg/m3 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Physical State Semi-solid to solid. Color Amber to dark amber. Odor (buttery texture) Mild petroleum odor Specific Gravity <1 (Water = 1) pH Not Applicable. Vapor Density >10 (Air = 1) Boiling Point/Range Not available. Melting/Freezing Not available. Point Vapor Pressure Not applicable. Viscosity (cSt @ 40oC) Not applicable. MSDS No. 631140386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 4 Service Pro Premium EP-2 Lithium Grease Solubility in Water Insoluble in cold water. Volatile Characteristics Negligible volatility Additional Properties NLGI Grade = 2 Thickener = Lithium Texture = Buttery SECTION 10: STABILITY AND REACTIVITY Chemical Stability Stable. Hazardous Polymerization Not expected to occur Conditions to Avoid Keep away from extreme heat, sparks, open flame, and strongly oxidizing conditions. Materials Incompatibility Hazardous Decomposition Products Strong oxidizers. No additional hazardous decomposition products were identified other than the combustion products identified in Section 5 of this MSDS. SECTION 11: TOXICOLOGICAL INFORMATION For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification in Section 3 of this MSDS. Toxicity Data Distillates, petroleum, hydrotreated heavy naphthenic: ORAL (LD50): Acute: >5000 mg/kg [Rat]. DERMAL (LD50): Acute: >2000 mglkg [Rabbit]. Distillates, petroleum, solvent-refined heavy paraffinic: ORAL (LD50): Acute: >5000 mg/kg [Rat]. DERMAL (LD50): Acute: >2000 mglkg [Rabbit]. Residual Oils, petroleum, solvent-refined light paraffinic: ORAL (LD50): Acute: >5000 mg/kg [Rat]. DERMAL (LD50): Acute: >2000 mglkg [Rabbit]. Distillates, petroleum, hydrotreated heavy paraffinic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. Distillates, petroleum, solvent-refined heavy paraffinic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested. Analyses conducted by method IP 346 indicate that the polycyclic aromatic concentration of this mineral oil is below 3.0 weight percent. Residual Oils, petroleum, solvent-refined: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested Raffinate, low-asphaltene vacuum residues: This product contains petroleum resins and vacuum residuum. Vacuum residuum did not result in tumor production in two-year mouse skin-painting bioassays. MSDS No. 631140386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 5 Service Pro Premium EP-2 Lithium Grease Greases: Injection of pressurized hydrocarbons under the skin, in muscle or into the blood stream can cause irritation, inflammation, swelling, fever, and systemic effects, including mild central nervous system depression. Injection of pressurized hydrocarbons can cause severe, permanent tissue damage. Ecotoxicity SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity data are not available for this product. Environmental Fate An environmental fate analysis has not been conducted on this specific product. Plants and animals may experience harmful or fatal effects when coated with petroleum-based products. Petroleum-based (mineral) lube oils will normally float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway can result in a loss of marine life or create an anaerobic environment. This material contains phosphorus which is a controlled element for disposal in effluent waters in most sections of North America. Phosphorus is known to enhance the formation of algae. Severe algae growth can reduce oxygen content in the water possibly below levels necessary to support marine life. SECTION 13: DISPOSAL CONSIDERATIONS Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent materials and residues at the time of disposition. Conditions of use may cause this material to become a "hazardous waste", as defined by federal or state regulations. It is the responsibility of the user to determine if the material is a RCRA "hazardous waste" at the time of disposal. Transportation, treatment, storage and disposal of waste material must be conducted in accordance with RCRA regulations (see 40 CFR 260 through 40 CFR 271). State and/or local regulations may be more restrictive. Contact the RCRAlSuperfund Hotline at (800) 424-9346 or your regional US EPA office for guidance concerning case specific disposal issues. SECTION 14: TRANSPORT INFORMATION DOT Status Not a U.S. Department of Transportation regulated material. Proper Shipping Name Hazard Class Packing Group(s) UN/NA 10 Reportable Quantity Placards HAZMA T STCC No. MARPOL III Status Not regulated. Not regulated. Not applicable. Not regulated. A Reportable Quantity (RQ) has not been established for any components of this material. ~ Emergency Response Guide No. Not applicable. Not assigned. Not a DOT "Marine Pollutant" per 49 CFR 171.8. SECTION 15: REGULATORY INFORMATION TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory. SARA 3021304 SARA 311/312 The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to Subparts 302 and 304 to submit emergency