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Home My WebLink AboutBuilding Permit 08-0875 5 Cl ❑ n O�❑❑O❑ = O o zc? y � O N�,-�„�, o � v o� m n n � $ -iza, co z m � mp 0 D o �� 3 m��3Z� m � y n� b � � �� 7C m Z SZpZ Z tn "^�� e r -�i � > Z � o�- � z� -� m ro � N N � � z O eo 'n -� � � � a o � mm � � � D � � '� r � m � p � ❑OO�OO m m m m '��y�3� c c � Z � o o � x �� R�1 O n � C v � � � Z c�i = O l c�i 3 � m �e m a =' ��go � � � v �� o z z�� z � Z � m �'° � o 0 � A � l� _ m � c � � y � ❑aooa❑ y � � �1 ?t n � a � D � r � � � � m a "'�c� � c �mm?r � -� c m Nx� Z� m -.I r � � �'" ) ,�,�� t � tp �'�, t'CTY C)� �'iZ10I2 LAKE 13Ut[..l)ING PERMIT, Date ftec'd �� TEM1'()12Al2Y CF,I2Tt�'It'A7'F t7F ZONiNG COMPLIANCE /O c� �� `�' �' ANI) LJTtLITY CONNECTION PERMIT � ;�� `�'NE� l. Whi[e File pERMIT NO . 2. pink Ciry D�f. U� _S 7 i. Yellow Applicant v (Ptease t or rint and si rt at bottom ADDRESS �� 8 �°t /C �JrYI�,. !/'�' . -��. ZONING (oFl�ce �5e) /v pr� �.t�fi��. /'Zi'/r/ � �—� LEGAL DESCRIPTION (office use only) LOT BLOCK ADDITION PID ��i �J 6 C.- Q� L./ � a plQ D�iER ISlC E (Phone) �� y�7— � 773 CG��r�rrE (ad�ress) /�o � 0 fi(/-Q� c v2 S'�. r�o�- L at�c i✓ BUTLDER (Company Name)�i'� s��S'�on�e �nS�ruc�iBrl ��Qttl1�V __ (Phone) q��2 — �{q(o - ' a a 7 (Contact Name) �s e j^�i�� C.l �Y1i'�'Z (Phone) 9✓�a — �� '— a � � 7 (Address) Jr00 J l c�YSG�`li l! Cc�. Jcc� �Q ,�� ,S'� `/7'l^/ ✓-�S3 7 TYPE �F WORK al New Construction ❑Deck ❑Porch ❑Re-Roofing ❑Re-Siding ❑Lower L,evel Finish ❑ Fueplace �[�Addition �Alteration �Utility Connection CODE: DI.R.C. `� I.B,C. � Te�ran-� F'n�sl� Type of Constractiod: I � III IV Y A� ,� / Occupancy Group: A B E F H I M R m U PROJECT COST/VALUE S�� Q� W! Division: � 2 3 4 5 (exclnding land) /lfet/� , cr I hereby certify that I have fumished infamation on this applicaaon which is to the best of my knowledge true and correct. I aiso certify that I am the owner or authorized a�ent for the above-mentione and that all s ction will mnf to all existing state and loral laws and will proaed in aocordance with submitted plans. I am aware thaz the building official can rev 't fm just Fu e�nore by agee that the city offiaa! or a designee may enter upon We p�nperty ro perForm needed inspecYi�s. X __ ' s �J/� � Q o Signature Contractor's License No. D te � Permit Valuation �—� _ Pazk Suppor[ Fee # $ Permit Fee $ ZS � SAC # $ Plan Check Fee $ ��. Z � Water Meter Size 5/8"; 1"; $ State Surcharge $ —p Pressure Reducer $ � Penalty $ Sewer/ Water Connection Fee # $ Plumbing Permit Fee $ Watec Tower Fee # $ Mechanical Permit Fee $ Suilder's Deposit $ Sewer & Water Permit Fee $ Other $ Gas Fireplace Permi�t Fee $ TOTAL DUE `D ,1ip� V $ �� 7 �� This li ti eco Your BuiCd'wg Permit n AQ oved Paid l 7 21 t NO. 9 � Date , 1, (p Zo � � 13uitdin O � ate Iriis is to certify that the request in the above appiicaaon and accompanying documents is in accordance with the City Zoning Chdinance and may groceed as requested. This document when signed by the ity Planuer rnnsdtures a temporary Certificare of Zoning c�ompliance and allows rnnstruction to mmmence. Before occupancy, a Cecti6qte of Occupancy mast be issued. �U � ��'^ � _ _ _---- ---._—___ .__-__ ------- - _ P ning Director Date Special Condibons, ifany 24 hour notice for sll inspections (952) 447-9850, fu (952) 447-4245 4646 Dakota Street S.E., Prior Lakq Minnesoh 553'I2 w " :, , c ��- ' �:�.� ' O � PRIp� � � �7" U tr� White - Building , .� Canary - Engineering NNESa Pink - Planning �UILDINC PERMIT APPLICATION DEPARTMENT CHECKLIST ` NAME OF APPLICANT ��'!c:-� ,".�'``%��-j« �, . �',.i,, r...�_;:" i�� APPLICATION RECEIVED ��i�, ��° �'�x „�:..��...�....,�.._,...,_,..�.. .�°°"' ."^�°�.��,� The Building, Engineering, and Planning Departments have rev�wed the buitding permit �°-�,� application for construction activity which is proposed at: ,� �~ :�.- �� , ,e � � � � "`/�:. �% � � J.�. t! ,/ ..,� F �i �" � f o' �. �,,,.. �'G,,�� f � �F �:� � �� ,,,... � . � / . � �<,-� � f ` � � � l �'�l`� / =� � Accepted � Accepted With Corrections Denied Reviewed By: Date: ��'� G8 � Comments: ' ;�:�. � "The issuance or granting of a permit or approval of plans, specifications and computations shall not be construed to be a permit for, or an approval of, any violation of any of the provisions of this code or of any other ordinance of the jurisdiction. Permits presuming to give authority to violate or cancel the provisions of this code or other ordinances of the jurisdiction shall not be valid." O � PRIp� � — -- ti �� U � White - Buildmg Canary - ngmeering �In'NESD�P Pink - Planning BUILDING PERMIT APPLICATION DEPARTMENT CHECKLIST NAME OF APPLICANT �I�� (��N� C� N�S �,, APPLiCATION RECEIVED �U. / - �� The Building, Engineering, and Planning Departments have rev' ed the building permit apptication for construction activity which is proposed at: t�� '�� //�� / �L-C:D/"lE �(/�. T�N N % �!/�// Sf� Accepted � Accepted Witl�Corrections Denied Reviewed By: Date: �O z ° °6 Comments: !�I'1 �-��v4r� ��--�'�� 1an.-�-� � d F /��-.�-Y� m fi� � �,� L� ! p � � o s -- �1v2-� d�c�i+.� !� �C��in.i �� ., I I "The issuance or granting of a permit or approval of plans, specifications and computations shall not be construed to be a permit for, or an approval of, any violation of any of the provisions of this code or of any other ordinance of the jurisdiction. Permits presuming to give authority to violate or cancel the provisions of this code or other ordinances of the jurisdiction shall not be valid." � s 4 , D AUTOMOT/VE 16860 Welcome Avenue SE Prior Lake, MN 55372 ' 952-447-7773 To: Bob Hutchens City of Prior Lake From: Chris & Adam Bendzick Pro Service Automotive, Inc. Date: 10/7/2008 � Pro Service Automotive, Inc. has been established for 5 years. Our main goal is to ; provide a customer friendly environment and repair our customers vehicles in a timely fashion. We do anything from fleet maintenance to everyday vehicle repairs. Pro Service Automotive currently employs two mechanics with over 15 years of experience. We are a Napa Auto Care Center and we are also ASE Certified. ; At Pro Service Automotive, Inc. we work on both foreign and domestic cars, trucks, and vans. We also service heavy duty trucks and trailers. Some of the services we provide are vehicle maintenance, computer diagnostics, and brakes. We also proudly install Jasper remanufactured engines and transmissions. Also, we provide services from minor tune- ups to full engine build-ups on classic cars. In addition to all of our many services, we provide a full line of tires to suit our customer's needs. We have provided an extra page of the shop equipment that we use and the inventory that we keep in our shop, along with the Material Safety Data Sheets for the products. We also have a Safety Program through Federated Insurance at our shop with information and training on hazard prevention, personal injury prevention and recovery, OSHA guidelines, and many other topics. VVe are looking forward to moving into the new building with Above All Hardwood Floors and Performance Construction. Thank you so much for your time. Sincerely, Adam Bendzick Chris Bendzick Owner Owner � e 4 �;; D AUTOMOT/VE 16860 Welcome Avenue SE Prior Lake, MN 55372 952-447-7773 Shop Equipment -Computer diagnostic equipment -Hand and specialty tools -Tire changer and balancer -Battery charging and testing equipment -Air compressor -Benches and vises -Four shop bays with vehicle hoists -Transmission and coolant flushing equipment -Waste oil furnace -Tires Office Equipment -Computers -Printers -Phones -Chairs and desks -Misc. office supplies Shop Supplies and Inventory (Please review M5DS Sheets) -Motor Oil (Sw30, Sw20, 1Ow30, 15w40) -Transmission Fluid (ATF, ATF+4, Mercon V) -Brake Fluid, Power Steering Fluid, Gear Oil -Brake Cleaner, Choke & Carb Cleaner, Penetrating Oil -Oil Filters -R 134 Refrigerant -Gas for Welder and Torch -Windshield Wiper Blades -Electrical Supplies -Batteries -Antifreeze .�i/h''`4"c �� az.+ �° � ° $ . � ...i .,� . , .. .,: . ��( .�re�rt . �9 i � . . �lY� Argon Section 1. Chemical product and company identification Product �larne : Argon Suppfier ; AIRGAS INC., on behaif of its subsidiaries 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087�283 1-610-687-5253 Product use : Synthefic/Anaiytical chemistry. MSDS# : 1004 Date of : 3/30/2005. P reparation/Rev is ion In case of emerqencv : 1-800-949-7937 Section 2. Composition, Information on Ingredients Name CAS numbe % Volume Exposure limits Argon 7440-37-1 100 Section 3. Hazards identification Physical state : Gas. (COLORLESS, ODORLESS INERT GAS) Emergency overview : Warning! CONTENTS UNDER PRESSURE. Do not puncture or indnerate cor�tainer. Corrtact with rapidty expanding gases or liquids can cause frostbite. Routes of entry : Inhalation Potential acute health effect Eyes : No known significarrt effects or critical hazards. Skin : No known significant effects or critical hazards. Inhalation : Acts as a simple asphyxiant. Ingestion : Ingestion is not a normal route of exposure for gases Potential chronic health : CARCINOGENIC EFFECTSNot available. effects MUTAGENIC EFFECTS Not available. TERATOGENIC EFFECT: Not available. Medical conditions : Acute or chronic respiratory conditions may be aggravated by overexposure to this gas. aggravated by overexposure See toxicobgical lnformation (section 11) Section 4. First aid measures No adion shall be taken irnrolvir� any personal ►isk or without suitable training.lf fumes are still suspected to be present, the rescuer should wear an appropriate mask or a self-contained breathing apparatus.lt may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical atterrtion if irritation occurs. Skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse, Get medical attention. Frostbite : Try to warm up the frozen tissues and seek medical attention. Inhalation : lf inhaled, remove to iresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. au��a � i Page: 1/5 .. gon I 3�,��z�as� Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear. Section 5. Fire fighting measures Flammability of the product : Non-flammable. Fire fighting media and : Use an extinguishing agent suitable far surrounding fires. instructions If involved in flre, shut off flow immediately if it can be done without risk. Apply water from a safe distance to c�ol container and protect surrounding area. No specific hazard. Special protective : Fire fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full facepiece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Shut off gas supply if this can be done safely. Isolate area until gas has dispersed. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 7. Handling and storage Handling � : Do not puncture or incinerate container. High pressure gas. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not dr�, roll, sfide, or drop. Use a suitable hand truck for cylinder movement. Never allow any unpr�eded part of the body to touch uninsulated pipes or vessels that contain cryogenic liquids. Prevent entrapment of liquid in Gosed systems a piping without pressure relief devices. Some materials may become brittle at low temperatures and will easily fracture. Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or �ing knocked over. Cylinder temperatures should not exceed 52 °C (125 °F}. Section 8. Exposure Controls, Personal Protection Engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. Personal protection Eyes : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists o� dusts. When working with cryogenic liquids, wear a full face shield. Skin : Personal protective equipment for the body should be selected based on the task being pertormed and the risks involved and should be approved by a specialist before handling this product. Respiratory : Use a properly fltted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. The applicable standards are {US) 29 CFR 1910.134 and {Canada) Z94.493 Hands : Chemical-resistant, impervious gloves or gauntlets complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Ir�sulated gloves suitab� for low temperatures 8ufla t.i �ge: tis d • ' x .igOl1 � �€�r ,rsr�� ts�r� 3�•� r:��: R self-contained breathing apparatus shouid be used to avoid inhalation of the product. af � I�rs�� sg�."s�i Consutt local authorities for acceptable exposure limits. Section 9. Physical and chemical properties Molecular weight : 39.95 g/mole Molecular formula : Ar Boilinglcondensation paint : -185.7°C (-302.3°F) Meltinglfreezing point : -189.2°C (-308.6°F) Critica{ temperature : -122.4°C (-188.3°F) Vapor density : 1.38 (Air = 1) Specific Volume (ft'/Ib) : 9.70874 Gas Density (Iblft : 0.103 Physical chemical : Not available. comments Section 10. Stability and reactivity Stability and reactivity : The product is stable. Section 11. Toxicological information Other toxic effects on : No specific information is available in our database regarding the other toxic effects of humans this material for humans. Specific effects Carcinogenic effects : No known significant effects or critical hazards, Mutagenic effects : No known significant�effects or critical hazards. Reproduction toxicity : No known significant effects or critical hazards. Section 12. Ecological information Toxicity of the products of : The product itself and its products of degradation are not toxic. biodegradation Environmental fate : Not available. Environmental hazards : No known significant effects or critical hazards. Toxicity to the environment : Not available. ` Section 13. Disposal considerations Product removed from the cytinder must be disposed of in accordance with appropriate Federal, State, local regulation.Return cytinders with residual product to Airgas, Inc.Do not dispose of locally. Section 14. Transport information Regulatory UN number Proper shipping Ctass Packing group Labef Additional information name information DOT Classification UN1006 ARGON, 2.2 Not applicable (gas). Limited COMPRESSED u n ' Yes. UN1951 Argon, retrigerated pacicaains� ��4u� instn�ction Passeeger AircraR , fluanfity limitation: 75 . k9 a�,,�� ., Page: 3/5 �� r A i' .. gon I Cargo Aircraftl Quantity limitation: 150 � TDG Classification UN1006 ARGON, 2.2 Not applicable (gas). Explosive COMPRESSED Limit and Limited , Quant' UN1951 Argon, refrigerated Index liquid 0.125 Passenaer Carrvin� Road or Rai Index 75 Special - arovisans 42 Mexico UN1006 ARGON, 2.2 Not applicable (gas). - Classification COMPRESSED UN1951 Argon, refigerated liquid Section 15. Regulatory information United States U.S. Federal regulations : TSCA 8(b) inventory: argon SARA 302/304/311/312 eutremely hazardous substances: No products v�nsere found. SARA 302/304 emergency planning and notification: No products were found. SARA 302J304/311/312 hazardous chemicals: argon SARA 311/312 MSDS distributia� - chemical irnentory - hazard identification: argon: Sudden Release of Pressure Clean Water Act (CWA) 307: No produds w�ere faind. Clean Water Ad (CWA) 311: No produc�s w�ere found. Clean air act (CAA) 112 accidental release prevention: No produds were found. Clean air act (CAAj 112 regulated flammable substances: No praiucts were found. Clean air act (CAA) 112 regulated toxic substances: No products were found. State regulations : Pennsylvania RTK: argon: (generic environmental hazard) Massachusetts RTK: argan New Jersey: argon Canada WHMIS (Canada) : Class A: Compressed gas. CEPA DSL: argon Section 16. Other information United States Label Requirements : CONTENTS UNDER PRESSURE. Canada Label Requirements : Glass A: Compressed gas. ., s��G � . � �::. Page: 4/5 ..gon t �iazard+�u� Pb�a�er6a� . ' 1 Ir��a�rna�inn Syst��n (��.5.1�.) a � Reactivity � Personal protection � liquid: e� t e 3 t � �:; f �;: ;i `�' ' . . � . � �. .0..:" . Reactivity ' 0 Personal protection X National Fir+e Protection . Association (U.S.A.) Flammability Health � Instability Special liquid: Flammability Health � Instability Special Notice to reade ' To the best of our knowledge, the infom�ation contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatscever for the accuracy or completeness of the information contained henein. Final determination of suitability of any materiat is the sole responsibility of the user. All materials may present unknown hazards and should be used witl� caution. Allhough certain hazards are described herein, we cannot guarantee that these are the ar�ly hazards that exist. s�,ild 1.1 P8g@: �J � � � �.. ��°` -� � `��x� � � � .. Acetylene Section 1. Chemical product and company identification Froduct Nan�e : Acetylene Supplier : AIRGAS INC., on behalf of its subsidiaries 259 North Radnor-Cheste� Road Suite 100 Radnor, PA 19087-5283 1-610�87-5253 Product use : Synthetic/Analytical chemistry. MSDS# : 001001 Date of : 5/2I2Q07. Preparation/Revision In case of emergency : 1�66-7343438 Section 2. Hazards identification Physical state : Gas. Emergency overview : Warning! FLAMMAB�:E GAS. CONTENTS UNDER PRESSURE. CAUSES DAMAGE TO THE FOLLOWING ORGANS: RESPIRATORY TRACT, CENTRAL NERVOUS SYSTEM. VAPOR MAY CAUSE FLASH FIRE. Keep away from heat, sparks and flame. Do not puncture or inanera�te c�ntainer. Keep corrtainer dased. Use �ly with adequate ventilation. Corrtact with rapidty expandi�g gasps can cause frostbite. Routes of entry : Inhalation Potentiaf acute health effect Eyes : No known significant effects or critical hazards. Skin : No known significant effects or critical hazards. Inhalation ; Acts as a simple asphyxiant. Ingestion : Ingestion is not a normal route of exposure for gases Poten#ial chronic;health : CARCINOGENIC EFF�CT3Not available. effects ' MUTAGENIC EFFECTS Not available. TERATOGENIC EFFECT: Not available. Medical conditions : Acute or chronic respiratory conditions may be aggravated by overexposure to this gas. aggravated by overexposure See toxicological Infomnation (section 11) Section 3. Composition, Information on Ingredients Name CAS numbe % Volume Exposure limits Acetylene 74-86-2 100 NIOSH REL (United States, 6/2001f. ' CEIL: 2662 mg/m Form: AA forms CEIL: 2500 ppm Form: AA forms �ection 4. �irst aid measures No action shall be fiaken involving any persa�al risk or v�itfiout suitable training.lf fumes are still suspected to be present, the rescuer should wear an appropriate mask or a self-contained brea�thing apparatus. ft may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Eye contact : In case of corrtact, immediately flush eyes with plerity of water for at least 15 minutes. Get medical attention if irritation occurs. suiid l.i �@: 7/� � ,,� �.c�r�t�c� : In case of contact, immediately flush skin with pienty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. �restbite : Try to warm up the frozen tissuss and seek medical attention. inhalatia� : If inhaled, remave to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear. Section 5. Fire fighting measures Flammability of the product : Flammable_ Auto-ignition temperature : 304.85°C (58Q.7°F) Flash �oint : Closed cup; -18.15°C (-0.7°F). Flammable limits : Lower: 2.5% Upper: 82% Products of combustion : These products are carbon oxides (CO, COz). Fire hazards in presence of : Extremely flammable in presence of open flames, sparks and static discharge, of heat, various substances of oxidizing materials. Exptosion hazards in : Ex�losive ir► presence of heat. presence of various su bstances Fire fighting media and : In case of frre, use water spray (fog), foam, dry chemicals, or CO z. instructions If involved in fire, shut off flow immediately if it can be done without risk. Apply water from a safe distance to cool container and proted suROUnding area. Extremely flammable. Gas may aaximulate in confined areas, travel considerable distance to source of ignition and flash back causing fire or explosion. Special protective : Fire fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters . apparatus (SCBA) with a full facepiece operated in positive pressure mode. Se�tion 6. Accidental release measures Personal precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Shut off gas supply if this can be done safely. Isolate area until gas has dispersed. Environmenta( precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 7. Handling and s�orage Handling : Keep container closed. Use only with adequate ventilation. Keep away from heat, sparks and flame. To avoid flre, mini+'riize ignition sources. Use explosion-proof electrical (�rentilating, lighting and material handling) equipment. Qo not puncture or incinerate container. High pressure gas. Use equipmer�t rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area. Cylinders should be �tored upright, with �alve protection eap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). ��,;�d t . � Page: 2/6 .z ��ection 8. Exposure Controls, Personal Protection En�irae�ri�iq cc��tr�[s : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels befow recommended exposure limits. The engineering controls also need to keep gas, vapor or dust concentrations below any explosive limits. Use explosion-proof ventilation equipment. Personal protection Eyes ; Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Skin : Personal protective equipment for the body should be selected based on the task being pertormed and the risks involved and should be approved by a specialist before handling this product. Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.493 Hands : Chemical-resistant, impervious gloves or gauntlets complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Personal protection in case : A self-contained breathing apparatus should be used to avoid inhalation of the product. of a large spill Consult bcal authorities tor acceptable e�kposure 1"imits. Section 9. Physical and chemical properties Molecular weight : 26.04 g/molQ Molecular formula : C2-H2 Boiling/condensation point : Not available. Meltinglfreezing point : Sublimation temperature: -81.8°C (-115.2°F) Critical temperature : 35.3°C (95.5°F) Vapor pressure : 635 psig Vapor density : 0.9 (Air = 1 � Specific Volume (ft : 14.7059 Gas Density (Ib/ft : OA68 Section 10. Stability and r�eactivity Stability and reactivity : The product may undergo hazardous decomposition, condensation or polymerization, it may react vfolently with water to emit toxic gases or it may become self-reactive under conditions of shock or increase in temperature or pressure. Incompatibility with various : Extremely reactive or incompatible with oxidizing agents su bstances Section 11. Toxicological information Ingredient name Test Result Route S_pecies Acetylene Not available. Not available. Not available. Not available. Chronic effects on humans : Causes damage to the following organs: upper respiratary tract, central nervous system (CNS). Other toxic effects on : No specific �nformation is available in our database regarding the other toxic effects of humans this material for humans. Specific effects Carcinogenic effects : No known significant effects or critical hazards. Mutagenic effects : No known slgnificant effects or critical hazards. a«�i� t. � , Pege: 3/6 .e ..��ro�;zscti�,s� �c�x_;�:��;� : No known significant effects or critical hazards. �Section 12. Ecological information fnc��°etfierst nam� � e�.ses P�ric�ci R�sult Acetylene Not available. Not available. Not available. Products af degradation : These products are carbon oxides (CO, COz) and water. Toxicity af the products of : The product itself and its products of degradation are not toxic. biodegradation Environmental fate : Not available. Environmental hazards : No known significant effeets or critical hazards. Toxicity to the environment : Not available. Section 13. Disposal considerations Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local regulation.Retum cylinders with residual product to Airgas, Inc.Do not dispose of locally. Section 14. Transport information Regulatory UN number Proper shipping Class Packing group Label Additional information name information DUT Classification UN1001 ACETYLENE, 2.1 Not appticable (gas). Limited DISSOLVED uan ' Yes. Packaain9 instruction Passenger Aircrait Quantity limitation: Forbidden. Cargo Aircraft Cluantity limitation: 15 k9 TDG Classification UN1001 ACETYLENE, 2.1 Not applicable (gas). Explosive DISSOLVED Limit and timited uant' Index 0 Passenaer Carrvinu Shia Index 75 Passenaer Carrvins� Road or Rail Index Forbidden Specia� provisans 38, 42 a�,;,� ; . Page: 4�6 .e �xi��a UN1001 ACETYLENE, 2.1 Not applicable (gas). - �:lass ��c�tirsr� DISSOLVED �" Section 15. Regulatory information United States U.S. Federal regulatians : TSCA 8(b) inventory: Acetylene SARA 302t3041311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency pianning and notification: No products were found. SARA 302/3Q4/311/312 hazardous chemica�s: Acetylene SARA 311/312 MSDS distributi� - chemical inverrtory - hazard ideMification: Acetylene: Fire hazard, reactive, Sudden Release of Pressure, Immediate (Acute) Health Hazard Clean Water Ad (CWA) 307: No products were found. Gean Water Act (CWA) 311: No produds w�ere found. Clean air act (CAA} 112 accidentaf release prevention: Acet�rfene Clean air act (CAA) 112 regulated flammable substances: Acetylene Clean air act (CAA) 112 regulatec! toxic substances; No products were found. State regulations : Pennsylvania RTK: Acetylene: (generic environmental hazard) Massachusetts RTK: Acetylene New Jersey: Acetylene Canada WHMIS (Canadaj : Class A: Compressed gas. Class &1: Flammable gas. Class F: Dangerously reactive material. CEPA DSL: Acetylene Section 16. Other information United States Label Requirements : FLAMMABLE GAS. CONTENTS UNDER PRESSURE. CAUSES DAMAGE TO THE FOLLOWING ORGANS: RESPIRRTORY TRACT, CENTRAL NERVOUS SYSTEM. VAPOR MAY CAUSE FLASH FIRE. Canada Label Requirements : Class A: Compressed gas. Class B-1: Flammable gas. Class F: Dangerously reactive material. Hazardous Material : . " 1 � Information System (U.S.A.) �� .. Reactivity 3 Personal protection C National Fire Protection . Flammability Association (U.S.A.) Health 3 Instabifity Special Notice to reade s��i�� . � � Page: 5�16 ,e . the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any tiability whatsoever for the accuracy or completeness of the information contained herein. Final detertnination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used witl� caution. �ltthough certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. �uiirJ 1.1 � � �� ; _ .. . e� � �� , Carbon Dioxide Section 1. Chemical product and company identification Product Narne : Carbon Dioxide Supplier : AIRGAS INC., on behalf of its subsidiaries 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087�283 1-610�87-5253 Product use : Synthetic/A�alytical chemistry. MSDS# : 001013 Date of : 6h 5/2006. Preparation/Revis ion In case of emerqencv : 1-866-7343438 Section 2. Hazards identification Physical state : Gas. � Emergency overview : Warning! CONTENTS UNDER PRESSURE. CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, CARDIOVASCULAR SYSTEM, SKIN, EYES, CENTRAL NERVOUS SYSTEM, EYE, LENS OR CORNEA. MAY CAUSE RESPIRATORY TRACT, EYE AND SK{N IRRITATION. Avoid contact with skin and dothing. Avad breathing gas. Do not punCture or inanerate cor►tainer. Keep container dosed. Use only with adequa�e venfilation. Wash thoroughly after handlir�q. Contact with rapicily expanding gas, liquid, or solid can cause frostbite. Routes of entry : Inhalation,Dermal,Eyes Potentiaf acute health effects Eyes : Moderately irritating to the eyes. Skin : Moderately irritating to the skin. Inhalation : Moderately irritating to the respiratory system. Ingestion : Ingestion is not a normal route of exposure for gases Potential chronic health : CARCINOGENIC EFFECTSNot available. effects MUTAGENIC EFFECTS Not available. TERATOGENIC EFFECT: Not available. Medical conditions : Acute or chronic respiratory conditions may be aggravated by overexposure to this gas. aggravated by overexposure See toxicological lnfom�ation (section 11) Section 3. Composition, lnformation on Ingredient�s Name CAS numbe % Volume Exposure limits Carbon Dioxide 12438-9 100 ACGIH TLV (Unified States, 912004). STEL: 54000 mg/m 15 minute(s). Form: All forms � STEL: 30000 ppm 15 minute(s). Form: All forms TWA: 9000 mg/m 3 8 hour(s). Form: All forms TWA: 5000 ppm 8 hour(s). Form: All forms NIOSH REL (United States, 6/2001). STEL: 54000 mg/m 15 minute(s). Form: All forms STEL: 30000 ppm 15 minute(s). Form: All forms TWA: 9000 mg/m 3 10 hour(s). Form: All - Suild 3.1 �@� �� ,�oxide forms TWA: 5000 ppm 10 hour(s). Form: All forms OSHA PEL (United States, 6/1993). TWA_ 9000 mg/m 3 8 hour(s). Form: All forms TWA: 5000 ppm 8 hour(s). Form: All forms Section 4. First aid measures No ac�ion shall be taken involving any personal risk or without suitable training.lf fumes are still suspected to be present, the rescuer should wear an appropriate mask or a self-contained breathing apparatus.lt may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated I clothing and shoes. Wash Gothing before reuse. Thoraughly clean shoes before reuse. Get medical attention. � Frostbite : Try to warm up the frozen tissues and seek medical attention. Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is diffcult, give oxygen. Get medical attention. Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical atterrtion if symptoms appear. Section 5. Fire fighting measures Flammability of the product : Non-flammable. Fire fighting media and : Use an extinguishing agent suitable for surrounding fires. instructions If involved in fire, shut off flow immediately if it can be done without risk. Apply water from a safe distance to cool container and proted surrounding area No speafic hazard. Special protective ; Fire fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full facepiece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Shut off gas supply if this can be done safely. � Isolate area until gas has dispersed. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 7. Handling and storage Handling : Avoid contact with eyes, skin and clothing. Keep container closed. Use only with adequate venti�ation. Do not puncture or incinerate container. Wash thoroughly after handling. High pressure gas. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cy{irxiers irom physic�l damage; do not drag, roll, slide, or drop. Use a suitable hand trudc for cylinder movement. Never alloow any unprotected part of the body to touch uninsulated pipes or vessels that cor�tain cryogenic liquids. Prevent er�trapment of liquid in closed systerr�s or piping without pressure relief devices. Some materials may become brittle at low temperatures and will easily fracture. Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). aui�d 1.1 Fage: 2/6 �oxide action 8. Exposure Controls, Personal Protection Ens�ir��rfa�c� cc��rc�ls ; Use only with adequate ventifatian. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure timits. Personal ,}�rratQeti�r� • Eyes : Safety eyewear complying with an approved standard should be used when a risk assessment i�dicates this is necessary to avoid exposure to liquid splashes, mists or d usts. When working with cryogenic liquids, wear a ful( face shield. Skin : Personal protective equipment for the body should be selected based on the task being pertormed and the risks involved and should be approved by a specialist before handling this product. Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approvect standard if a risk assessment indicates this is necessary.Respirator selection must be tsased on kr�own ar artticipatec! exposure levels, the hazards of the product and the safe w�nricing limits of the se�ted respirator. The applicable sta►xiards are (US) 29 CFR 'l910.134 and (Canada) Z94.493 Hands : Chemical-resistant, impervious gloves or gauntlets complying with an approved standard should be worn at all times when handlir�g chemical products if a risk assessment indicates this is necessary. Insulated gloves suitable for low temperatures Personal protection in case : A self-contained breathing apparatus should be used to avoid inhalation of the product. of a large spilt Consult local authorities for acceptable exposure limits. - Section 9. Physical and chemical properties Molecular weight : 44.01 g/mole Molecular formula : CO2 Boilinglcondensation point : -78.55°C (-109.4°F) Melting/freezing point : Sublimation temperature: -78.5°C (-109.3°F) Critical temperature : 30.9°C (87.6°F) ' Vapor pressure : 83Q psig Vapor density : 1.53 (Air = 1) Specific Volume (fi�t(b) : 8.77193 Gas Density (Ib/ft : 0.114 Section 10. Stability and reactivity Stability and reactivity : The product is stable. Section 11. Toxicological information Toxicity data Inqredient name Test Result Route S ecies Carbon Dioxide Not available. Not available. Not available. Not available. IDLH : 40000 ppm Chronic effects on humans : Causes damage to the following organs: lungs, cardiovascular system, skin, eyes, central nervous system (CNS), eye, lens or cornea. Other toxic effects on : No specific information is available in,our database regarding the other toxic effects of humans this material for humans. Specific effects Carcinogenic effects : No known significant effects or critical hazards. Mutagenic effects : No known significant effects or critical hazards. Reproduction taxicity : No known significant effects or critical hazards. ��a��a t.; Page: 3/6 iOXf�C action 12. Ecological information Enqr��ient nast�� S��ee� ��r�� suit Carbon Dioxide Not available. Not available. Not available. Praducts of degradation : These products are carbon oxides (CO, COZ). Toxicity of fhe praducts of : not available biodegradation Environmental fate : Not available. Environmental hazards : No known significant effects or critical hazards. Toxicity to the environment : Not available. . Section 13. Disposal considerations Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local regulation.Retum cylinders with residual product to Airgas, Inc.Do not dispose of locally. Section 14. Transport information Regulatory UN number Proper shipping Class Packing group Label Additional information name information DOT Classification UN1013 CARBON DIOXIDE 2,2 Not applicable (gas). Limited uan ' Yes. UN2187 Carbon dioxide, refrigerated liquid Packasfina instn�ction Passenger Air+crait �uantity timitation: 75 k9 Cargo Aircraft Quantity limitation: 150 � TDG Classification UN1013 CARBON DIOXIDE 22 Not applicable (gas). iv Limit and Limited UN2187 Carbon dioxide, � Quant' refrigerated liquid Index 0.125 Passenaer Carrvins� Road or Rail Index 75 Mexico UN1013 CARBON DIOXIDE 2.2 Not applicable {gas). - Classification UN2187 Carbon dioxide, refigerated liquid Buld t.i Page: 4�6 � ,roxide ,ection 15. Regulatory information unitea states U.S. Feder rec{udat�a��s : TSCA 8(b) inventory: Carbon Dioxide SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency pianning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: Carbon Dioxide SARA 311l312 MSDS distribution - chemical inventory - hazard identification: Carbon Dioxide: Sudden Release of Pressure, Imrnediate (Acute} Heatth Hazard, Deiayed (Chronic) Health Haza�d Ciean Water Act (CVNA) 307: No products w�ere found. Clean Water Ad (CWA) 311: No products w�ere found. Clean air act (CAA)112 accidental release prevention: No produds vNere found. Ciean air act (CAA)112 regulated flammabie substances: No products were found. Clean air act (CAA)112 regulated toxic substances: No products were found, State regulations : Pennsylvania RTK; Carbon Dioxide: (generic environmental hazard) Massachusetts RTK: Carbon Dioxide New Jersey: Carbon Dioxide Canada WHMIS (Canadaj : Class A: Compressed gas. CEPA DSL Carbon Dioxide SeCtion 16. Other information United States Label Requirements : GONTENTS UNDER PRESSURE. CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, CARDIOVASCULAR SYSTEM, SKIN, EYES, CENTRAL NERVOUS SYSTEM, EYE, LENS OR CORNEA, MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. Canada Label Requirements : Class A: Compressed gas. Hazardous Material : � " 1 Information System (U.S.A.) � .. Reactiv ity ` � Personal protection � liquid: . .,- ' , O Reactivity � ' Personal protection National Fire Protection . Association (U.S.A.) Flammability Health p Instability ' Special liquid: Eu!!11.1 �@: � �p ,�oxide F�arnmabiiity Health �" � lnstability � Spe�iai Notice to reade To the best of our knowtedge, the info�rnation contained her9ein is accurate. However, neither the above narned supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the infom�ation contained here�. Final deteRnination of suitabiiity of any matertai is the sole responsibility of the user. All materials may present unknown hazards and should be used wilh caution. AMhough cerCain hazards are described herein, we cannot guaran�eee that these are tl�e only hazards that exist. aui�a t i Page: W6 � �;. T y� r � x ,� � . �.i . .. -,. . � k... � � � . � . �, � �3 . ��. . . Oxygen ' Section 1. Cherreical product and company identification Praduct Nam� : Oxygen Supplier : AIRGAS INC., on behalf of its subsidiaries 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087�283 1�10-687-5253 Product use ; Synthetic/Analytical chemistry. Synonym : oxygen (dot),Oxygen USP, Aviator's Breathing Oxygen (ABO) MSDS# : 001043 Date of ; 7/30/2007. Preparation/Rev is ion In case of emerqencv � 1-866-7343438 Section 2. Hazards identification Physical state : Gas. Emergency overview : Warning! . � CONTENTS UNDER PRESSURE. Contact with combustible material may cause fire. Do not puncture or inanerate container. Store in tightly dosed container. Avoid contact with combustible materials. Contact with rapidly expanding gases or liquids can cause frostbite. Routes of entry : Inhalation Potential acute health effect Eyes : No known significant effects or critical hazards. Skin : No known significant effects or critical hazards. Inhalation : Slightly irritating to the respiratory system. Practically non-toxic by inhalation. Ingestion : Ingestion is not a normal route of exposure for gases Potential chronic health : CARCINOGENIC EFFECT3Not available. effects MUTAGENIC EFFECTS Not available. TERATO(3ENIC EFFECT: Not available. Medical conditions : Acute or chronic respiratory conditions may be aggravated by overexposure to this gas. aggravated by overexposure See toxicological Information (section 11) ' Section 3. Composition, Information on Ingredients Name CAS numbe % Volume Exposure limits Oxygen 7782-44-7 1 QO Section 4. First aid measures No action shafl be taken irnolving any personal risk or without suitable training.lf tumes are still suspected to be present, the rescuer should wear an appropriate mask or a sel�-contained breathing apparatus.lt may be dangerous to the person providing aid to give mouth to-mouth resuscitation. Eye contact ; In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs. Skin contact : In case of corrtact, immediately flush skin with plenty of water. Remove corrtaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean ahoes before reuse. Get medical attention. Frostbite : Try to warm up the frozen tissues and seek medical attention. t��3a i . � Page: 1/5 atic�r� : If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical attention. Inqestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear. Section 5. Fire fighting measures �lammability of the product : Non-flammable. Fire fighting media and : Use an extinguishing agent suitable for surrounding fires. instructions if involved in fire, shut off flow immediately if it can be done wittiout risk. Apply water from a safe distance to cool c�ntainer and proted suROUnding area. This material increases the risk of fire and may aid c�mbustion. Contact with combustible material may cause fire. Special protective : Fire fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full facepiece operated in positive pressure mode. Section s. Accidental release measures Personal precautions : Immediately contact emergency personnel. Eliminate all ignition sources. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Do not touch or walk through spilled materiaL Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 7. Handling and storage Handling : Store in tightly closed coritainer. Avoid contact with combustible materials. Do not puncture or incinerate container. High pressure gas. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders ftorn physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Never allow any unprotected part of the body to touch uninsulated pipes or vessels that contain cryogenic liquids. Prevent entrapment of liquid in dosed systems or piping without pressure relief devices. Some materials may become brittle at low temperatures and will easily fracture. Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area. Cylinders should be stored upright, with valve protection cap in place, and firmly secureci to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F}. Se�tion 8. Exposure Controls, Personal Protection Engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. Personal protection Eyes : Safety eyewear complying with an approved standard should be used when a r�sk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. When working with cryogenic liquids, wear a full face shield. Skin : Personat protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory : Use a properly fitted, air-purifying or air-fed respirator comptying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. The applicable standards are (US) 29 CFR 19'10.134 and (Canada) Z94.493 st,ild t . I Pag@: 2/J .�� ; Chemical-resistant, impervious gloves or gauntlets compfying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Insuiated gfoves suitabie for lowtemperatures F�ersanai ptote�tion in ease : A self-contained breathing apparatus should be used to avoid inhalation of the product. of a large spii! Consult local authorides for acceptable euposure limits. Section 9. Physicai and chemicai properties Molecular weight : 32 g/mole Molecular formula : 02 Boilingicondensaiion point : -183.11°C (-297.6°F) - Meltinglfreezing point : -218.55°C (-361.4°F) Critical temperature : Not available. Vapor density : 1.105 (Air = 1) Specific Volume (ft'llb) : 12.0482 Gas Density �ib/ft : 0.083 Section 10. Stability and reactivity Stability and reactivity : The product is stable. Incampatibility with various : Extremely reactive or incompatible with reducing agents, combustible materials. substances Section 11. Toxicological information Other toxic effects on : No specific information is available in our database regarding the other toxic effects of humans this material for humans. Specific effects Carcinogenic effects : No known significant effects or critical hazards. Mutagenic effects : No known significarit effects or critical hazards. Reproduction toxicity : No known significant effects or critical hazards. Section 12. Ecological information Toxicity of the products of : The product itself and its products of degradation are not toxic. biodegradation Environmental fate : Not available. Environmental hazards : No known significant effects or critical hazards. Toxicity to the environment : Not available. Section 13. Disposal considerations . Product removed from the cylinder must be disposed af in accordance with appropriate Federal, State, 1oca1 regulation.Retum cylinders with residual product to Airgas, Inc.Do not dispose of locally. Section 14. Transport information Regulatory UN number Proper shipping Class Packing group Label Additional information name information DOT Classification UN1072 OXYGEN, 22 Not applicable (gas). imited COMPRESSED uanf Yes. UN1073 Oxygen, refrigerated Packaaina liquid � instruction �� Passenger SW7�CS 1 . i Page: 3/5 Aircraft Quantity limitation: 75 k9 Cargo Aircraft Quantity limitation: 150 k9 sp�cial provfsions A52 7DG Classification UN1072 OXYGEN, 2.2 Not applicable (gas). E�cplosive COMPRESSED Limit and Limited ua t' UN1073 Oxygen, refrigerated Index liquid 0.125 d, ERAP Index 3000 Passens�er Carryina Ship Index 50 Passerwer . Carrvina Road or Rai Index 75 Saec�a� arov�ions 42 Mexico UN1072 OXYGEN, 2.2 Not applicable (gas). - Classification COMPRESSED UN1073 O�rygen, refrigerated liquid � Al Section 15. Regulatory information United States U.S. Federal regulations : TSCA 8(b) inventary: C?xygen SARA 3021304/311/312 extremely hazardous substances: No products were found. SARA 302J304 emergency planning and notificcation: No products were found. SARA 302/3Q4/3111312 hazarctous chemicals: Oxygen SARA 311/312 MSDS distribution - chemica! inventory - hazard identification: O�cygen: Fire hazard, Sudden Release of Pressure, Delayed (Chronic) Health Hazard Clean Water Ad (CWA) 307: No produds were found. Clean Water Ad (CWA) 311: No produds w�er�e found. Ctean air act (CAA)112 accidental release prevention: No produds were found. Clean air act (CAA)112 regulated flammable substances: No products were found. C1ean air act (CAA)1'12 regutated toxic substances: No products were found. B��ila ;,i � P8g@: �i �e r��=��} = Pennsylvania RTK: Oxygen: (generic environmental hazard) Massachusetts RTK: Oxygen New Jersey: Oxygen Canada � WtiMlS (Canada) : C1ass A: Compressed gas. Ciass C: Oxidizing material. CEPA DSL: Oxygen Sec#ion 16. Other information United States Label Requirements : OXIDIZER. CONTENTS UNDER PRESSURE. CONTACT W{TH OTHER MATER{AL MAY CAUSE FiRE. Canada Label Requirements : Class A: Compressed gas. Class C: Oxidizing materiaL Hazardous Material : � , , : 0 ` Information System (U.S.A.� p . Reactivity 0 Personal protection .