planning and notification information based on Threshold Planning Quantities (TPQs) and Reportable Quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355. No components were identified. The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to this subpart to submit aggregate information on chemicals by "Hazard Category" as defined in 40 MSDS No. 631140386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 6 Service Pro Premium EP-2 Lithium Grease CFR 370.2. This material would be classified under the following hazard categories: No SARA 311/312 hazard categories identified. SARA 313 This product contains the following components in concentrations above de minimis levels that are listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section 313 of SARA: No components were identified. CERCLA The Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) requires notification of the National Response Center concerning release of quantities of "hazardous substances" equal to or greater than the reportable quantities (RQ's) listed in 40 CFR 302.4. As defined by CERCLA, the term "hazardous substance" does not include petroleum, including crude oil or any fraction thereof which is not otherwise specifically designated in 40 CFR 302.4. Chemical substances present in this product or refinery stream that may be subject to this statute are: Zinc and Zinc Compounds, Concentration: 0 - 2%. CWA This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. New Jersey Right-to-Know Label This material may contain the following components which are known to the State of California to cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of Califomia Proposition 65 (CA Health & Safety Code Section 25249.5): Toluene: 0.0004% Petroleum Oil California Proposition 65 Additional Regulatory Remarks No additional regulatory remarks. SECTION 16: OTHER INFORMATION Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product. REVISION INFORMATION Version Number 2.2 Revision Date 04/19/2005 Print Date Printed on 04/19/2005. ABBREVIATIONS AP: Approximately EO: Equal >: Greater Than <: Less Than NA: Not Applicable NO: No Data NE: Not Established ACGIH: American Conference of Governmental Industrial Hygienists IARC: Intemational Agency for Research on Cancer NIOSH: National Institute of Occupational Safety and Health NPCA: National Paint and Coating Manufacturers Association NFPA: National Fire Protection Association AIHA: American Industrial Hygiene Association NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration HMIS: Hazardous Materials Information System EPA: US Environmental Protection Agency DISCLAIMER OF LIABILITY THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME MSDS No. 631140386097 Revision Date 04/19/2005 Continued on Next Page Page Number: 7 Service Pro Premium EP-2 Lithium Grease RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. * * * * * END OF MSDS * * * * * MSDS No. 631140386097 Revision Date 04/19/2005 Page Number: 8 Lubrication Technologies Material Safety Data Sheet Lubrication Technologies, Inc. 900 Mendelssohn Avenue North Golden Valley, MN 55427-4309 Emergency: Information: Fax: 800-424-9300 763-545-0707 763-545-9256 SECTION 1 CHEMICAL PRODUCT IDENTIFICATION Product: Synonyms/Other: Part Number: MSDS Number: Product Type: Preparation/Revision Date: ACE AQUA KLEEN ALUMASAFE POWDERED PARTS WASH Not applicable. 111-10400-100LBDR, 111-10400-1 OOLBDR 1769 Powdered parts wash 01/30/2006 SECTION 2 COMPOSITION INFORMATION INGREDIENTS CAS # % OSHA TWA 2 mg/m3 OSHA STEL ACGIH TWA SKIN NO NO NO Sodium metasilicate* Sodium carbonate Sodium tripolyphosphate 6834-92-0 497-19-8 77758-29-4 60-70 20-30 0-5 Comments: * - Exposure level is threshold limit for dust form. TWA - Time Weighted Average is the employee's average airborne exposure in any 8-hour work shift of a 40-hour work week which shall not be exceeded. STEL - Short Tenn Exposure Limit is the employee's 15-minute lime weighted average exposure which shall not be exceeded at any time during a work day unless another lime limit is specified. SECTION 3 HAZARDOUS IDENTIFICATION Ingestion: - CAUSES EYE IRRITATION - CAUSES SKIN IRRITATION - CAUSTIC Irritant. Effects may range from mild to severe burns depending upon length of exposure, solution concentration and first aid measures. Avoid skin contact. This product contains materials that cause skin irritation. Prolonged or repeated contact may result in dermatitis (dryness, chapping and reddening of skin). This material is caustic - overexposure may lead to defatting of skin tissue. Overexposure by inhalation of misted material may cause nonspecific discomfort, such as nausea, burning, headache, or weakness. Caution should be taken to prevent aerosolization or misting of this product without proper respiratory protection. Harmful if swallowed. Ingestion is not expected to be a primary route of exposure. Do not ingest. Product may attack lining of esophogus and stomach. Not applicable. WARNING: Eye contact: Skin contact: Inhalation: Other: SECTION 4 FIRST AID MEASURES Inhalation: Check for and remove contact lenses. Flush immediately with copious amounts of water or normal saline (minimum of 15 minutes), holding eyelids apart to ensure complete irritation of the eye and eyelid tissue. Take exposed individual to a health care professional, preferably an opthalmologist, for further evaluation. Remove contaminated dothing. Wash exposed area with plenty of soap and water. Repeat washing. If redness or irritation occurs, seek medical attention. Wash contaminated clothing before reuse. If exposure by inhalation is suspected, immediately move exposed individual to fresh air. If individual experiences nausea, headache, dizziness, has difficulty breathing or is cyanotic, seek a health care professional immediately. Eye contact: Skin contact: Ace Aqua Kleen Alumasafe Powdered Parts Wash (1769). Page 1 of 6 900 MENDELSSOHN AVE N . GOLDEN VALLEY, MN 55427. PHONE 763-545-0707. FAX 763-545-9256 Lubrication Technologies Material Safety Data Sheet Ingestion: Other: Drink 1-2 large glasses of milk or water. Do not induce vomiting unless directed by a physician. If spontaneous vomiting occurs keep head below hips to prevent aspiration and monitor for breathing difficulty. Gastric lavage should be performed only by qualified medical personnel. Keep affected person warm and at rest. Seek medical attention. Not applicable. SECTION 5 FIRE FIGHTING MEASURES Flash point: Flammable limits: Extinguishing media: Special firefighting procedures: Unusual fire & explosion hazards: Byproducts of combustion: Autoignition temperature: Explosion data: Other: Not flammable. Not applicable. Not applicable. General directions - product will not bum without extreme high temperatures. Evacuate area and fight fire from a safe distance. If leak or spill has not ignited, ventilate area and use water spray to disperse gas or vapor and to protect personnel attempting to stop a leak. Use water spray to cool adjacent structures and to protect personnel. Shut off source of flow if possible (safely). Stay away from storage tank ends. Withdraw immediately in case of rising sound from venting safety device or any discoloration of storage tank due to fire. Fire fighters must wear MSHAlNIOSH approved positive pressure breathing apparatus (SCBA) with full face mask and full protective equipment. High temperatures may create heavy flammable vapors that may settle along ground level and low spots to create an invisible fire hazard. When wet contact with metal can form hydrogen gas that is flammable and can form explosive mixtures with air. Fires and high temperatures involving this product may release oxides of carbon and nitrogen; reactive hydrocarbons and irritating vapors. Not applicable. Not determined. Care should always be exercised in dust/mist areas. Not applicable. SECTION 6 ACCIDENTAL RELEASE MEASURES Spill control procedures (land): Spill control procedures (water): Initially minimize area affected by the spill or leak. Block any potential routes to water systems (e.g., sewers, streams, lakes, etc.) Based on the product's toxicological and chemical properties, and on the size and location of the spill or leak, assess the impact on contaminated environments (e.g., water systems, ground, air equipment, etc.). There are no methods available to completely eliminate any toxicity this product may have on aquatic environments. Minimize adverse effects on these environments. Recover as much of the pure product as possible into appropriate containers using appropriate equipment. Address clean-up of contaminated environments. Spill or leak residuals may have to be collected and disposed of. Clay, soil or commercially available absorbents may be used to recover any material that can not readily be recovered as pure product if dissolved in a solvent. Flushing residual material to an industrial sewer, if present at the site of a spill or leak incident MAY be acceptable if authorized (local sewer) approval is obtained. If product residuals are flushed to an industrial sewer, insure that they do not come into contact with incompatible materials. Contact the person(s) responsible for the operation of your facility's industrial sewer system prior to intentionally flushing or pumping spills or leaks of this product to the industrial sewer. This material readily mixes with water - a spill will not be contained with booms Ace Aqua Kleen Alumasafe Powdered Parts Wash (1769). Page 2 of 6 900 MENDELSSOHN AVE N . GOLDEN VALLEY, MN 55427. PHONE 763-545-0707. FAX 763-545-9256 Lubrication Technologies Material Safety Data Sheet Waste disposal method: Other: or be able to be removed by skimming water surface. This material may be toxic to aquatic life (see Section 11 and 12). If a large spill occurs notify appropriate authorities (normally the National Response Center or Coast Guard at 800-424-8802). Determine if waste containg this product