� tiquKl: � i 3 , p Reactivity ' � Personal profiection National Fire Protection . Flammability Association (U.S.A.) Health � Instability Special tiquid: Flammability Health a Instability Special Notice to reade To fhe best of our knawledge, fhe infom�ation contained herein is accurate. However, neifher the above named suppl"ier nor any of its subsidiaries assumes any liability whatscever for the accuracy or completeness of the infom�ation contained herein. Finat determmation of suitabitity of any ma�erial is the sote responsibility of ihe user. All materials may present unknown hazards and should be used wilh caution. AHhough certain haza�ds are described herein, we cannot guarantee that these are the only hazards that exist. aU;ia ti i Page: 5✓5 09/20/07 11:01 AM M S D S I N F 0 R M A T 2 O N Page 1 Part: 35101 Line: NBF Desc: GALLON � MATERIAL SAFETY DATA SHEET Effective Date: 11-15-99 Revision Date: none NAPA Brake Fluid DOT 3 Code: CST Page: 1 ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 1- Product and Company Identification PRODUCT NAME: NAPA Brake Fluid DOT 3 MAN[JFACTURER'S NAME: EMERGENCY TELEPHONE NUMBER Coastal Uni-Lube Inc. (713)877-1400 9 Greenway Plaza Houston, TX 77046 MISCELLANEOUS INFORMATION ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 2 - Hazardous Ingredients OSHA ACGIH Product Name CAS # Wt. PEL TLV Other Units Coastal S. H. D. Brake Fluid Mixture 100$ NA NA DOT3 � Ingredients Blend of various Glycol Ethers, Glycol and Polyglycol NA-P 100� NA NA NA PPM NA= Not Available NA-P= Information is claimed proprietary by supplier STEL= Short Term Exposure Limit; 15 Minutes ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Effective Date: none Revision Date: none NAPA Brake Fluid DOT 3 Code: CST Page: 2 ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 3 - Hazards Indentification - This product has not been tested as a whole to determine its specific hazards. The information provided in this section is based on health hazard information on the product components. Effects of overexposure: Acute: EYES: May cause severe eye irritation and chemical burns. SKIN: Slightly irritating to the skin. Harmful amounts may be absorbed through the skin with extensive and prolonged contact. _ INHALATION: Exposure to vapors or mist may result in irritation of the respiratory tract, headache, drowsiness and dizziness. High concentrations of ethylene glycol ethers may be lethal. _ INGESTION: May cause irritation of the mouth, throat, and the respiratory tract, abdominal discomfort, dizziness, lumbar pain, CNS depression, kidney and liver damage. Chronic: Prolonged or repeated contact may result in toxic amounts being absorbed throuah the skin. 09/20/07 11:01 AM M S D S I N F O R M A T I O N Page 2 Part: 35101 Line: NBF Desc: GALLON Carcinogenicity: NTP: No IARC Monographs: No OSHA Regulated: No ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 4- First Aid Measures Eye Contact: Flush thoroughly with large amounts of water for at least 15 minutes, including underthe eye lids. Contact a physician immediately, preferably an opthamologist. Speed and thoroughness in rinsing eyes are important to avoid permanent injury. Skin Contact: Remove contaminated clothing. wash affected areas with soap and water. If irritation occurs, get medical help. Discard contaminated shoes. Inhalation: Remove to fresh air. If breathing has stopped, apply artificial respiration. Get immediate medical attention. Ingestion: Never give anything by mouth to an unconsious or convulsing person. Have the affected person, if conscious, drink 1 to 2 glasses of water, then induce vomiting. Get immediate medical attention. ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- MATERIAL SAFE'I`Y DATA SHEET Effective Date: none Revision Date: none NAPA Brake Fluid DOT 3 Code: CST Page: 3 Section 5 - Firefighting Measures Flash Point: >200 F Flammable Limits in Air $ by Vol.: Lower: N.A. Upper: N.A. Autoignition Temperature: N.A. Extinguishing Media: Dry chemical, foam, carbon dioxide Special Fire Fighting Procedure: Water spray may be used to keep fire-exposed containers cool, preventing pressure build up and explosion. Firefighters should wear self-contained breathing apparatus. Unusual Fire or Explosion Hazard: May ignite when sufficient heat is _. applied. ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- 5ection 6- Environmental Release Measures Spill Procedures: Remove sources of heat or ignition including internal combustion engines and power tools. Remove spill with vacuum trucks or pump and soak up residue with an absorbent. Use approved respirator where occupational exposure limits may be exceeded. ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 7- Handling and Storage Store in tightly closed aontainers in an dry place, away from incompatible ' materials or sources of heat, ignition or strong oxidizers. Ground and bond all transfer and storage equipment. Empty containers may contain residue tliquid and/or vapor) and can be dangerous. Do not pressurize, cut, puncture, incinerate, weld, braze, solder, drill, grind or expose such containers to heat, flame, sparks or other sources of ignition. 09/20/07 11:01 AM M S D S 2 N F 0 R M A T I O N Page 3 Part: 35101 Line: NBF Desc: GALLON Section 8- Exposure ControlslPersonal Protection Eye Protection: Remove contact lenses and wear chemical safety goggles where contact with liquid or mist may occur. Skin Protection: Wear impervious gloves when contact with skin may occur. Use face shield where spla.shing may occur. Wash with soap and water before eating, drinking and smoking. Launder contaminated clothing before reuse. Inhalation: Use approved respiratory pxotective equipment for cleaning large spills or entry into lazge tanks, vessels or other confined spaces or in situations where exposure may exceed occupational exposure levels. Ventilation: Provide adequate general and local exhaust ventilation: (1) to keep mist and vapors below occupational exposure levels; and (2) to prevent the formation of an oxygen deficient atmosphere, particularly in a confined space. ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Effective Date: none Revision Date: none NAPA Brake Fluid DOT 3 Code: CST Page: 4 ------------------------------------�--------------------------------------- � ---------------------------------------------------------------------------- Section 9- Physical and Chemical Properties Boiling Point 760 mmHg: 401 F Melting Point: N.A. Vapor Pressure mmHg @ 100F: <0.1 Vapor Density (air=1): N.A. Solubility in H20 �: Soluble pH: N.A. Specific Gravity(H20): 1.02-1.04 Evaporation Rate: � Volatile by Volume: N.A. (ethyl ether=l): N.A. Viscosity (method, temp): N.A. Appearance: Clear liquid Odor: Mild ether odor N.A. = Not Available ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 10 - Stability and Reactivity Stability: Stable Hazardous Polymerization: Will not occur. Conditions to Avoid/Incompatibility: Strong oxidizing agents, heat, spark, flame and build-up of static electricity. Iiazardous Decomposition Products: Carbon monoxide, carbon dioxide, water and/or oxygenated hydrocarbons. ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 11 - Toxicological Information Persons with preexisting resperatory, liver, kidney, eye or skin diseases may be adversely affected by this product. Ethylene glycol and ethylene � glycol ethers have produced dose-related teratogenic effects and maternal toxicity in laboratory animals. Exposure to vapors of ethylene glycol ethers have caused testicular atrophy in laboratory animals. - ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 12 - Ecological Information No information. 09/20/07 11:01 AM M S D S I N F 0 R M A T I 0 N Page 4 Part: 35101 Line: NBF Desc: GALLON Section 13 - Disposal Considerations Waste Disposal: Dispose through a licensed waste disposal company. Follow federal, state and local regulations. Section 14 - Transport Information Not applicable. MATERIAL SAFETY DATA SHEET Effective Date: none Revision Date: none NAPA Brake Fluid DOT 3 Code: CST Page: 5 Section 15 - Regulatory Information SARA TITLE III INFORMATION • Section 311/312 Hazard Categorization Acute Chronic Fire Pressure Reactive X X SARA Hazardous Substances Ingredient CAS No. �, wt Sec 313 Sec 302 RQ, lb TPQ, lb - Ethylene Glycol 110-80-5 NA X Glycol Ethers various <75 X Key: Sec 313 = Toxic Chemicals, Section 313 Sec 302 = Extremely Hazardous Substances (EH5) RQ = Reportable Quantity of EHS TPQ = Threshold Planning Quantity of EHS ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 16 - Other Information CALIFORNIA PROPOSITION 65 WARNING Chemicals known to the State of California to cause cancer, birth defects or other reproductive harm may be found in the petroleum products. Although it is possible to sufficiently refine the petroleum products to remove the potential for cancer, we are advising that one or more of the listed chemicals may be present in some detectable quantities. Read and follow directions and use care when handling these petroleum products. THIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS TO THE BEST OF THIS COMPANY'S KNOWLEDGE AND BELIEVED ACCURATE AND RELIABLE AS OF THE DATE INDICATED. HOWEVER, NO F2EPRESENTATION, WARRANTY OR GUARANTEE IS MADE AS TO THE '4`` ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABLENESS AND COMPLETENESS OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE. � � 09/20/07 11:01 AM M S D S I N F 0 R M A T I O N Page 5 Part: 35101 Line: NBF Desc: GALLON *** End of Report *** '�, s _ _ 09/20/07 11:01 AM M S D S I N F 0 R M A T I O N Page 1 Part: 9801 Line: PSF Desc: PWR STEERING FL-1GAL ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Effective Date: 9-6-01 Revision Date: none NAPA Power Steering Fluid Code: CST Page: 1 ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 1- Product and Company Identification PRODUCT NAME: NAPA Power Steering Fluid MANUFACTURER'S NAME: EMERGENCY TELEPHONE NiJNIBER Coastal Uni-Lube Inc. (713)877-1400 9 Greenway Plaza Houston, TX 77046 MISCELLANEOUS INFORMATION ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 2 - Hazardous Ingredients Occupational Exposure Limits* OSHA ACGIH Product CAS Number Wt$ PEL TLV Other Units NAPA Mixture 100 N.A. N.A. Power Steering Fluid*** Ingredient(s): Severely Hydrotreated 64742-52-2 >99 5 5 10 3TEL mg/m3** Heavy Naphthenic Distillate Additives containing N.A. -P <1 N.A. N.A. Zinc salt of dialkyl- dithiophosphate (ZDDP), 2,6-di-t-butylphenol and polymers * = 8-Hr. TWA unless otherwise specified. ** = As mineral oil Mist *** = All ingredients in this product are listed in the T.S.C.A. Inventory. N.A. = Not Available STEL = Short Term Exposure Limit; 15 minutes. N.A. -P = Information for this component is claimed proprietary by supplier ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Effective Date: 9-6-01 Revision Date: none NAPA Power Steering Fluid Code: CST Page: 2 ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 3 - Hazards Indentification Eves: The heaw baraffinic petroleum distillate fraction of this 09/20/07 11:01 AM M S D S I N F 0 R M A T I 0 N Page 2 Part: 9801 Line: PSF Desc: PWR STEERING FL-1GAL Skin: The heavy paraffinic petroleum distillate fraction of this , product is believed to be minimally irritating. Inhalation: The inhalation hazards of this products components are negligible to minimally irritating if airborne concentrations are kept be]i,ow permissible occupational exposure limits. , i Ingestion: Ingestion hazards range from practically non-toxic to minimally toxic for the components of this product. If vomiting occurs, product is an aspiration hazard. Chronic: Frequent or prolonged contact may cause skin irritation. Acute: Additional Medical and Toxicological Information: May aggravate pre-existing dermatitis. The International Agency for Research on Cancer (IARC) has determined that there is sufficient evidence for the carcinogenicity in experimental animals of used oil. This product has not been tested as a whole to determine its specific health hazards. The information provided in this section is based on health hazard information on the product components. ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 4- First Aid Measures Eye Contact: Flush thoroughly with water for at least 15 minutes. Get medical attention. Skin Contact: Remove contaminated clothing. Wash affected areas with soap and water. If irritation occurs, get medical help. Inhalation: Remove to fresh air. Apply artificial respiration if not breathing. Get medical attention. Ingestion: Do not induce vomiting. If spontaneous vomiting occurs hold the victim's head lower than hips to prevent aspiration. ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Effective Date: 9-6-01 Revision Date: none NAPA Power Steering Fluid Code: CST Page: 3 ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 5 - Firefighting Measures Flash Point: 350 F Flammable Limits in Air $ by Vol. Lower: N.A. Upper: N.A. Autoignition Temperature: N.A. Extinguishing Media: Dry chemical, foam, carbon dioxide or water spray. Special Fire Fighting Procedure: Water spray may be ineffective on flames but should be used to keep fire-exposed containers cool. Firefighters should wear self-contained breathing apparatus. 09/20J07 11:01 AM M S D S I N F 0 R M A T I 0 N Page 3 Part: 9801 Line: PSF Desc: PWR STEERING FL-1GAL applied. Section 6- Environmental Release Measures 5pi11 Procedures: Remove sources of heat or ignition including internal combustion engines and power tools. Remove spill with vacuum trucks or pump and soak up residue with and absorbent. Use approved respirator where occupational exposure limits may be exceeded. Section 7- Handling and Storage Storage Requirements: Store in tightly closed containers in an dry cool place, away from sources of heat, ignition or strong oxidizers. Ground and bond all transfer and storage equipment and equip with self closing valves, pressure vacuum bungs and flame arrestors. ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 8- Exposure Controls/Personal Protection Eye Protection: Remove contact lenses and wear chemical safety goggles where contact with liquid or mist may occur. Skin Protection: Wear impervious gloves when contact with skin may occur. Use face shields where splashing may occur. Inhalation: Use approved respiratory protective equipment for cleaning large spills or entry into large tanks, vessels or other confined spaces or in situations where exposure may exceed occupational exposure levels. Ventilation: Provide adequate ventilation to keep mist or vapors below occupational exposure levels. ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Effective Date: 9-6-01 Revision Date: none NAPA Power Steering Fluid Code: CST Page: 4 ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 9- Physical and Chemical Properties Boiling Point 760 mmHg: N.A. Melting Point: Vapor Pressure mmHg @ 100F: N.A. Vapor Density (air=1): N.A. Solubility in H 20 �: Nil. pH: N.A. � Specific Gravity (H 20): 0.922 Evaporation Rate (ethyl ether =1): N.A. � Volatile by Volume: N.A. Odor: Slight hydrocarbon odor Viscosity (method, temp): 32 cSt @ 40C Appearance: Pale Liquid N.A. = Not Available ----------------------------------------------------�----------------------- ---------------------------------------------------------------------------- Section 10 - Stability and Reactivity Stability: Stable ° Hazardous Polvmerization: Will not occur. 09/20/07 11:01 AM M S D S I N F 0 R M A T I 0 N Page 4 Part: 9801 Line: PSF Desc: PWR STEERING FL-1GAL spark, flame and build-up of static electricity. Hazardous Decomposition Products: Hydrogen sulfide, carbon monoxide, carbon dioxide, aldehydes, ketones, and combustion products of sulfur and nitrogen. ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 11 - Toxicological Information Carcinogenicity: NTP: No IARC Monographs: No OSHA Regulated: No Occupational Exposure Limits: See COMPOSITION section. -----------------------------------�---------------------------------------- ---------------------------------------------------------------------------- Section 12 - Ecological Information No information ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 13 - Disposal Considerations � Waste Disposal: Dispose through a licensed waste disposal company. Fo11ow federal, state and local xegulation. ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Effective Date: 9 Revision Date: none NAPA Power Steering Fluid Code: CST Page: 5 ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 14 - Transport Information , Not regulated ---------------------------------------------------------------------------- ---------------------------------------------------------------------------- Section 15 - Regulatory Information SARA TITLE III INFORMATION Acute Chronic Fire Pressure Reactive X X SARA Hazardous Substances Ingredient CAS N0. $, WT Sec 313 Sec 302 RQ, lb TPQ, lb Zinc Compound N.A. <1 X Key: Sec 313 = Toxic Chemicals, Section 313 Sec 302 = Extremely Hazardous Substances (EHS) RQ = Reportable Quantity of EHS TPQ = Threshold Planning Quantity of EHS 09/20/07 11:01 AM M S D S I N F O R M A T I 0 N Page 5 Part: 9801 Line: PSF Desc: PWR STEERING FL-1GAL Section 16 - Other Information CALIFORNIA PROPOSITION 65 WARNING Chemicals known to the State of California to cause cancer, birth defects or other reproductive harm may be found in the petroleum products. Although it is possible to sufficiently refine the petroleum products to remove the potential for cancer, we are advising that one or more of the listed chemicals may be present in some detectable quantities. Read and follow directions and use care when handling these petroleum products. THIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS TO THE BEST OF THIS COMPANY'S KNOWLEDGE AND BELIEVED ACCURATE AND RELIABLE AS OF THE DATE INDICATED. HOWEVER, NO REPRESENTATION, WARRANTY OR GUARANTEE IS MAKE AS TO THE ACCURACY, RELIABILITY OR COMPLETENESS. IT IS TfiE USER'S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABLENESS AND COMPLETENESS OF SL1CH INFORMIITION FOR HIS OWN PARTICULAR USE. *** End of Report *** 09/20/07 11:00 AM M S D S I N F 0 R M A T I 0 N Page 1 Part: 75200 Line: NOL Desc: QT ATF 8 MATERIAL SAFETY DATA SHEET The Valvoline Company Page 001 Date Prepared: 01/14/02 Date Printed: 05/01/06 MSDS No: 505.0200299-007.004 DEXRON III/MERCON ATF 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Material Identity Product Name: DEXRON III/MERCON ATF SAP Material No: W351 General or Generic ID: PETROLEUM BASED-LUBRICATING OIL Company Telephone Numbers The Valvoline Company Emergency: 1-800-274-5263 P.O, Box 14000 Lexington, KY 40512 Information: 1-859-357-7206 __ 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS Number � (by weight) -------------------------------------------- ------------- ------------- ALIPHATIC PETROLEUM DISTILLATES 64742-65-0 73.0- 83.0 TRn,NSMISSION FLUID PACKAGE 3. HAZARDS IDENTIFICATION ' Potential Health Effects Eye Unlikely to cause eye irritation or injury. Skin Prolonged or repeated contact may dry and crack the skin. Additional svmotoms of skin contact mav include: acne. Passaae of 09/20/07 11:00 AM M S D S I N F 0 R M A T I 0 N Page 2 Part: 75200 Line: NOL Desc: QT ATF 8 this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use. MATERIAL SAFETY DATA SHEET The Valvoline Company Page 002 Date Prepared: 01/14/02 Date Printed: 05/01/06 MSDS No: 505.0200299-007.004 DEXRON III/MERCON ATF Swallowing Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Symptoms of Exposure Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways). Target Organ Effects No data Developmental Information There are no data available for assessing risk to the fetus from maternal exposure to this material. Cancer Information � s: 09/20/07 11:00 AM M S D S I N F O R M A T I O N Page 3 Part: 75200 Line: NOL Desc: QT ATF 8 This material is not listed as a carcinogen by the International Agency for Research on Cancer, the National Toxicology Program, or the Occupational Safety and Health Administration. Other Health Effects No data Primary Route(s) of Entry Inhalation, Skin contact, Eye contact, Ingestion. 4. FIRST AID MEASURES Eyes If symptoms develop, move individual away from exposure and into fresh air. Flush eyes gently with water while holding eyelids apart. If symptoms persist or there is any visual difficulty, seek medical attention. MATERIAL SAFETY DATA SHEET The Valvoline Company Page 003 Date Prepared: 01/14/02 Date Printed: 05/01/06 MSDS No: 505.0200299-007.004 DEXRON III/MERCON ATF Skin First aid is not normally required. However, it is recommended that exposed areas be cleaned by washing with soap and water. Swallowing Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomitina. 09/20/07 11:00 AM M S D S 2 N F O R M A T I O N Page 4 Part: 75200 Line: NOL Desc: QT ATF 8 If possible, do not leave individual unattended. Inhalation If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. Note to Physicians Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. Symptoms are often subtle and radiological changes appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary . abnormalities. Preexisting disorders of the following organs ( or organ systems) may be aggravated by exposure to this material: skin, lung (for example, asthma-like conditions). 5. FZRE FIGHTING MEASURES Flash Point 365.0 F (185.0 C) COC MATERIAL SAFETY DATA SHEET The Valvoline Company Page 004 Date Prepared: 01/14/02 Date Printed: 05/01/06 09/20/0711:OOAM MSDS INFORMATION Page5 Part: 75200 Line: NOL Desc: QT ATF 8 M5D5 No: 505.0200299-007.004 DEXRON I22/MERCON ATF Explosive Limit No data Autoignition Temperature No data Hazardous Products of Combustion May form: carbon dioxide and carbon monoxide, various hydrocarbons. Fire and Explosion Hazards Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively. Dense smoke may be generated while burning. Extinguishing Media regular foam, carbon dioxide, dry chemical. Fire Fighting Instructions Water or foam may cause frothing which can be violent and possibly endanger the life of the firefighter. Water may be used to keep fire-exposed containers cool until fire is out. Wear a self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn-out qear and chemical resistant personal protective equipment. Refer to the personal protective equipment section of this MSD5. NFPA Rating . Health - 1, Flammability - 1, Reactivity - 0 6. ACCIDENTAL RELEASE MEASURES Small Spill Absorb liquid on vermiculite, floor absorbent or other absorbent material. Persons not wearina Arober oersonal protective 09J20/07 11:00 AM M S D S I N F 0 R M A T I O N Page 6 Part: 75200 Line: NOL Desc: QT ATF 8 equipment should be excluded from area of spill. MATERIAL SAFETY DATA SHEET The Valvoline Company Page 005 Date Prepared: 01/14/02 Date Printed: 05/01/06 MSDS No: 505.0200299-007.004 DEXRON I22/MERCON ATF Large Spill Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occured. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. 7. HANDLING AND STORAGE xandling , Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or - solid), all hazard precautions given in the data sheet must be observed. All five gallon pails and larger metal containers including tank cars and tank trucks should be grounded and/or bonded when material is transferred. Avoid prolonged or repeated contact. Storage Do not store near extreme heat, open flame, or sources of ignition. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 09/20/07 11:00 AM M S D S I N F O R M A T I O N Page 7 Part: 75200 Line: NOL Desc: QT ATF 8 Eye Protection Not required under normal conditions of use. However, if misting or splashing conditions exist, then safety glasses or chemical splash goggles are advised. Skin Protection Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin contact, wear impervious clothing and boots. MATERIAL SAFETY DATA SHEET The Valvoline Company Page 006 Date Prepared: 01/14/02 Date Printed: 05/01/06 , MSDS No: 505.0200299-007.004 DEXRON III/MERCON ATF Respiratory Protections If workplace e�osure limit(s) of product or any component is . exceeded (See Exposure Guidelines), a NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental � control. OSHA regulations also permit other NIOSH/MSHA respifators (negative pressure type) under specified conditions 1 (consult your industrial hygienist�. Engineering or administrative controls should be implemented to reduce exposure. Engineering Controls � Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s). Exposure Guidelines Component 09/20/07 11:00 AM M S D S I N F O R M A T I O N Page 8 Part: 75200 Line: NOL Desc: QT ATF 8 ALIPHATIC PETROLEUM DISTILLATES (64742-65-0) OSHA VPEL 5.000 mg/m3 - TWA ACGIH TLV 5.000 mg/m3 - TWA TRANSMISSION FLUID PACKAGE No exposure limits established 9. PHXSICAL AND CHEMICAL PROPERTIES Boiling Point No data Vapor Pressure No data Specific Vapor Density No data ' MATERIAL SAFETY DATA SHEET The Valvoline Company Page 007 Date Prepared: 01/14J02 Date Printed: 05/O1/06 MSDS No: 505.0200299-007.004 DEXRON III/MERCON ATF Specific Gravity .875 Cd b0.00 F Liquid Density 7.290 lbs/gal @ 60.00 F .875 kg/1 @ 15.60 C Percent Volatiles (Including Water) No data Evaporation Rate SLOWER THAN ETHYL ETHER 09/20/07 11:00 AM M S D S I N F 0 R M A T I 0 N Page 9 Part: 75200 Line: NOL Desc: QT ATF 8 Appearance No data State LIQUID Physical Form No data Color RED Odor PETROLEUM PH No data Viscosity 6.9 - 8.0 cst @ 100 C 29.0 - 42.6 cst @ 40 C - > 175.0 ratio MATERIAL SAFETY DATA SHEET The Valvoline Company Page 008 • Date Prepared: O1/14/02 Date Printed: 05/01/06 MSDS No: 505.0200299-007.004 AEXRON III/MERCON ATF 10. STABILITY AND REACTIVITY Hazardous Polymerization Product will not undergo hazardous polymerization. Hazardous Decomposition I�Iay form: carbon dioxide and carbon monoxide, various l�vdrocarbons. , I 09/20/07 11:00 AM M S D S I N F 0 R M A T I 0 N Page 10 Part: 75200 Line: NOL Desc: QT ATF 8 Chemical Stability Stable. IncompatibiliCy Avoid contact with: strong oxidizing agents. 11. TOXICOLOGICAL INFORNIATION No data 12. ECOLOGICAL INFORMA.TION No data 13. DISPOSAL CONSIDERATION Waste Management Information Dispose of in accordance with all applicable local, state and . federal regulations. 14. TE2ANSPORT INFORMATION DOT Information - 49 CFR 172.101 DOT Description: Not Regulated MATERIAL SAFETY DATA SHEET The Valvoline Company Page 009 Date Prepared: 01/14/02 Date Printed: 05/O1/06 MSDS No: 505.0200299-007.004 DEXRON III/MERCON ATF Container/Mode: CASES/SURFACE - NO EXCEPTIONS 09/20/07 11:00 AM M S D S I N F O R M A T I 0 N Page 11 Part: 75200 Line: NOL Desc: QT ATF 8 NOS Component: None RQ (Reportable Quantity) - 49 CFR 172.101 Not applicable 15. REGULATORY INFORMATION US Federal Regulations TSCA (Toxic Substances Control Act) Status TSCA (UNITED STATES) The intentional ingredients of this product are listed. CERCLA RQ - 40 CFR 302.4 None SARA 302 Components - 40 CFR 355 Appendix A None Section 3111312 xazard Class - 40 CFR 370.2 Immediate( ) Delayed( ) Fire( ) Reactive( ) Sudden Release of Pressure( ) SARA 313 Components - 40 CFR 372.65 None International Regulations Inventory Status • AICS (AUSTRALIA) The intentional ingredients of this product are listed. CICS (CHINA) The intentional ingredients of this product are listed. DSL (CANADA) The intentional ingredients of this product are listed. EINECS (EUROPE) The intentional ingredients of this product are listed. 09/20/07 11:00 AM M S D S 2 N F O R M A T I 0 N Page 12 Part: 75200 Line: NOL Desc: QT ATF 8 MATERIAL 5AFETY DATA SHEET The Valvoline Company Page O10 Date Prepared: 01/14/02 Date Printed: 05/01/06 MSDS No: 505.0200299-007.004 DEXRON III/MERCON ATF State and Local Regulations California Proposition 65 None 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the � information is current, applicable, and suitable to their circumstances. *** End of Report *** 09/20/07 10:58 AM M S D S I N F O R M A T I O N Page 1 Part: 75150 Line: NOL Desc: SAE5W20 MATERIAL SAFETY DATA SHEET The Valvoline Company Page 001 Date Prepared: 09/14/05 Date Printed: 01/02/07 MSDS No: 505.0366793-003.001 ALL CLIMATE 5W20 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Material Identity Product Name: ALL CLIMATE 5W20 SAP Material No: NP75150 General or Generic ID: PETROLEUM-BASED LUBRICATING OIL Company Telephone Numbers The Valvoline Company Emergency: 1-800-274-5263 P.O. Box 14000 Lexington, KY 40512 Information: 1-859-357-7206 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS Number � (by weight) -------------------------------------------- ------------- ------------- HYRDOTREATED HEAVY PARAFFINIC DISTILLATE 64742-54-7 80.0- 90.0 ZINC COMPOUNDS 68988-45-4 1.0- 1.0 ALKYI,ATED PHENOL 26998-80-1 1.0- 6.0 3. HAZARDS IDENTIFICATION Potential Health Effects Eye May cause mild eye irritation. Skin Mav cause mild skin irritation. Prolonaed or repeated contact mav 09/20/07 10:58 AM M S D S I N F 0 R M A T I 0 N Page 2 Part: 75150 Line: NOL Desc: SAE5W20 dry and crack the skin. Swallowing Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. MATERIAL SAFETY DATA SHEET The Valvoline Company Page 002 Date Prepared: 09/14/05 Date Printed: O1/02/07 MSDS No: 505.0366793-003.001 ALL CLIMATE 5W20 Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal � handling is not 1ikely to cause harmful effects. Symptoms usually occur at air concentrations higher than the recommended exposure limits (See Section 8J. Symptoms of Exposure Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways), pain in the abdomen. Target Organ Effects No data Developmental Information There are no data available for assessing risk to the fetus from maternal ex►�osure to this material. 09120/07 10:58 AM M S D S I N F 0 R M A T I 0 N Page 3 Part: 75150 Line: NOL Desc: SAE5W20 Cancer Information Used motor oil has been shown to cause skin cancer in laboratory animals continually exposed by repeated applications. Avoid prolonged or repeated skin contact. Other Health Effects No data Primary Route(s) of Entry Inhalation, Skin contact, Eye contact, Ingestion. 4. FIRST AID MEASURES Eyes If symgtoms develop, move individual away from exposure and into fresh air. Flush eyes gently with water while holding eyelids apart. If symptoms persist or there is any visual difficulty, seek medical attention. MATERIAL SAFETY DATA SHEET The Valvoline Company Page 003 Date Prepared: 09/14/05 Date Printed: 01/02/07 MSDS No: 505.0366793-003.001 ALL CLIMATE 5W20 Skin � Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse. Swallowing Seek medical attention. If individual is drowsy or unconscious, do not aive anvthincs bv mouth: olace individual on the left side 09/20/07 10:58 AM M S D S I N F 0 R M A T I 0 N Page 4 Part: 75150 Line: NOL Desc: SAE5W20 with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and - quiet; seek immediate medical attention. Note to Physicians Preexisting disorders of the following organs ( or organ systems) may be aggravated by exposure to this material: skin. 5. FIRE FIGHTING MEASURES Flash Point > 390.0 F (198.8 C) Explosive Limit No data Autoignition Temperature No data Hazardous Products of Combustion May form: carbon dioxide and carbon monoxide, nitrogen oxides, sulfur oxides, various hydrocarbons, zinc oxide. MATERIAL SAFETY DATA SHEET The Valvoline Company Page 004 Date Prepared: 09/14/05 Date Printed: 01/02/07 MSDS No: 505.0366793-OQ3.001 ALL CLIMATE 5W20 09/20/07 10:58 AM M S D S I N F 0 R M A T I 0 N Page 5 Part: 75150 Line: NOL Desc: SAE5W20 Fire and Explosion Hazards Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively. Dense smoke may be generated while burning. Extinguishing Media regular foam, water fog, carbon dioxide, dry chemical. Fire Fighting Instructions Water or foam may cause frothing which can be violent and possibly endanger the life of the firefighter. Wear a self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective equipment. Refer to the personal protective equipment section of this MSDS. NFPA Rating Health - 1, Flammability - 1, Reactivity - 0 6. ACCIDENTAL RELEASE MEASURES Small Spill Absorb liquid on vermiculite, floor absorbent or other absorbent material. Large Spill Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occured. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent < spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, c1ay, earth, floor absorbent, or other absorbent material and shoveled into containers. 09/20/07 10:58 AM M S D S I N F 0 R M A T I 0 N Page 6 Part: 75150 Line: NOL Desc: SAE5W20 MATERIAL SAFETY DATA SHEET The Valvoline Company Page 005 Date Prepared: 09/14/05 Date Printed: 01/02/07 MSDS No: 505.0366793-003.001 ALL CLIMATE 5W20 7. HANDLING AND STORAGE - Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage Keep containers closed when not in use. � 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Not required under normal conditions of use. However, if misting or splashing conditions exist, then safety glasses or chemical splash goggles are advised. Skin Protection Not normally required. However, wear resistant gloves such as nitrile rubber to prevent irritation which may result from prolonged or repeated skin contact with product. Wear normal work clothing covering arms and legs. , Respiratory Protections Not required under normal conditions of use. However, if oil mists are generated above recommended PEL/TLV of 5 mg/m3, then a NIOSH/MSHA approved respirator is advised in absence of proper environznental control. (See vour industrial hvaienist.) 09/20/07 10:58 AM M S D S I N F O R M A T I O N Page 7 Part: 75150 Line: NOL Desc: 5AE5W20 Engineering Controls Not required under normal conditions of use. However, if unusual operating conditions exist, then provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below PEL/TLV (s). MATERIAL SAFETY DATA SHEET The Valvoline Company Page 006 Date Prepared: 09/14/05 Date Printed: 01/02/07 MSDS No: 505.0366793-003.001 ALL CLIMATE 5W20 , Exposure Guidelines - Component HYRDOTREATED HEAVY PAF2AFFINIC DISTILLATE (64742-54-7) OSHA VPEL 5.000 mg/m3 - TWA ACGIH TLV 5.000 mg/m3 - TWA ZINC COMPOUNDS (68988-45-4) No exposure limits established ALKYLATED PHENOL (26998-80-1) No exposure limits established 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point No data Vapor Pressure No data Soecific Vabor Densitv 09/20/07 10:58 AM M S D S I N F O R M A T I 0 N Page 8 Part: 75150 Line: NOL Desc: SAE5W20 No data Specific Gravity .861 @ 60.00 F Liquid Density 7.150 lbs/gal @ 60.00 F .861 kg/1 F Percent Volatiles (Including Water) No data MATERIAL SAFETY DATA SHEET The Valvoline Company Page 007 Date Prepared: 09/14/05 Date Printed: 01/02/07 � MSDS No: 505.0366793-003.001 ALL CLIMATE 5W20 Evaporation Rate No data Appearance State LIQUID Physical Form No data Color Odor pH No data VisCOSity <= 2800.0 cps > 3500.0 cbs 09/20/07 10:58 AM M S D S I N F 0 R M A T 2 0 N Page 9 Part: 75150 Line: NOL Desc: SAE5W20 8.0 - 9.0 cst @ 100 C 10. STABILITY ANB REACTIVITY _ Hazardous Polymerization Product will not undergo hazardous polymerization. Hazardous Decomposition May form: carbon dioxide and carbon monoxide, hydrogen sulfide, methylacrylate, nitrogen oxides, sulfur oxides, various hydrocarbons, zinc oxide. Chemical Stability Stable. MATERIAL SAFETY DATA SHEET The Valvoline Company Page 008 Date Prepared: 09/14/05 Date Printed: 01/02/07 MSDS No: 505.0366793-003.001 ALL CLIMATE 5W20 Incompatibility Avoid contact with: strong oxidizing agents. 11. TOXICOLOGICAL INFORMATION No data 12. ECOLOGICAL INFORMATION No data 13. DISPOSAL CONSIDERATION Waste Manaaement Information 09/20/07 10:58 AM M S D S 2 N F 0 R M A T I 0 N Page 10 Part: 75150 Line: NOL Desc: SAE5W20 Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION DOT Information - 49 CFR 172.101 DOT Description: Not Regulated Container/MOde: CASES/SURFACE - NO EXCEPTIONS NOS Component: None MATERIAL SAFETY DATA SAEET The Valvoline Company Page 009 Date Prepared: 09/14/05 Date Printed: 01/02/07 MSDS No: 505.0366793-003.001 ALL CLIMATE 5W20 RQ (Reportable Quantity) - 49 CFR 172.101 Not applicable 15. REGULATORY INFORMATION US Federal Regulations CERCLA RQ - 40 CFR 302.4 None 5AR.A 302 Components - 40 CFR 355 Appendix A None Section 311/312 Hazard Class - 40 CFR 370.2 Immediate( 1 Delaved( ) Fire( ) Reactive( ) Sudden 09/20/07 10:58 AM M S D S I N F 0 R M A T I O N Page 11 Part: 75150 Line: NOL Desc: SAE5W20 Release of Pressure( ) SAF2A 313 Components - 40 CFR 372.65 None International Regulations Inventory Status Not determined State and LoCal Regulations California Proposition 65 None 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. *** End of Report *** 09/20/07 10:56 AM M S D S I N F 0 R M A T I 0 N Page 1 Part: 75050 Line: NOL Desc: SAE5W30 MATERIAL SAFETY DATA SHEET The Valvoline Company Page 001 Date Prepared: O1/14/02 Date Printed: 12/01/04 MSDS No: 505.0172013-013.004 ALL CLIMATE MOTOR OIL SAE 5W30 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Material Identity Product Name: ALL CLIMATE MOTOR OIL SAE 5W30 SAP Material No: NP75050 General or Generic ID: PETROLEUM BASED-LUBRICATING OIL Company Telephone Numbers The Valvoline Company Emergency: 1-800-274-5263 P.O. Box 14000 Lexington, KY 40512 Information: 1-859-357-7206 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS Number $ (by weight) -------------------------------------------- ------------- ------------- DISTILLATES, PETROLEUM, HYDROTREATED HEAVY P 64742-54-7 77.0- 87.0 DETERGENT/DISPERSANT ADDITIVE 5.0- 15.0 VISCOSITY MODIFIER 1.9- 12.0 ZINC COMPOUNDS 1.0- 6.0 3. HAZARDS IDENTIFICATION Potential Health Effects Eye May cause mild eye irritation. Skin 09/20/07 10:56 AM M S D S I N F O R M A T I O N Page 2 Part: 75050 Line: NOL Desc: SAE5W30 May cause mild skin irritation. Prolonged or repeated contact may dry and crack the skin. Additional symptoms of skin contact may include: acne, Passage of this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use. MATERIAL SAFETY DATA SHEET The Valvoline Company Page 002 Date Prepared: 01/14/02 Date Printed: 12/01/04 MSDS No: 505.0172013-013.004 ALL CLIMATE MOTOR OIL SAE 5W30 Swallowing Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Symptoms usually occur at air concentrations higher than the recommended exposure limits (See Section 8). Symptoms of Exposure Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways), blood abnormalities (breakage of red blood cellsl. liver damaae. 09/20/07 10:56 AM M S D S I N F 0 R M A T I O N Page 3 Part: 75050 Line: NOL Desc: SAE5W30 Target Organ Effects No data Developmental Information There are no data available for assessing risk to the fetus from maternal exposure to this material. Cancer Information This material is not listed as a carcinogen by the International Agency for Research on Cancer, the National Toxicology Program, or the Occupational Safety and Health Administration. Used motor oil has been shown to cause skin cancer in laboratory animals continually exposed by repeated applications. Avoid prolonged or repeated skin contact. Other Health Effects No data MATERIAL SAFETY DATA SHEET � The Valvoline Company Page 003 Date Prepared: 01/14/02 Date Printed: 12/01/04 MSDS No: 505.0172013-013.004 ALL CLIMATE MOTOR OIL SAE 5W30 Primary Route(s) of Entry Inhalation, Skin absorption, Skin contact, Eye contact, Ingestion. 4. FIRST AID MEASURES Eyes If symptoms develop, move individual away from exposure and into fresh air. Flush eyes gently with water while holding eyelids aAart. If svmotoms Aersist or there is anv visual difficultv. 09/20/07 10:56 AM M S D S I N F 0 R M A T I O N Page 4 Part: 75050 Line: NOL Desc: SAE5W30 seek medical attention. Skin Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse. Swallowing Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. Inhalation ' If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. Note to Physicians Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia) that may progress to pulmonary fibrosis. Symptoms are often subtle and radiological changes appear worse than clinical � abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary MATERIAL SAFETY DATA SHEET 09/20/07 10:56 AM M S D S I N F 0 R M A T 2 0 N Page 5 Part: 75050 Line: NOL Desc: SAE5W30 The Valvoline Company Page 004 Date Prepared: 01/14/02 Date Printed: 12/O1/04 MSDS No: 505.0172013-013.004 ALL CLIMATE MOTOR OIL SAE 5W30 _ abno�alities. Preexisting disorders of the following organs ( or organ systems) may be aggravated by exposure to this material: skin. 5. FIRE FIGHTING MEASURES Flash Point 410.0 F (210.0 C) COC Explosive Limit No data Autoignition Temperature No data Hazardous Products of Combustion � May form: carbon dioxide and carbon monoxide, oxides of sulfur, nitrogen and phosphorus, various hydrocarbons. Fire and Explosion Hazards Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively. No special fire hazards are known to be associated with this product. Dense smoke may be generated while burning. Extinguishing Media regular foam, carbon dioxide, dry chemical. Fire Fighting Instructions Water or foam may cause frothing which can be violent and possibly endanger the life of the firefighter. Water may be used to keep £ire-exvosed containers cool until fire is out. Wear a 09/20/07 10:56 AM M S D S I N F O R M A T I 0 N Page 6 Part: 75050 Line: NOL Desc: SAE5W30 self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective equipment. Refer to the personal protective equipment section of this MSDS. , MATERIAL SAFETY DATA SHEET The Valvoline Company Page 005 Date Prepared: 01/14/02 Date Printed: 12/O1/04 MSDS No: 505.0172013-013.004 ALL CLIMATE MOTOR OIL SAE 5W30 NFPA Rating Health - 1, Flammability - 1, Reactivity - 0 6. ACCIDENTAL RELEASE MEASURES Small Spill . Absorb liquid on vermiculite, floor absorbent or other absorbent material. Persons not wearing proper personal protective equipment should be excluded from area of spill. Large Spill Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occured. Persons not wearing protective equipment ' should be excluded from area of spill until clean-up has been completed. 7. HANDLING AND STORAGE Handling Containers of this material mav be hazardous when emutied. Since 09/20/07 10:56 AM M S D S I N F 0 R M A T I 0 N Page 7 Part: 75050 Line: NOL Desc: SAE5W30 emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Al1 five gallon pails and larger metal containers including tank cars and tank trucks should be grounded and/or bonded when material is transferred. Precautions during use: avoid prolonged or frequently repeated skin contact with this material. Skin contact can be mininized by wearing impervious protective gloves. As with all products of this nature, good personal hygiene is essential. Hands and other exposed areas should be washed thoroughly with soap and water after contact, especially before eating and/or smoking. Regular laundering of contaminated clothing is essential to reduce indirect skin contact with this material. Warning. Sudden release of hot organic chemical vapors or mists from process equipment operating at elevated temperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions without the presence of obvious ignition sources. Published "autoignition" or ^ignition^ temperature values cannot be treated as safe operating MATERIAL SAFETY DATA SHEET The Valvoline Company Page 006 Date Prepared: 01/14/02 Date Printed: 12/O1/04 MSDS No: 505.0172013-013.004 ALL CLIMATE MOTOR OIL SAE 5W3� ` temperatures in chemical processes without analysis of the actual process conditions. Any use of this product in elevated temperature processes should be thoroughly evaluated to establish and maintain safe operatina conditions. 09/20/07 10:56 AM M S D S I N F O R M A T I 0 N Page 8 Part: 75050 Line: NOL Desc: SAE5W30 Storage _ Do not store near extreme heat, open flame, or sources of ignition. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Not required under norn�al conditions of use. However, if misting or splashing conditions exist, then safety glasses or chemical splash goggles are advised. Skin Protection Not normally required. However, wear resistant gloves such as nitrile rubber to prevent irritation which may result from prolonged or repeated skin contact with product. To prevent repeated or prolonged skin contact, wear impervious clothing and boots. Wear normal work clothing covering arms and legs. Respiratory Protections If workplace exposure limit(s) of product or any component is exceeded (See Exposure Guidelines), a NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (consult your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure. Not required under normal conditions of use. However, if oil mists are generated above recommended PEL/TLV of 5 mg/m3, then a NIOSH/MSHA approved respirator is advised in absence of proper environmental control. (See your industrial hygienist.) MATERIAL SAFETY DATA SHEET The Valvoline Companv Paae 007 09/20/07 10:56 AM M S D S I N F 0 R M A T 2 O N Page 9 Part: 75050 Line: NOL Desc: SAE5W30 Date Prepared: 01/14/02 Date Printed: 12/O1/04 MSDS No: 505.0172013-013.OQ4 ALL CLIMATE MOTOR OIL SAE 5W30 Engineering Controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s). - Exposure Guidelines Component DISTILLATES, PETROLEUM, HYDROTREATED HEAVY PARAFFINIC (64742-54-7) No exposure limits established • DETERGENT/DISPERSANT ADDITIVE No exposure limits established VISCOSITY MODIFIER No exposure limits established ziNC coMPOUrms No exposure limits established 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point (for component) > 425.0 F(218.3 C) @ 760.00 mmHg Vapor Pressure No data Specific Vapor Density No data Specific Gravity - .876 @ 60.00 F 09/20/07 10:56 AM M S D S I N F 0 R M A T I 0 N Page 10 Part: 75050 Line: NOL Desc: SAE5W30 MATERIAL SAFETY DATA SHEET The Valvoline Company Page 008 Date Prepared: O1/14/02 Date Printed: 12/01/04 MSDS No: 505.0172013-013.004 ALL CLIMATE MOTOR OIL SAE 5W30 Liquid Density _ 7.290 lbs/gal @ 60.00 F .876 kg/1 @ 15.60 C Percent Volatiles (Including Water) No data Evaporation Rate SLOWER TH.z1I�T ETHYL ETHER Appearance DRY, CLEAR & BRIGHT State LIQUID Physical Form Not applicable Color No data Odor No data PH Not applicable Viscosity <= 3300.0 cps @ -25 C 10.5 - 11.2 cst @ 100 C 10. STABILITY AND REACTIVITY 09/20/07 10:56 AM M S D S I N F 0 R M A T I O N Page 11 Part: 75050 Line: NOL Desc: SAE5W30 Hazardous Polymerization Product will not undergo hazardous polymerization. MATERIAL SAFETY DATA SHEET The Valvoline Company Page 009 Date Prepared: O1/14/02 Date Printed: 12/01/04 MSDS No: 505.0172013-013.004 ALL CLIMATE MOTOR OIL SAE 5W30 Hazardous Decomposition May foxm: aldehydes, carbon dioxide and carbon monoxide, hydrogen sulfide, oxides of sulfur, nitrogen and phosphorus, toxic fumes, � various hydrocarbons. Chemical Stability Stable. Incompatibility Avoid contact with: acids, halogens, strong oxidizing agents. 