can be handled by available industrial effluent system or other on-site waste management unit. If off-site management is required, contact a company experienced in industrial waste management. This product is not specifically listed in 40 CFR 261 as a Resource Conservation and Recovery Act (RCRA) waste. However, spill or leak residuals may meet the criteria of a characteristic hazardous waste under RCRA. Check the characteristic of used, spill or leak material to be disposed of to verify RCRA exempt. CAUTION - If spilled material is cleaned up using a regulated solvent, the resulting waste mixture will be regulated. SECTION 7 HANDLING AND STORAGE Handling procedures: Storage procedures: Additional information: Keep containers closed when not in use. Do not transfer to unmarked containers. Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld, or use for any other purposes. Return drums to reclamation centers for proper cleaning and reuse. Open containers carefully in a well ventilated area or use appropriate respiratory protection. Wash thoroughly after handling. Store containers away from heat, sparks, open flame, or oxidizing materials. Product should be stored between 40 and 90oF. Extended storage at excessive temperatures may produce odorous and toxic fumes from product decomposition. No additional information. SECTION 8 EXPOSURE CONTROLS I PERSONAL PROTECTION Personal protection: Respiratory protection: Eye protection: Hand protection: Other protection: Local control measures: Other: Applicable mainly to persons in repeated contact situations such as packaging of product, service/maintenance, and cleanup/spill control personnel. None required if airbome concentrations are maintained below threshold limits listed on page one. Otherwise a respiratory protection program meeting OSHA 1910.134 and ANSI Z88.2 requirements must be followed. Where misting may occur, wear an MSHAlNIOSH approved (or equivalent) half-mask form dust/mist air purifying respirator. Eye protection is strongly recommended. If material is handled such that it could be splashed into the eyes, wear safety glasses with side shields or vented/splash proof goggles (ANSI Z87.1 or approved equivalent). Impervious gloves such as neoprene or nitrile rubber to avoid skin sensitization and absorption. Use of an apron and overboots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin sensitization and absorption. If handling hot material use insulated protective equipment. Launder soiled clothes. Properly dispose of contaminated leather articles and other materials which cannot be decontaminated. Use adequate ventilation when working with material in an enclosed area. Mechanical methods such as fume hoods or area fans may be used to reduce localized vapor/mist areas. If vapor or mist is generated when the material handled, adequate ventilation in accordance with good engineering practice must be provided to maintain concentrations below the specifed exposure. Eyewash stations and showers should be available in areas where this material is used and stored. Consumption of food and drink should be avoided in work areas where product is present. Always wash hands and face with soap and water before eating, drinking or smoking. Ace Aqua Kleen Alumasafe Powdered Parts Wash (1769). Page 3 of 6 900 MENDELSSOHN AVE N. GOLDEN VALLEY, MN 55427. PHONE 763-545-0707. FAX 763-545-9256 Lubrication Technologies Material Safety Data Sheet SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Vapor pressure: Solubility: Percent volatile: Vapor density (air=1): Evaporation rate (n-Butyl Acetate=1): Odor: Appearance: Viscosity: Boiling point: Pour/Freeze point: Other: Not applicable. Partially miscible in water - requires agitation. Not applicable. >1. Not applicable. No noticable odor. White, granular powder. Not determined. Not determined. Not determined. pH of concentrate: not applicable.. pH (1% solution): -11.7. SECTION 10 STABILITY AND REACTIVITY Stability: Conditions to avoid: Incompatibility with other materials: Decomposition products: Hazardous polymerization: Other: Material is stable at room temperatures and pressure. Avoid high temperatures and product contamination. Avoid contact with acids and oxidizing materials. Smoke, carbon monoxide and dioxide, and other aldehydes of incomplete combustion. Oxides of carbon and nitrogen; reactive hydrocarbons and irritating vapors. Will not occur. Not applicable. SECTION 11 TOXICOLOGICAL INFORMATION Oral toxicity: Dermal toxicity: Inhalation toxicity: Dermal sensitization: Chronic toxicity: Carcinogenicity: Mutagenicity: Reproductive toxicity: Other: Not determined. This material is caustic and will destroy skin tissue during prolonged contact. Based upon data from similar materials. Not determined. Prolonged or repeated contact may make skin more sensitive to other skin sensitizers. Not determined. The known components of this material are not listed by IARC, NTP, OSHA or ACGIH as known or