11. TOXICOLOGICAL INFORMATION No data 12. ECOLOGICAL INFORMATION No data 13. DISPOSAL CONSIDERATION Waste Management Information Dispose of in accordance with all applicable local, state and federal regulations. �9l20/�7 10:56 AM M S D S 2 N F O R M A T I 0 N Page 12 Part: 75050 Line: NOL Desc: SAE5W30 14. TRANSPORT INFORMATION DOT Information - 49 CFR 172.101 DOT Description: Not Regulated MATERIAL SAFETY DATA SHEET The Valvoline Company Page 010 Date Prepared: 01/14/02 Date Printed: 12/O1/04 MSDS No: 505.0172013-013.004 ALL CLIMATE MOTOR OIL SAE 5W30 Container/Mode: CASES/SURFACE - NO EXCEPTIONS NOS Component: None RQ (Reportable Quantity) - 49 CFR 172.101 Not applicable 15. REGULATORY INFORMATION ` US Federal Regulations CERCLA RQ - 40 CFR 302.4 None SARA 302 Components - 40 CFR 355 Appendix A None Section 311/312 Hazard Class - 40 CFR 370.2 Immediate( ) Delayed( ) Fire( ) Reactive( ) Sudden Release of Pressure( ) SARA 313 Components - 40 CFR 372.65 None 09/20/07 10:56 AM M S D S I N F 0 R M A T I 0 N Page 13 Part: 75050 Line: NOL Desc: SAE5W30 International Regulations Inventory Status Not determined State and Local Regulations California Proposition 65 None MATERIAL SAFETY DATA SHEET The Valvoline Company Page 011 Date Prepared: 01/14/02 Date Printed: 12/01l04 MSDS No: 505.0172013-013.004 ALL CLIMATE MOTOR OIL SAE 5W30 16. OTHER INFORMATTON _ The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. circumstances. 09/20/07 10:56 AM M S D S I N F 0 R M A T I 0 N Page 14 Part: 75050 Line: NOL Desc: SAE5W30 09/20/07 10:56 AM M S D S I N F 0 R M A T I 0 N Page 1 Part: 7575 Line: BAT Desc: BATTERY I. PRODUCT IDENTIFICATION MANI7FACTURER CHEMICAL/TRADE NAME Lead-Acid Battery Exide Technologies (as used on label) 13000 Deerfield Parkway Bldg. 200 CHEMICAL FAMILY/ Electric Storage Battery Alpharetta, GA 30004 CLASSIFICATION FOR INFORMATION (610)921-4052 Fred Ganster, Environmental, DATE REVISED: October 1, 2001 Safety & Health Page 1 of 9 FOR EMERGENCY CHEMTREC (800)424-9300 CHEMTREC INTERNATIONAL (703)527-3887 - Collect 24-hour Emergency Response Contact Ask for Environmental Coordinator 22. HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Approximate Air Exposure Limits (ug/m3) Components CAS Number � by Wt. OSHA ACGIH NIOSH Inorganic compounds of: Lead 7439-92-1 54-62 50 150 100 Antimony 7440-36-0 0.4 500 500 -- Tin 7440-31-5 0.16 2000 2000 -- Calcium 7440-70-2 0.02 -- -- -- Arsenic 7440-38-2 0.01 10 200 -- Electrolyte (sulfuric acid/water/solution) 7664-93-9 26-40 1000 1000 1000 Case Material: Polypropylene 9003-07-0 5-12 N/A N/A N/A Hard Rubber -- Plate separator material: Polyethylene 9002-88-4 1-2 N/A N/A N/A NOTE: Inorganic lead and electrolyte (water and sulfuric acid solution) are the primary components of every battery manufactured by Exide Technologies or its subsidiaries. Other ingredients may be present dependent upon battery type. Polypropylene is the principal case material of automotive and commercial batteries. 09/20/07 10:56 AM M S D S I N F 0 R M A T I O N Page 2 Part: 7575 Line: BAT Desc: BATTERY III. PHYSICAL DATA - ELECTROLYTE Page 2 Boiling Point - 203 deg.F-240 deg.F (for S.G. range) Melting Point - Not Applicable Solubility in Water - 100� Evaporation Rate (Butyl acetate=l) - Less Than 1 Appearance and Odor - A clear liquid with a sharp, penetrating, pungent odor. A battery is a manufactured article; no apparent odor. Specific Gravity (H2O=1) - 1.230 to 1.350 Vapor Pressure (mm Hg) 77deg.F - 17 to 11 (for S.G. range) Vapor Density (AIR=1) - Greater than 1 � Volatiles by Weight - Not Applicable IV. FIRE AND EXPLOSION HAZARD DATA Flash Point: Not Applicable Flammable Limits: LEL = 4.1� (Hydrogen Gas in air); UEL = 74.2� Extinguishing media: CO2; foam; dry chemical Special Fire Fighting Procedures: Use positive pressure, self-contained breathing apparatus. Beware of acid splatter during water application and wear acid-resistant clothing, gloves, face and eye protection. If batteries are on charge, shut off power to the charging equipment,but, note that strings of series connected batteries may still pose risk of electric shock even when charging equipment is shut down. Unusual Fire and Explosion hazards: In operation, batteries generate and release flammable hydrogen gas. They must always be assumed to contain this gas which, if ignited by burning cigarette, naked flame or spark, may cause battery explosion with dispersion of casing fragments and corrosive liquid electrolyte. Carefully follow manufacturer's instructions for installation and service. Keep away � all sources of gas ignition and do not allow metallic articles to simultaneously contact the negative and positive terminals of a battery. V. REACTIVITY DATA Stability: Stable X Unstable Conditions to Avoid: Prolonged overcharge at high current; sources of ignition. Incompatibility: (materials to avoid) Electrolyte Contact with combustibles and organic materials may cause fire and explosion. Also reacts violently with strong reducing agents, metals, sulfur trioxide gas, strong oxidizers, and water. Contact with metals may produce toxic sulfur dioxide fumes and may release flammable hydrogen gas. V. REACTIVITY DATA (CONTINUED) Paae 3 09/20/07 10:56 AM M S D S I N F 0 R M A T I O N Page 3 Part: 7575 Line: BAT Desc: BATTERY Lead compounds: Avoid contact with strong acids, bases, halides, halogenates, potassium nitrate, permanganate, peroxides, nascent hydrogen, and reducing agents. Hazardous Decomposition Products: Electrolyte: Sulfur trioxide, carbon monoxide, sulfuric acid mist, sulfur dioxide, hydrogen sulfide. Lead compounds: Temperatures above the melting point are likely to produce toxic metal fume, vapor, or dust; contact with strong acid or base or presence of nascent hydrogen may generate highly toxic arsine gas. VI. HEALTH HAZARD DATA Routes of Entry: Electrolyte: Harmful by all routes of entry. Lead compounds: Hazardous exposure can occur only when product is heated above the melting point, oxidized or otherwise processed or damaged to create dust, vapor or fume. Inhalation: Electrolyte: Breathing of sulfuric acid vapors or mists may cause severe respiratory irritation. Lead compounds: Inhalation of lead dust or fumes may cause irritation of upper respiratory tract and lungs. Ingestion: Electrolyte: May cause severe irritation of mouth, throat, esophagus and stomach. Lead compounds: Acute ingestion may cause abdominal pain, nausea, vomiting, diarrhea and severe cramping. This may lead rapidly to systemic toxicity. Skin Contact: Electrolyte: Severe irritation, burns and ulceration. Lead compounds: Not absorbed through the skin. Eye Contact: � Electrolyte: Severe irritation, burns, cornea damage, blindness. Lead compounds: May cause eye irritation. VI. HEALTH HAZARD DATA (CONTINUED) Page 4 09/20/07 10:56 AM M S D S I N F 0 R M A T 2 0 N Page 4 Part: 7575 Line: BAT Desc: BATTERY Electrolyte: Severe skin irritation, damage to cornea may cause blindness, upper respiratory irritation. Lead compounds: Symptoms of toxicity iriclude headache, fatigue, abdominal pain, loss of appetite, muscular aches and weakness, sleep disturbances, and irritability. Effects of Overexposure - Chronic: Electrolyte: Possible erosion of tooth enamel; inflammation of nose, throat and bronchial tubes. Lead compounds: Anemia; neuropathy, particularly of the motor nerves, with wrist drop; kidney damage; reproductive changes in both males and females. Carcinogenicity: Electrolyte: The National Toxicology Program (NTP) and the International Agency for Research on Cancer (IARC) have classified "strong inorganic acid mist containing sulfuric acid" as a substance that is carcinogenic to humans. This classification does not apply to sulfuric acid solutions in static liquid state or to electrolyte in batteries. Batteries subjected to abusive charging at excessively high currents for prolonged periods of time without vent caps in place may create a surrounding atmosphere of the offensive strong inorganic acid mist containing sulfuric acid. Lead compounds: Listed as a 2B carcinogen, likely in animals at extreme doses. Proof of carcinogenicity in humans is lacking at present. Arsenic: Listed by International Agency for Research on Cancer (IARC), OSHA and NIOSH as a carcinogen only after prolonged exposure at high levels. Medical Conditions Generally Aggravated by Exposure: Overexposure to sulfuric acid mist may cause lung damage and aggravate pulmonary conditions. Contact of electrolyte (water and sulfuric acid solution) with skin may aggravate skin diseases such as eczema and contact dermatitis. Contact of electrolyte (water and sulfuric acid solution) with eyes may damage cornea and/or cause blindness. Lead and its compounds can aggravate some forzns of kidney, liver and neurologic diseases. Emergency and First Aid Procedures: Inhalation: Electrolyte: Remove to fresh air immediately. If breathing is difficult, give oxygen. Lead compounds: Remove from exposure, gargle, wash nose and lips; consult physician. VI. HEALTH HAZARD DATA (CONTINUED) Page 5 09/20/07 10:56 AM M S D S I N F 0 R M A T I 0 N Page 5 Part: 7575 Line: BAT Desc: BATTERY Electrolyte: Give large quantities of water; DO NOT induce vomiting; consult physician. Lead compounds: Consult physician immediately. Skin: Electrolyte: Flush with large amounts of water for at least 15 minutes; remove contaminated clothing completely, including shoes. Lead compounds: Wash immediately with soap and water. Eyes: Electrolyte and Lead compounds: Flush immediately with large amounts of water for at least 15 minutes; consult physician immediately. VII. PRECAUTIONS FOR SAFE HANDLING AND USE Handling and Storage: Store batteries under roof in cool, dry, well-ventilated areas that are separated from incompatible materials and from activities that may create flames, sparks or heat. Store on smooth, impervious surfaces that are provided with measures for liquid containment in the event of electrolyte spills. Keep away from metallic objects that could bridge the terminals on a battery and create a dangerous short-circuit. Handle carefully and avoid tipping, which may allow electrolyte leakage. Single batteries pose no risk of electric shock but there may be increasing risk of electric shock from strings of connected batteries exceeding three 12-volt units. Charging: There is a possible risk of electric shock from charging equipment and from strings of series connected batteries, whether or not being charged. Shut-off power to chargers whenever not in use and before detachment of any circuit connections. Batteries being charged wi11 generate and release flammable hydrogen gas. Charging space should be ventilated. Keep battery vent caps in position. Prohibit smoking and avoid creation of flames and sparks nearby. Wear face and eye protection when near • batteries being charged. Spill or Leak Procedures: Stop flow of material, contain/absorb small spills with dry sand, earth, and vermiculite. Do not use combustible materials. If possible, carefully neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc. Wear acid-resistant clothing, boots, gloves, and face shield. DO NOT ALLOW DISCHARGE OF TIN-NEUTRALIZED ACID TO SEWER. Neutralized acid must be managed in accordance with approved local, state and federal requirements. Consult state environmental agency andlor federal EPA. VII. PRECAUTIONS FOR SAFE HANDLING AND USE (CONTINUED) Page 6 Waste Disposal Methods: 09{20/07 10:56 AM M S D 5 I N F O R M A T I O N Page 6 Part: 7575 Line: BAT Desc: BATTERY Spent batteries: Send to secondary lead smelter for recycling. Electrolyte: Place neutralized slurry into sealed acid resistant containers and dispose of as hazardous waste, as applicable. Large water-diluted spills, after neutrization and testing, should be managed in accordance with approved local, state and federal requirements. Consult state environmental agency and/or federal EPA. Precautionary Labeling: POISON - CAUSES SEVERE BURNS DANGER - EXPLOSIVE GASES CORROSIVE - CONTAINS SULFURIC ACID KEEP AWAY FROM CHILDREN VIII. CONTROL MEASURES Engineering Controls and Work Practices: Store and handle in well-ventilated area. If inechanical ventilation is used, components must be acid-resistant. Handle batteries cautiously, do not tip to avoid spills. Make certain vent caps are on securely. If battery case is damaged, avoid bodily contact with internal components. Wear protective clothing, eye and face protection, when filling, charging, or handling batteries. Respiratory Protection: None required under normal conditions. When concentrations of sulfuric acid mist are known to exceed PEL, use NIOSH or MSHA-approved respiratory protection. Protective gloves: Rubber or plastic acid-resistant gloves with elbow-length gauntlet. Eye Protection: � Chemical goggles or face shield. Other Protection: Acid-resistant apron. Under severe exposure or emergency conditions, wear acid-resistant clothing, gloves and boots. Emergency Flushing: In areas where water and sulfuric acid solutions are handled in concentrations greater than 1$, emergency eyewash stations and showers should be provided, with unlimited water supply. IX. OTHER REGULATORY INFORMATION Page 7 NFPA Hazard Rating for sulfuric acid: Flammability (Red) = 0 Health (Blue) = 3 09/20/07 10:56 AM M S D S I N F 0 R M A T I 0 N Page 7 Part: 7575 Line: BAT Desc: BATTERY Sulfuric acid is water-reactive if concentrated. TRANSPORTTATION: Wet (filled with electrolyte) batteries are regulated by U.S. DOT as a hazardous material, as provided in 49 CFR 173.159. Proper Shipping Name: Battery, wet, filled with acid Hazard Class/Division: 8 ID Number: UN2794 Packing Group: I2I Label Required: Corrosive RCRA: Spent lead-acid batteries are not regulated as hazardous waste when recycled. Spilled sulfuric acid is a characteristic hazardous waste; EPA hazardous waste number D002 (corrosivity). CERCLA (Superfund) and EPCRA: (a) Reportable Quantity (RQ1 for spilled 100$ sulfuric acid under CERCLA (Superfund) and EPCRA (Emergency Planning and Co�nunity Right to Know Act) is 1,000 lbs. State and local reportable quantities for spilled sulfuric acid may vary. (b� Sulfuric acid is a listed "Extremely Hazardous Substance" under EPCRA, with a Threshold Planning Quantity (TPQ) of 1,000 lbs. (c) EPCRA Section 302 notification is required if 1,000 lbs or more of sulfuric acid is present at one site. An average automotive/commercial battery contains approximately 5 lbs. of sulfuric acid. Contact your Exide representative for additional information. (d) EPCRA Section 312 Tier Two reporting is required for non-automotive batteries if sulfuric acid is present in quantities of 500 lbs. or more and/or if lead is present in quantities o£ 10,000 lbs or more. IX. OTHER REGULATORY INFORMATION (CONTINUED) Page 8 (e) Supplier Notification: This product contains toxic chemicals that may be reportable under EPCRA Section 313 Toxic Chemical Release Inventory (Form R) requirements. For a manufacturing facility under SIC codes 20 through 39, the following information is.provided to enable you to complete the required reports: Approximate Toxic Chemical CAS Number � by Weight Lead 7439-92-1 54-62 Sulfuric Acid/Water Solution 7664-93-9 26-40 * Antimony 7440-36-0 0.4 * Arsenic 7440-38-2 0.01 * Not present in all battery types. Contact your Exide representative for additional information. If vou distribute this product to other manufacturers in SIC Codes 20 09/20/07 10:56 AM M S D S I N F 0 R M A T I 0 N Page 8 Part: 7575 Line: BAT Desc: BATTERY of each calendar year. Note: The Section 313 supplier notification requirement does not apply to batteries that are "consumer products". CAA: Exide Technologies supports preventative actions concerning ozone depletion in the atmosphere due to emissions of CFC's and other ozone depleting chemicals (ODC's), defined by the USEPA as Class I substances. Pursuant to Section 611 of the Clean Air Act Amendments (CAAA) of 1990, finalized on January 19,1993, Exide established a policy to eliminate the use of Class I ODC's prior to the May 15, 1993 deadline. TSCA: Ingredients in Exide's batteries are listed in the TSCA Registry as follows: CAS N0. TSCA Stdtus Electrolyte: Sulfuric acid (H2504) 7664-93-9 Listed Inorganic Lead Compound Lead (Pb) 7439-92-1 Listed Lead Oxide (Pb0) 1317-36-8 Listed Lead Sulfate (Pb504) 7446-14-2 Listed Antimony (Sb) 7440-36-0 Listed Arsenic (AS) 7440-38-2 Listed Calcium (Ca) 7440-70-2 Listed Tin (Sn) 7440-31-5 Listed CANADIAN REGULATIONS: All chemical substances in this product are listed on the CEPA DSL/NDSL � or are exempt from list requirements. CALIFORNIA PROPOSITION 65: "WARNING: This product contains lead, a chemical known to the State of California to cause cancer, or birth defects or other reproductive harm." IX. OTHER REGULATORY INFORMATION (CONTINUED) Page 9 PREPARED BY: ENVIRONMENTAL, SAFETY AND HEALTH DEPARTMENT EXIDE TECHNOLOGIES 13000 DEERFIELD PARKWAY, BUILDING 200 ALPHARETTA, GA 30004 VENDEE AND THIRD PERSONS ASSUME THE RISK OF INJURY PROXIMATELY CAUSED BY THE MATERIAL IF REASONABLE SAFETY PROCEDURES ARE NOT FOLLOWED AS PROVIDED FOR IN THE DATA SHEET, AND VENDOR SHALL NOT BE LIABLE FOR INJURY TO VENDEE OR THIRD PERSONS PROXIMATELY CAUSED BY ABNORMAL USE OF THE MATERIAL EVEN IF REASONABLE PROCEDURES ARE FOLLOWED. ALL PERSONS USING THIS PRODUCT, ALL PERSONS WORKING IN AN AREA WHERE THI5 ' PRODUCT IS USED, AND ALL PERSONS HANDLING THIS PRODUCT SHOULD BE FAMILIAR WITH THE CONTENTS OF THIS DATA SHEET. THIS INFORMATION SHOULD BE EFFECTIVELY COMMUNICATED TO EMPLOYEES AND OTHERS WHO MIGHT COME IN CONTACT WITH THE PRODUCT. 09/20/07 10:56 AM M S D S I N F O R M A T I 0 N Page 9 Part: 7575 Line: BAT Desc: BATTERY ACCURATE AS OF THE DATE HEREOF, EXIDE TECHNOLOGIES MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE FOR THEIR PARTICULAR CIRCUMSTANCES. ANY PHOTOCOPY MUST BE OF TH25 ENTIRE DOCUMENT (ESSENTIALLY SIMILAR TO FORM OSHA 20 - U.S. DEPARTMENT OF LABOR) *** End of Report *** .. ..r��...... .... ... �. . ....�� w�.� � .... UitO: /Il tl/ I IRM: 5:09:5� PM . .... . . .. . ... , . .. .. .. . ' Paye 15 cf 1 B .. ,. _ . , : .. . : ... , _ , . i . _ .. . . ,. . _ .. • ' i , �/t�• c`�,.;, � �-.. � r PAGE 1 08 6 MATER=AI, SAFET� �D�ATA SHEET to , , `� �'`�.�� r�� w T �., 1 i � } � � '/� ;�� k � A � `:v� .o �.., � A � r � � '+�.� '�' .. i x9r w. .,�k ,� � f +oi� ��i i� ° ��' �aMu rr� ."'!'7\�1 � s' �r ��>. si� .7P-.'� .+�Sa�, .�f x w,�,�F. 'a+i MADRTI�ACTQRER'S NAM$ Par3c� Corpor3tion C�t=GL N71t� 4 SYNONYEIi[3 Petroleum Solvent 3TREET 1�DDitESS One West Strr�et C887�tG1L F71�lZLY Hydrocerbon MixC•.ire CITY, ST7►T� i� 2IP Fall River, MA 02720 TRADE L�11ti ACC� �R�I, SPIRITS Ee�RGF.N+c7t TELEp80AiE (508) b79-59.38 Sz�s/CODS3 Ga21on i�12792 • Quart ik13791 • pORMCJL71.4 Mixture nEVISaa Oz/04/98 � � �'.�, S �'a` �,"� �+�;x .,�y�... ^'�' ^.'a�a,� e, • _1 :.� �.;.�,� . : . nr '..M —9n� , , . /� , }Yo z � � t : ""�SE� _ �� 7�' y � � w � a .:� a .`?" ..�, � .. .... .'"�'-� � ' .- h'Y�F'.. ac."� • ��:A �: .' . Y�.'.� $�wy,':y � ..;' . n6C-...�. y�.Y; � �,�4� y� � � P11=NTS pRESERV7ITI'VES i� SOLVLrNT3 � ' tT�TS 30LVENT3 G►S � � 'at A�ICY '1'1,V TlPS . �. , Stoddard Solvent 8052-41-3 I06 . ACGIH 100 TWA , , ACGZH 200 STEL• �a � OS&�► 100 TWA This comDonent may contain 3.58 �f • r �'1, 2, 4 Tri Metk�yl 95-63-6 � � , Bwnzene • *SFCTIODT 313 0�!' 8]1A�► T2TL� IZi. ., SAZ7�RDOIIS O! I � SOtrYDB ' O� CJ►Sa8 = N. A. r ' �"' , ,n,�,� i�%M ' Sk3., • J „.��'� "•"G�. ' �. . .. ,. ... . ;. . . . . . . .. ?!•. . . . ....� .- ... . � ,. . _ ,,,. �. e .. ,:.�;ro,; ,., �.. . f... .: SoILttQG Poi'DIT (°1r) 310 - 405'F � spSCI7'ZC GR�►V=TY i8,0 . 2) 0.789 'PA�?OR P�38tTltE <mmBQ) 2 mtnHg ��iCiDlP V'OL711'Zi.Z„ 3.00 VAAOA D�T82T7C (71S1t s i) 4:.9 f EY, ViOb� (�li) " . . SOLtTB=L=TY IN �P1►T8R Negliqi�l� (<5$1: 3v1►pOR]1T=� RaS'E, Less than 1 . �7t�aR�C� water whita c2eas� (� � 1) oDOR Hyc2rocarbon tyge vA.c. '773 gi : _.,.� . . �.. .. .• • :. .. ,t�. _•s i i'"��'r '!?,:.. . ��' u'i:�'�i ' i� n..:•. ' .:Jr , • .�� T yt. . ��'"' � ,.i• � � .��iV�'' .. � 'w:.� �.:�:+�+r: r..Y. xs. � . _ -.sx.�lsoY• '.. y....w . FL1►SH pOlm'1' il�z`SOD IISZD) s 105°F; TCC. � p�►aLa Lxxx�rs t �c vaz � r.�: z . o ; � . ___.. '� . �� ; vELt 6.0 i �e � ��: �ri : �� - �za�o�ts�x�o ��►r Extir.guis3i dry chA.,mical, CO� or �a universa]. cype toun. Sp C?.,nL ?SaST� PROC�tJRE ]l� ptRE AiVQ Self breaching apparatus recononenc'.ed for f re fighter� Water spray may be useful in minfmizing vapors and cooling containers exposed �o heaG and fl�ame. Avoid.aprsadiaq burning witb watez used for coolinQ purposes. This ma��rial is�combustible ar►d inay be iynited by heat or flame. Never uae weldinq or cutting tor::h oa or'nenr containers tevars ea4pty) becauae product (even just residue) can iqr�ite explo;�sively. " All 5 gallon pails and drums abould be grounded and/or bond.d whwn material is;transfai;red. Vaaors are heavier thaa air and may travel alonq the ground or may be move�d.by ver and ignited by tieat, pilot liqhCs, oth�r flames e�nd ignition sources at�loceciona diatane froa�aiatorial handlin� Doint. �i �i • , y . � : ��r : �' S,> � ..�_ � ..�� . � ��. From: Respo�der lo: 5iEPHANIE RAINEY Date: T/18/20Q2 Tims: 5:08:54 PM . Pap� 16 of 18 �_ ,� �, � pAGE T OF 4 Apt 1(INaRAT. �PI�(tITS REY=3�D: 0]J04j98 � „�: i "'b� �w� � wan i Y., > .. AC't� �'a. ..• i r� : ; � . �. t k;$EC',�Q,�v� °�I�� `;�;FsI�E � .:w.�. .�40 �,. ��Z.�,��D��fi''�i , �. � � .... X��' �,�=,«i IINVS�TAL PIRE �NA EXPLOSIODI HAZ7►RDS' L171T11 '� . H7►Zl►ItD R71Di1�ING ' . ,'� ' 0 Loa�tj 1 91iqhC� 2 �1od�sat�i 3 SiQhj 4 Extr� NFPA H117.ARD CLASS 8aSI9 H71Z11ItD CL71S8 Health Hazard 0 Health Hazard 1 Fiammability 2 _ FlamnabiiiCy 2 Reactivity 0 iteactivity 0 "�"�e�_� ' )� � � v.,.. ^ ... � Wn{. �+ _ f �. f�Jf�,. •. �'�. h» 'v. : �b. f.Y.:.�� `.w��" �y� A .�.. fN 'F4� .L . y � � .'Ha q$.. ^ � . °9�i oF' � � . . .k{ �fs" S. .!2'+M! :!'.. ..v�a.%� .�:3sg' . . N T�tESBOLD L=MYT VALUEs See 5ectio II. � i` ' E!'TSCTS o! OV7�3t�7CPO5VRE ;► . , , aYE CONT!►CTs Expoaure may causei'mild eye irricatioa. Symptoms uW�y incluQe stinginq, tears.�ng' and rednes� . .,: � ffiC2� CONT�CT: Exposure may csuse ��.:d akin�;irritation. Prolon�ed or repeated oxposure may dry the sk�n. Symptoms may includ rednes"s, buming, 8zying and crackiag amd skin burna. Preexisti7ng skin disorders niay be sFggravat�d hy exposura to this meterial. Skin absorptica is possible but harmful eftects are not expected fr�n this route ot exposure under normal conditions of har�lihq aad use. ' tNli71L71T=ODt (Sit�7►T8Z7�G� : Expoaure� to vapor or.; miat is possibls. Short tene fahaiatioa tox?city i: loar. Breathir�q'small, amounts during normal husdling is not likely to cause harmtul effects_ Sreathinq largQ aawunta may be hassaful. 5ymptoms aze more Cypl.aally seen at air concentratioaa exceedisig tYs",�a: exposurQ limits. Syt�taaoa Ot exposure may include irritation (nose, throat.: resgiratory�tractl, pre-exiaeing lunq disorders (e.Q. asthma-1J:k� conditions nu►y be aggravated by exp��u=e to this material) and c�ntral nervous system depression (dizziaess, �rFirowsiaess, weaktlass, fati�ue, nausea,, beadache, unconscicusneas). :� =NG88�ZON�swALLO��ri�_; Sinqle dose oral toxicity is low. Swallowing small amo��.nts during aor:nal hanil nQ ,� likaly to caus4' haim£uJ. effects. SaPallowiny lnrge �unts may be liz►rmful. 5ymptoms taay iac3ude ga��rointestinal irritacion (:sausea, vomitirig, disrrhe and ceaCrsl awrvous system d.epres.sioa, (diaz3.�is�ss: dzowrinwcs,.weakness, �atigue, nausea, headache, uaconseiousness)�. Th�a�mafer�al� can enter the lungs during swal?owing or vomitiag and cause lunq inflacmmt�.on aad/or� daczag�: � • �RGaNCY � tIRST JIID P]lOC�'DQR]ES 7�YS Co1�tT�►CT: Flush wi th weter tor 15 miautes . SQek medical help . , . 83�=�1 C010T11CT: Wash with mild soap and wa►ter solution and saek mQdical attQntion. i�L�TZON: Remove to fresh air.`''Apply �rtificial respiration if breathirig stops. Saek enedical atcentioa immediatsly. ' ' � � , Y�STSO�s If swallowed, do not iiuluce tiaaiting. Seek�medical attention im�nediately. pR�AY Rot�T=(8) OF �TA7t: Inhaiation, skin contact and eye contact. � < E!'FSCTS O! CHlto�IC �7ePOSVRS: Has�d on th�a available intormstion, this eaaterisl caruiot bQ classi£ied with regard to carcinaqeaicity�. This msteria►1 is not listod as a carcinoqea by ZARC, NTP �r OSHA. u � : �' '�'v' ^ tiy' „ '� , • ' �: . �-'�' .+�, n , r � �,t.�,.:; ..... i ?r ;r:.y�'"-:..wj x ': x�:. _:�" ��'�� x r•�SECTIO?�VT;�� '��'R�ACTI�.�. �A�;'�� :' �A l.,t.;.�,:r�'' . :: ��:rF. ,. . � e:. :� ° .� � 9 ST�SILSTY: Stable. •; CosTasTZ�N so a►voZD: Heat, snnrk;�, tire, opsa tlame and all othor sources oF iqnition. i . � a.. ., . � - -- _�.�,� s` .<esponder To: STEPHANIE RAINEY Date: 7/18/2002 Tirtro: 5:08:54 PM Paye 17 ot 18 .:.. . : , .._..... ... . . . ,.,,. .., . ,•..,_ . . ... ..,. � .- .... .�_ , ..... ,.. . _ .. ., ._ . _�.. _. . . . , . . , .. ' . PAGE 3 OF 4 �.CB tfINERAL 3PIAITS REVISED: 02/04/98 ip �',�;'i. ».�� ,�.M+la� .., .."...x '�(i1� a,yl�. � ... ""' { : ;:� .� % � � TA .corr�:�� , � :� '�"'_; "s {��?�,��.w.. :� �. �. _: .:R� �,' � INCOMPATISILIT7C (MA'1'ERIALS TO ]►VOID : Strong oxidizing agents. Strong acids or bases and selected amines. � xAZAADOVS DECOMPO8ITI0N PRODIICTS: TY:ermal dec!�mposition may yield carbon monoxide and/or CO . SAZA1tDOV9 POLYD�EAIZAT20N Will not occur. � COI4DITION3 TO. ]1YOID: � � ! t �� P _. .a� � � �''� �'�.^"5 s@S�� n�` .:: t �v R X.. � "A �. �'" � � , �}f r .i Mb 'Y ��-� 3� .� .rY : .. .� . a :� ��"��ro �c � � sP= .. �� e�� `�� ' � . � �..`._; 1 STEPS TO HE T]1REi�T 2� CASE DZATERI.i 23 RBI OR S?ILLED t . ;�� Sr11�tL SPZLL:, Absorb liquid on vp.xmiculite, floor absorbent or other ai�sorben;. material. L7►RG� SgSLLs Eliminate all ign�tion sources• (flares, Elsmes, including pilot lignts, electrical soarks). Persons not wea:inq �rotective equipment should be excluded from area oE spill until cleanup has been �ompletec?. Seop spill at soi:z�cQ. Prevent from e�tering draina, aewers, atrearas or other bodies of water. Prevent trom sprsading. 3f runoff occurs, notify authorities ea required. Pump rsr vacuum tranrfer spilled product to clean container9 for recovery. A2�sorb unzecoverablu product, trari�fex cont2�minated sbsorbent, soil and other materiala to contair.ers for diaposal. Prevent runoff to sewers, streaa�s or other bodies of wnter. 2f r�noff occurs., notity proper authorities, as required, that a sDiil Yaas occurrad. WJ►STS DISBOS7IL t�T80D a, � s�L spZLL Dispose of ia acco.:`d�snce w$tY�:�a21 local, state and federal regulatians. y ^". .. �, i�►RGS SpSLL: Dispose of in ac'�c+rdnn�e..�with all applica�blo local, state •3nd sederal regulations . '� •r • �+: � � . . ��},.. y y�.�. y • • ' � �a j � ' ;� . , . . + O�' .. '` +$J"k $ �� = s .. . . P .. E .. . , . : ��. � ��. � �� -:. .. . ;. . RESp�TO�tY PROT�CTIO� (SpsCi�c 2�t�E� :` Self-.coatained breathiag apperatus for concentrations above TLV limits.� ,, . . _ VENTIL7lTI0� : . . . . ., � : LoCl►L �IIB'Ps Adequste ventilaCior. rQqriired: 1. , . �C811li=C71L (�) s Yes • B�CZaLs No smokfag: � � OTS�A N.A. � `• � . .. j PROTECTIVi GLOVES: Itapermeable �jk�vea. .i ' �YE PROT�CTIO�: Saf'tY 9oQ4 �. ' , • i CTI�R pROTSCTIVB EQD=?�1Ts Zt ;;� auggost� t!�u�t a source of clean water be available in work area for fluahing eyes and �kin. Iri�ervious clothing should be worn as needed. Y �^. �...�A��M . "y�l , I .. siYe+,� ` s .-...'�is.. �•.+k�' i ..� '�' �• " ' '" �� •� `'• � , 7 �� ,r�i'" y �� ` ° �� 1 �� , . , •� �...i>.3 :... .?4 .:.w� 'R«2 & . ♦ !1 w . yq; , xi�::.,.Y�. .s. .':.f ..y.s. .�.t '+w`� T .,.o�e �" :, : pR8GDT20�t3 TO SL T71REUT ZN HANDTdNG �� 9TORZNG: Keep away lrom heac, sparks and opG� flame. Usa �rith adequate ventil�t�ion. :Ceep coataiaer closed. o�r�x p�tsGlvTior�s: Parsonnwl shouid avoic.� inhr.lacioa oP vapors . PQrsonal contact with the product should be avoided. Should contact be ma►de, remove saturated clothing an6 flush aftacted areas with water. • 3 � �:�.., . �. .� . , ; � �;..�. � � ��'�� f'� t� ...xm3..��.� .,. from: Responder To: STEPFiANIE RAINEY � Oato: 7/18l20pT Time: 5:08:54 PM Paps 18 of 18 .. , .; . � . .. � � .:. ... .':..., ' ��: -. �....a.:.o!�.:..�..:� .: ;,`f'�� ,��..�� .,.: ti :tL .�� '' ..�,�� i�- _�. .. � , ..... i . .� ...... . . . ... �.. ... .. �. . . . . .....� . . .t. : . � . .. . . . . .. .. . .... � � . � •d �� . PAQE 4 OP � xC � 1(IDiEA71L SPI�tITS AE'�tI38Di C1/0`/98 J" w"" e aA �N l� �""",�+�_ ,�' a w. ��"I�' , r`'.� ° �!71�' �•' Y t�' ;�.. '�1y"� �. . r r:;� 'n'� ,d+ 7.�-:i � s��er�:t��:� s�o�� N �.> � p :1� � 'ir. � ar. .�:: � r.wa:re. .+l�. �:x�,.c�w,., .�..::« .«..ar T:^+r s i � oT�3ER RE6DL�TORY INFORbtAT=ODi: Tb's State of California's Safe Drinkin�, Water and Toxic Enforceznent Act of 1986 {Prop 65) develc.ps a list of chemicals that raquirE s�ecific warnings relating to cancer and/•�r :eprcductive Coxicity. This product cor.tains the following chemicals subject to the r�portir.g requirements of the State of California's Safe DrinkinQ WaCer and Toxic Enforcenunt Act af 1986 tProp 65). CSEMICAL � GS � 4U71NT2TY Toluene** 108••88-3 500 PPM Senzene+* 71�•43-2 • <10 PPM The warninQ or► the product statss,: � , WARNING: IIS� OF THIS BRODUCT WILL..EXPOSE YOG' TO BF1iZSNE WHICH IS t�TOWN TO CAUSE CAI�'CER ANA TO TOLUENE WFIICH IS SQJOWN TO CAiJS13 BIRTH �EFF:C'i`3 OR OTHER REPROD�ICTIVE HARM. ++Not iaclnded ix S�atioa 22 as t�.ts a]�a�aal �ia l�ss tbsa .i�C of th� tormnla. • .:.. • : r • r . . ... � . . . � _ ... �. � .i.; v� . . . '^il:t ;. .YZ t:l� . . `�� .. ..a �: �� Y•� ....�" ' � .r � r' .. 'tj ' ' ' . .. �r; � . � ►�-..�.,� � .�.. . ..: r - .:d"inLt " etc. . ... <: r: � t':.ti'.rs•.:' � ;. x.1e• ,t .X'Jiy�Y• . . • . : n . — �• . • . •' � , .. �.; � . , � . . . . .v -.Y .,�.. ., �..� .. ... �-..:. __ _— . _ _ . . . � �'�". t� . . . . THE INF�RMATI�N IN THIS DOCUMENT YS B�,uIBt�� T0 HE CORRECT AS OF THE DATE I3SVED. HOWEVER, NO WARRANTY OF MERCHANTAHILITY. F;I'PIdESS F�GR ANY PJIRTICULJ�R PURPOSS OR ANY OTH:::� WARRANTY IS EXPRESSED OR IS TO BE I�[dP1�'IED RF.�GAR�ING THE ACCUR]�CY OR COMPLETBNE::.S OF THIS INFORMATION, THE•RESULTS TO BE OF3`AINED FROM T'3E USE OF THIS INFORMATION OR THE PRODLJCT, THE SAFETY OF TfiIS PRODUCT OR THE :3AZARDS QELelTr."D TO ITS USE. THIS INFORMP►TZ013 ',I•;D PRODUCT ARE FURNZSI3ED ON T�iE CONDITIQN � THAT T.HE PFRSON RECEIVING THEM SHALL 1�.>:r: HIS OWN DETERMINATION AS TO THn SUITASILITY OF TI�`E PRODUCT FOR HIS PARTICULAR PURPOSE 11ND ON TI3E CONDITION THAT HE ASSUME THE RISI; OP HIS 'QSE �•if$REOF. .. z Z � { 'S , � R � ! e � r . � R. � +•. ,� R � � y, ' - . . . � � . � . � . .. ' f�� .� . . . f• . . � ' �. a � 1 . . . , {'• ' . .. . .; ' i� , ! ; . � ; � • . � �. . • � � �. . � • . � E; , � � , , . �� . . , "1 . ......��. . 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":�.-_�_ I� � oZG" 4� � Dete �� '' �'��►�i'`a�tfte for aq ias Special Condiriovs, ifany � $..= pcctioas (952) 447-985Q fa: (952) 447-4245 '`�3� ��a� �hctt S.E., Prior take, Minnesota 55372 e� ; �� ` �"r:` ' s� � �' r . ' _ ... ... � � � . . . .. . ��j k �a�x.�,+ . �, � -� : . .� � : _ � . + : _.__. _ _ _.._ � .; . -- - �" �£ �,�.w«,. _,.. _ _ _ — — __