suspected carcinogens. Not determined. Not determined. Not applicable. SECTION 12 ECOLOGICAL INFORMATION Environmental toxicity: Environmental fate: Other: This material may be toxic to aquatic organisms and should be kept out of sewage and drainage systems and all bodies of water.. Not determined. Not applicable. SECTION 13 DISPOSAL CONSIDERATIONS Waste disposal: Disposal consideration: Under RCRA it is the responsibility of the user of the product to determine at the time of disposal whether the product meets RCRA criteria for hazardous waste. This product unadulterated by other materials may be dassified as a non- regulated waste in some areas - but still needs to be disposed of at approved facilities. Waste management should be in full compliance with federal, state, and local laws. Determine if waste containg this product can be handled by available industrial Ace Aqua Kleen Alumasafe Powdered Parts Wash (1769). Page 4 of 6 900 MENDELSSOHN AVE N. GOLDEN VALLEY, MN 55427. PHONE 763-545-0707. FAX 763-545-9256 Lubrication Technologies Material Safety Data Sheet Other: effluent system or other on-site waste management unit. If off-site management is required, contact a company experienced in industrial waste management. This product is not specifically listed in 40 CFR 261 as a Resource Conservation and Recovery Act (RCRA) waste. However, spill or leak residuals may meet the criteria of a characteristic hazardous waste under RCRA. Check the characteristic of used, spill or leak material to be disposed of to verify RCRA exempt. Look in a local telephone directory or internet for headings under, 'Waste', 'Waste Services', 'Waste Disposal' for companies licensed to handle such material. Additional information can be obtained from local EPA, DNR, Sewer and Land-Fill sites. Unused, packaged fluids may be donated to other companies or charities (fluids MUST be unused). The transportation, storage, treatment and disposal of RCRA waste material must be conducted in compliance with 40 CFR 262, 263, 264, 268 and 270. Disposal can only occur in properly permitted facilities. Check state and local regulations for any additional requirements as these may be more restrictive than federal laws and regulations. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. Disposal of this material must be conducted in compliance with all federal, state, and local regulations. SECTION 14 TRANSPORT INFORMATION U.S. DOT shipping description: U.S. DOT identification number: u.S. DOT hazard classification: Packaging class: Other: Corrosive solid, basic, inorganic, n.o.s., (disodium trioxosilicate), UN3262 8 III Not applicable. SECTION 15 REGULATORY INFORMATION Clean water act/oil pollution act: TSCA: Other TSCA: SARA Title III: CERCLA: Other: No components of this product are listed. All components of this material are listed in the U.S. TSCA Inventory. Not applicable. Section 3021304 extremely hazardous substances: None. Section 311,312 hazard categorization: Acute (immediate health effects): Chronic (delayed health effects): Fire (hazard): Reactivity (hazard): Pressure (sudden release hazard): Section 313 toxic chemicals: No materials present are listed under SARA 313. For stationary/moving sources - reportable quantity (due to): Not regulated. Not applicable. YES NO NO NO NO SECTION 16 OTHER INFORMATION HEALTH: FIRE: REACTIVITY: SPECIFIC HAZARD: PROTECTION INDEX: Precautionary labels: NFPA 704 2 o 1 NONE N/A NPCA-HMIS 2 o 1 N/A B KEY o = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe - CAUSES EYE IRRITATION Ace Aqua Kleen Alumasafe Powdered Parts Wash (1769). Page 5 of 6 900 MENDELSSOHN AVE N . GOLDEN VALLEY, MN 55427 . PHONE 763-545-0707 . FAX 763-545-9256 Lubrication Technologies Material Safety Data Sheet - CAUSES SKIN IRRITATION - CAUSTIC External information: This product may be formulated in part with components purchased from other companies. In many instances, especially when proprietary or trade secret materials are used. Lube-Tech must rely upon information provided by those materials manufacturers or distributors. Creation date: File: Version: 07/23/20003 Ace Aqua Kleen Alumasafe Powdered Parts Wash (1769) I INFORMATION PROVIDED IN THIS MSDS IS CONSIDERED ACCURATE AND RELIABLE BASED ON INFORMATION ISSUED FROM INTERNAL AND OUTSIDE SOURCES TO THE BEST OF LUBE-TECH'S KNOWLEDGE HOWEVER. LUBE-TECH MAKES NO REPRESENTATIONS. GUARANTEES OR WARRANTIES, EXPRESSED OR IMPLIED. OF MERCHANTABILITY OR FITNESS FOR THE PARTICULAR PURPOSE. REGARDING THE ACCURACY OF SUCH INFORMATION OR THE RESULT TO BE OBTAINED FROM THE USE THEREOF, OR AS TO THE SUFFICIENCY OF THE INFORMATION HEREIN PRESENTED. LUBE-TECH ASSUMES NO RESPONSIBILITY FOR INJURY TO RECIPIENT OR TO THIRD PERSONS OR FOR ANY DAMAGE TO ANY PROPERTY AND RECIPIENT ASSUMES ALL SUCH RISKS. Revisions / Comments: Ace Aqua Kleen Alumasafe Powdered Parts Wash (1769). Page 6 of 6 900 MENDELSSOHN AVE N. GOLDEN VALLEY. MN 55427. PHONE 763-545-0707. FAX 763-545-9256